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Enantioselective, Electrocatalytic Oxidation of 1-Phenylethylamine on a Chiral Tempo-Modified Electrode

  • Yoshitomo Kashiwagi
  • Futoshi Kurasima
  • Chikara Kikuchi
  • Jun-ichi Anzai
  • Testuo Osa
Conference paper

Abstract

Preparative enantioselective electrocatalytic oxidation of 1-phenylethylamine was succeeded achived on a poly (acrylic acid) (PAA)-coated graphite felt (GF) electrode immobilized (6R,7R,10R)-1-aza-4-amino-2,2,7-trimethyl-10-isopropylspiro[5.5]undecane-1-yloxyl (Chiral TEMPO) in high current efficiency and (R)-enantioselectivity.

Keywords

High Performance Liquid Chromatography Acrylic Acid Current Efficiency Cationic Exchange Membrane Potential Electrolysis 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

References

  1. 1).
    Z. Ma, G. Huang, and J. M. Bobbitt, J. Org . Chem., 1993, 58, 4837.Google Scholar
  2. 2).
    Y. Kashiwagi, F. Kurashima, Y. Yanagisawa, J. Anzai, T. Osa, and J. M. Bobbitt, Proceedings of 7th International Symposium on Electrochemistry (Taiwan), 1996, 58.Google Scholar
  3. 3).
    Y. Kashiwagi, H. Ono, and T. Osa, Chem. Lett., 1993, 257.Google Scholar

Copyright information

© Springer Japan 1998

Authors and Affiliations

  • Yoshitomo Kashiwagi
    • 1
  • Futoshi Kurasima
    • 1
  • Chikara Kikuchi
    • 1
  • Jun-ichi Anzai
    • 1
  • Testuo Osa
    • 1
  1. 1.Faculty of Pharmaceutical SciencesTohoku UniversityAobayama, Aoba-ku, SendaiJapan

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