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Application of Transition Metal Substituted α-Keggin Silicon Polyoxotungstates as Oxidation Electrocatalyst

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Novel Trends in Electroorganic Synthesis

Abstract

Transition-Metal (Mn, Co, Fe, and Cr) substituted silicon polyoxotungstates (SiW11O39Mn−) can be used successfully as electrocatalyst for alcohol oxidation. The behavior of a manganese substituted silicon polyoxotungstate (K6SiW11O39Mn(II)(H2O)) under electrochemical oxidation conditions was investigated by means of cyclic voltammetry and the formation of the active complex SiW11O39Mn(OH) was confirmed.

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References

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Author information

Authors and Affiliations

  1. Kekulé-Institut für Organische Chemie und Biochemie, Universität Bonn, Gerhard-Dormagk-Str. 1, 53121, Bonn, Germany

    Masahiro Sadakane & Eberhard Steckhan

Authors
  1. Masahiro Sadakane
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  2. Eberhard Steckhan
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Editor information

Editors and Affiliations

  1. Department of Applied Chemistry, Faculty of Engineering, Okayama University, 3-1-1 Tsushima-naka, 700-8530, Okayama, Japan

    Sigeru Torii

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© 1998 Springer Japan

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Sadakane, M., Steckhan, E. (1998). Application of Transition Metal Substituted α-Keggin Silicon Polyoxotungstates as Oxidation Electrocatalyst. In: Torii, S. (eds) Novel Trends in Electroorganic Synthesis. Springer, Tokyo. https://doi.org/10.1007/978-4-431-65924-2_42

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  • DOI: https://doi.org/10.1007/978-4-431-65924-2_42

  • Publisher Name: Springer, Tokyo

  • Print ISBN: 978-4-431-65926-6

  • Online ISBN: 978-4-431-65924-2

  • eBook Packages: Springer Book Archive

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