Advertisement

Electrochemical Oxidation of Diols Mediated by Organotin Compounds

  • Toshihide Maki
  • Kazuhiro Fukae
  • Hitomi Harasawa
  • Takahiro Ohishi
  • Yoshihiro Matsumura
Conference paper

Abstract

A new diol selective electrochemical oxidation method has been developed utilzing dibutyltin oxide and bromide anion as mediators. The oxidation proceeded effectively at 0°C under nutral condition. Cyclohexane diol was selectivly oxidized even in the presence of excess primary or secondary alcohols.

Keywords

Secondary Alcohol Organotin Compound Method Electrolysis Bromide Anion Current Electrolysis 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Reference

  1. 1.
    S. David and A. Theffry, J. Chem Soc. Perkin I, 1568–1573 (1979).Google Scholar
  2. 2.
    Y. Tsuda, M. Hanajima, and K. Yoshimoto, Chem. Pharm. Bull., 31, 3778–3788 (1983).CrossRefGoogle Scholar

Copyright information

© Springer Japan 1998

Authors and Affiliations

  • Toshihide Maki
    • 1
  • Kazuhiro Fukae
    • 1
  • Hitomi Harasawa
    • 1
  • Takahiro Ohishi
    • 1
  • Yoshihiro Matsumura
    • 1
  1. 1.Faculty of Pharmaceutical SciencesNagasaki University1-14 Bunkyo-machi, Nagasaki 852Japan

Personalised recommendations