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Modification of Cephalosporins Bearing Substituents at C(3’)Position via Electrogenerated Radical-Cation of Sulfide

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Novel Trends in Electroorganic Synthesis

Abstract

Chemoselective electrooxidations of 3-(3, 5-Di tert-butyl-4-methoxyphenylsulfenylmethyl)-△3-cephem la was successfully achieved to affored 3-methoxymethyl-△3-cephem 2 On the other hand, electrooxidations of 3-(3,5-dimethyl-4-methoxyphenylsulfenylmethyl)-△3-cephem 1b was afforded 3dimethoxymethyl-△3-cephem 3

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Authors and Affiliations

  1. Department of Applied Chemistry, Faculty of Engineering, Okayama University, Okayama 700, Japan

    Hideo Tanaka, Yoshihisa Tokumaru & Ken-ichi Fukui

  2. Ecole Normal Superieure, Labotatorire de Chimie, URA CNRS 1679, 24 rue Lhomond, 75231, Paris Cedex 05, France

    Christian Amatore & Anny Jutand

Authors
  1. Hideo Tanaka
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  2. Yoshihisa Tokumaru
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  3. Ken-ichi Fukui
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  4. Sigeru Torii
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  5. Christian Amatore
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  6. Anny Jutand
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Editor information

Editors and Affiliations

  1. Department of Applied Chemistry, Faculty of Engineering, Okayama University, 3-1-1 Tsushima-naka, 700-8530, Okayama, Japan

    Sigeru Torii

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© 1998 Springer Japan

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Cite this paper

Tanaka, H., Tokumaru, Y., Fukui, Ki., Torii, S., Amatore, C., Jutand, A. (1998). Modification of Cephalosporins Bearing Substituents at C(3’)Position via Electrogenerated Radical-Cation of Sulfide. In: Torii, S. (eds) Novel Trends in Electroorganic Synthesis. Springer, Tokyo. https://doi.org/10.1007/978-4-431-65924-2_20

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  • DOI: https://doi.org/10.1007/978-4-431-65924-2_20

  • Publisher Name: Springer, Tokyo

  • Print ISBN: 978-4-431-65926-6

  • Online ISBN: 978-4-431-65924-2

  • eBook Packages: Springer Book Archive

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