Abstract
Electron transfer reactions in condensed medium are accompanied by the reorganization of the nuclear system of a molecule (ΔG or ,) and solvation sheath (ΔG osolv ). In electrochemical reactions of organic and elementorganic compounds the spatial reorganisation of a molecule might happen ranging from minimal structural changes to the rapture (or formation) of a-bonds. The extreme case corresponds to the dissotiative (concert) mechanism of electron transfer, all other cases corresponds to the formation of anion-(or cation-) radical.
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References
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© 1998 Springer Japan
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Yanilkin, V.V., Mamedov, V.A., Berdnikov, E.A. (1998). Reversible Electron Transfer in Electroorganic Chemistry. In: Torii, S. (eds) Novel Trends in Electroorganic Synthesis. Springer, Tokyo. https://doi.org/10.1007/978-4-431-65924-2_138
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DOI: https://doi.org/10.1007/978-4-431-65924-2_138
Publisher Name: Springer, Tokyo
Print ISBN: 978-4-431-65926-6
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