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Reactivity of O,O’-Dihalogenated Phenols in Anodic Oxidations

  • Shigeru Nishiyama
  • Hironori Konishi
  • Satoshi Iida
  • Shosuke Yamamura
Conference paper

Abstract

Anodic oxidations of o,o’-dihalogenated phenols afford diaryl ether or diaryl derivatives as one-electron oxidation products. Halogen substituents control the oxidation mode: the Cl or Br derivatives provide the diaryl ethers, whereas the diaryls are specifically produced from the iodo compounds. The reaction mechanism of these reactions is discussed.

Keywords

Anodic Oxidation Iodine Atom Phenolic Oxidation Oxidation Mode Halogen Substituent 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

References

  1. 1).
    S. Yamamura and S. Nishiyama, “Studies in Natural Products Chemistry”, (Atta-ur-Rahman Ed); Elsevier, 1992, 10F, 669.Google Scholar
  2. 2).
    S. Nishiyama, M. H. Kim, and S. Yamamura, Tetrahedron Lett., 1994, 35, 8397.CrossRefGoogle Scholar
  3. 3).
    S. C. Fry, Meth. Enzymol., 1984, 107, 388.CrossRefGoogle Scholar

Copyright information

© Springer Japan 1998

Authors and Affiliations

  • Shigeru Nishiyama
    • 1
  • Hironori Konishi
    • 1
  • Satoshi Iida
    • 1
  • Shosuke Yamamura
    • 1
  1. 1.Department of Chemistry, Faculty of Science and TechnologyKeio UniversityKohoku-ku, Yokohama 223Japan

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