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Remarkable Effect of Supporting Electrolyte on the Electroreductive Cyclization of Cyclic Enones

  • Akinori Konno
  • Heinrich Bode
  • R. Daniel Little
Conference paper

Abstract

The stereoselectivity of electroreductive cyclization of butenolide 1 changes significantly depending upon the choice of supporting electrolyte. Metal coordination to the anionic intermediate of electroreductive cyclization is postulated.

Keywords

Electrochemical Reaction Supporting Electrolyte Chemical Reduction Remarkable Effect Metal Coordination 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

References

  1. 1.
    Nonaka, T. In Organic Electrochemistry, Lund, H. and Balzer, M. M. eds., Dekker. New York, 1991; chapter 7.Google Scholar
  2. 2.
    Little, R. D.; Schwaebe, M. K. Top. Curr. Chem., 1997, 185, 1.CrossRefGoogle Scholar
  3. 3.
    Bode, H. E.; Sowell, C. G.; Little, R. D. Tetrahedron Lea. 1990, 31, 2525.CrossRefGoogle Scholar

Copyright information

© Springer Japan 1998

Authors and Affiliations

  • Akinori Konno
    • 1
    • 2
  • Heinrich Bode
    • 1
    • 2
  • R. Daniel Little
    • 1
    • 2
  1. 1.Faculty of EngineeringShizuoka UniversityHamamatsu 432Japan
  2. 2.Department of ChemistryUniversity of CaliforniaSanta BarbaraUSA

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