Electrochemical Oxidation of Diols Mediated by Organotin Compounds
A new diol selective electrochemical oxidation method has been developed utilzing dibutyltin oxide and bromide anion as mediators. The oxidation proceeded effectively at 0°C under nutral condition. Cyclohexane diol was selectivly oxidized even in the presence of excess primary or secondary alcohols.
KeywordsSecondary Alcohol Organotin Compound Method Electrolysis Bromide Anion Current Electrolysis
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