A Convenient Electrochemical O-Glycosylation of Thioglycoside Using Catalytic Br
O-Glycosylation of thioglycosides 1 with alcohols 3–5 was successfully performed by electrooxidation in the presence of catalytic amount of ammonium or metal bromide to afford O-glycosides 2.
KeywordsBenzyl Alcohol Current Efficiency Platinum Electrode Catalytic Amount Electricity Yield
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
- 1).G. Balavoine, S. Berteina, A. Gref, J.-C. Fischer, and A. Lubineau, J. Carbohydr. Chem. 1995, 14, 1217, ibid. 1995, 14, 1237.Google Scholar
- 2).C. Amatore, A. Jutand, G. Meyer, P. Bourhis, F. Machetto, J.-M. Mallet, P. Sinay, C. Tabeur, Y. M. Zhang, J. Applied Elctrochem. 1994 24,725 and the references cited therein.Google Scholar
© Springer Japan 1998