Abstract
A novel electrochemical partial fluorination of α, β-unsaturated esters efficiently took place accompanied by the rearrangement of the β-substituted alkyl groups to the α-position to afford gem-β,β-difluoroesters in good yields under the pulse electrolysis conditions using Et3N-5HF electrolyte.
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References
N.Yoneda, 7étrahedm,47 5329 (1991).
T.Fuchigami, M.Shimojo, AKonno, J. Org. Chem., 60, 3495 (1995).
K Momota, K Kato, M. Morita, Y. Matsuda, IIectrachimicaActâ, 40, 233 (1995).
S.-Q.Chen, T.Fukuhara, S Hara, N.Yoneda, IIectrachemícaActa, 42, 1951 (1997).
J.H.Meurs, WEilenberg, ktrahedrnn,47 705(1991).
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© 1998 Springer Japan
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Yoneda, N. (1998). Electrochemical Partial Fluorination of α, β -Unsaturated Esters. In: Torii, S. (eds) Novel Trends in Electroorganic Synthesis. Springer, Tokyo. https://doi.org/10.1007/978-4-431-65924-2_35
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DOI: https://doi.org/10.1007/978-4-431-65924-2_35
Publisher Name: Springer, Tokyo
Print ISBN: 978-4-431-65926-6
Online ISBN: 978-4-431-65924-2
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