Enantioselective, Electrocatalytic Oxidation of 1-Phenylethylamine on a Chiral Tempo-Modified Electrode
Preparative enantioselective electrocatalytic oxidation of 1-phenylethylamine was succeeded achived on a poly (acrylic acid) (PAA)-coated graphite felt (GF) electrode immobilized (6R,7R,10R)-1-aza-4-amino-2,2,7-trimethyl-10-isopropylspiro[5.5]undecane-1-yloxyl (Chiral TEMPO) in high current efficiency and (R)-enantioselectivity.
KeywordsHigh Performance Liquid Chromatography Acrylic Acid Current Efficiency Cationic Exchange Membrane Potential Electrolysis
- 1).Z. Ma, G. Huang, and J. M. Bobbitt, J. Org . Chem., 1993, 58, 4837.Google Scholar
- 2).Y. Kashiwagi, F. Kurashima, Y. Yanagisawa, J. Anzai, T. Osa, and J. M. Bobbitt, Proceedings of 7th International Symposium on Electrochemistry (Taiwan), 1996, 58.Google Scholar
- 3).Y. Kashiwagi, H. Ono, and T. Osa, Chem. Lett., 1993, 257.Google Scholar