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Remarkable Effect of Supporting Electrolyte on the Electroreductive Cyclization of Cyclic Enones

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Novel Trends in Electroorganic Synthesis

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Abstract

The stereoselectivity of electroreductive cyclization of butenolide 1 changes significantly depending upon the choice of supporting electrolyte. Metal coordination to the anionic intermediate of electroreductive cyclization is postulated.

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References

  1. Nonaka, T. In Organic Electrochemistry, Lund, H. and Balzer, M. M. eds., Dekker. New York, 1991; chapter 7.

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  2. Little, R. D.; Schwaebe, M. K. Top. Curr. Chem., 1997, 185, 1.

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  3. Bode, H. E.; Sowell, C. G.; Little, R. D. Tetrahedron Lea. 1990, 31, 2525.

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Author information

Authors and Affiliations

  1. Faculty of Engineering, Shizuoka University, 3-5-1 Johoku, Hamamatsu 432, Japan

    Akinori Konno, Heinrich Bode & R. Daniel Little

  2. Department of Chemistry, University of California, Santa Barbara, CA, 93106, USA

    Akinori Konno, Heinrich Bode & R. Daniel Little

Authors
  1. Akinori Konno
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  2. Heinrich Bode
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  3. R. Daniel Little
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Editor information

Editors and Affiliations

  1. Department of Applied Chemistry, Faculty of Engineering, Okayama University, 3-1-1 Tsushima-naka, 700-8530, Okayama, Japan

    Sigeru Torii

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© 1998 Springer Japan

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Konno, A., Bode, H., Little, R.D. (1998). Remarkable Effect of Supporting Electrolyte on the Electroreductive Cyclization of Cyclic Enones. In: Torii, S. (eds) Novel Trends in Electroorganic Synthesis. Springer, Tokyo. https://doi.org/10.1007/978-4-431-65924-2_64

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  • DOI: https://doi.org/10.1007/978-4-431-65924-2_64

  • Publisher Name: Springer, Tokyo

  • Print ISBN: 978-4-431-65926-6

  • Online ISBN: 978-4-431-65924-2

  • eBook Packages: Springer Book Archive

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