Ring Opening Reaction of Phenylthio-Cyclopropanes by Anodic or Photochemical One-Electron Oxidation

  • Makoto Kimura
  • Hirotaka Kawai
  • Yasuhiko Sawaki


The ring opening of several phenylthiocyclopropane cation radicals generated electrochemically or photochemically has been studied with the product analysis and laser flash photolysis.


Cation Radical Ring Opening Ring Opening Reaction Laser Flash Photolysis Show Absorption Maximum 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


  1. 1).
    S. Torii, T. Inokuchi, and N. Takahashi, J. Org. Chem., 1978, 43, 5020.CrossRefGoogle Scholar
  2. 2).
    Y. Takemoto, T. Ohra, H. Koike, S. Furuse, C. Iwata, and H. Ohishi, J.Org.Chem., 1994, 59, 4727.CrossRefGoogle Scholar
  3. 3).
    A. Abe and A. Oku, J. Org. Chem., 1995, 60, 3065.CrossRefGoogle Scholar
  4. 4).
    M. Kimura, K. Kobayashi, Y. Yamamoto, and Y. Sawaki, Tetrahedron, 1996, 52, 4303.CrossRefGoogle Scholar
  5. 5).
    M. Kimura, H. Kawai, and Y. Sawaki, Electrochim. Acta, 1997, 42, 497.CrossRefGoogle Scholar
  6. 6).
    M. Braun and D. Seebach, Chem. Ber., 1976, 109, 669.CrossRefGoogle Scholar
  7. 7).
    S. A. Chaudhri, H. Mohan, E. Anklam, and K.-D. Asmus, J. Chem. Soc., Perkin 2, 1996, 383.Google Scholar

Copyright information

© Springer Japan 1998

Authors and Affiliations

  • Makoto Kimura
    • 1
  • Hirotaka Kawai
    • 1
  • Yasuhiko Sawaki
    • 1
  1. 1.Department of Applied Chemistry, Graduate School of EngineeringNagoya UniversityChikusa, NagoyaJapan

Personalised recommendations