Reversible Electron Transfer in Electroorganic Chemistry

  • Vitalii V. Yanilkin
  • Vakhid A. Mamedov
  • Eugene A. Berdnikov
Conference paper


Electron transfer reactions in condensed medium are accompanied by the reorganization of the nuclear system of a molecule (ΔG r o ,) and solvation sheath (ΔG solv o ). In electrochemical reactions of organic and elementorganic compounds the spatial reorganisation of a molecule might happen ranging from minimal structural changes to the rapture (or formation) of a-bonds. The extreme case corresponds to the dissotiative (concert) mechanism of electron transfer, all other cases corresponds to the formation of anion-(or cation-) radical.


Electron Transfer Electrochemical Reaction Electron Transfer Reaction Dissociate Electron Transfer Condensed Medium 
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Copyright information

© Springer Japan 1998

Authors and Affiliations

  • Vitalii V. Yanilkin
    • 1
  • Vakhid A. Mamedov
    • 1
  • Eugene A. Berdnikov
    • 2
  1. 1.A. E. Arbuzov Institute of Organic and Physical ChemistryRussian Academy of SciencesKazanRussia
  2. 2.Department of Organic ChemistryKazan State UniversityKazanRussia

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