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Novel Trends in Electroorganic Synthesis pp 213–216Cite as

Influence of Electrogenerated Bases on the Electroreduction of Some Carbonyl Derivatives

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Abstract

The influence of bases generated during an electrolytic reduction may influence the reduction route of compounds having a removable hydrogen in different ways. In this communication the reduction of some carbonyl derivatives in DMF has been investigated. The presence of a labile hydrogen may lead to reactions which can be classified as follows.

  1. 1.

    Evolution of hydrogen

  2. 2.

    Formation of anion

  3. 3.

    Elimination to nitrile

  4. 4.

    Rearrangement.

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Author information

Authors and Affiliations

  1. Department of Organic Chemistry, University of Aarhus, DK-8000, Aarhus C, Denmark

    Henning Lund, Benoit Soucaze-Guillous & Zi-rong Zheng

Authors
  1. Henning Lund
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  2. Benoit Soucaze-Guillous
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  3. Zi-rong Zheng
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Editor information

Editors and Affiliations

  1. Department of Applied Chemistry, Faculty of Engineering, Okayama University, 3-1-1 Tsushima-naka, 700-8530, Okayama, Japan

    Sigeru Torii

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© 1998 Springer Japan

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Lund, H., Soucaze-Guillous, B., Zheng, Zr. (1998). Influence of Electrogenerated Bases on the Electroreduction of Some Carbonyl Derivatives. In: Torii, S. (eds) Novel Trends in Electroorganic Synthesis. Springer, Tokyo. https://doi.org/10.1007/978-4-431-65924-2_65

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  • DOI: https://doi.org/10.1007/978-4-431-65924-2_65

  • Publisher Name: Springer, Tokyo

  • Print ISBN: 978-4-431-65926-6

  • Online ISBN: 978-4-431-65924-2

  • eBook Packages: Springer Book Archive

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