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Enantioselective, Electrocatalytic Oxidation of 1-Phenylethylamine on a Chiral Tempo-Modified Electrode

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Novel Trends in Electroorganic Synthesis

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Abstract

Preparative enantioselective electrocatalytic oxidation of 1-phenylethylamine was succeeded achived on a poly (acrylic acid) (PAA)-coated graphite felt (GF) electrode immobilized (6R,7R,10R)-1-aza-4-amino-2,2,7-trimethyl-10-isopropylspiro[5.5]undecane-1-yloxyl (Chiral TEMPO) in high current efficiency and (R)-enantioselectivity.

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References

  1. Z. Ma, G. Huang, and J. M. Bobbitt, J. Org . Chem., 1993, 58, 4837.

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  2. Y. Kashiwagi, F. Kurashima, Y. Yanagisawa, J. Anzai, T. Osa, and J. M. Bobbitt, Proceedings of 7th International Symposium on Electrochemistry (Taiwan), 1996, 58.

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  3. Y. Kashiwagi, H. Ono, and T. Osa, Chem. Lett., 1993, 257.

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Author information

Authors and Affiliations

  1. Faculty of Pharmaceutical Sciences, Tohoku University, Aobayama, Aoba-ku, Sendai, 980-77, Japan

    Yoshitomo Kashiwagi, Futoshi Kurasima, Chikara Kikuchi, Jun-ichi Anzai & Testuo Osa

Authors
  1. Yoshitomo Kashiwagi
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  2. Futoshi Kurasima
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  3. Chikara Kikuchi
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  4. Jun-ichi Anzai
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  5. Testuo Osa
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Editor information

Editors and Affiliations

  1. Department of Applied Chemistry, Faculty of Engineering, Okayama University, 3-1-1 Tsushima-naka, 700-8530, Okayama, Japan

    Sigeru Torii

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© 1998 Springer Japan

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Kashiwagi, Y., Kurasima, F., Kikuchi, C., Anzai, Ji., Osa, T. (1998). Enantioselective, Electrocatalytic Oxidation of 1-Phenylethylamine on a Chiral Tempo-Modified Electrode. In: Torii, S. (eds) Novel Trends in Electroorganic Synthesis. Springer, Tokyo. https://doi.org/10.1007/978-4-431-65924-2_52

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  • DOI: https://doi.org/10.1007/978-4-431-65924-2_52

  • Publisher Name: Springer, Tokyo

  • Print ISBN: 978-4-431-65926-6

  • Online ISBN: 978-4-431-65924-2

  • eBook Packages: Springer Book Archive

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