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Reversible Electron Transfer in Electroorganic Chemistry

  • Vitalii V. Yanilkin
  • Vakhid A. Mamedov
  • Eugene A. Berdnikov
Conference paper

Abstract

Electron transfer reactions in condensed medium are accompanied by the reorganization of the nuclear system of a molecule (ΔG r o ,) and solvation sheath (ΔG solv o ). In electrochemical reactions of organic and elementorganic compounds the spatial reorganisation of a molecule might happen ranging from minimal structural changes to the rapture (or formation) of a-bonds. The extreme case corresponds to the dissotiative (concert) mechanism of electron transfer, all other cases corresponds to the formation of anion-(or cation-) radical.

Keywords

Electron Transfer Electrochemical Reaction Electron Transfer Reaction Dissociate Electron Transfer Condensed Medium 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

References

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    Krischtalik L.I. Electrodnie reactii, Mechanism elementarnogo akta. M.: Nauka, 1979.Google Scholar
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    Trasatti S. In: Comprehensive treaties of electrochemistry. Ed. by Bockris J.O’M., Conway B.E., Yeager E.V. 1.New York: Plenum Press. 45 (1980).Google Scholar
  3. 3.
    Zverev V.V., Yanilkin V.V., Gromakov V.S., Mironov V.F. Abstr. of XI Inter. Confer. on Chemistry of Phosphorus Compounds. Kazan, Russia. 216 (1996).Google Scholar

Copyright information

© Springer Japan 1998

Authors and Affiliations

  • Vitalii V. Yanilkin
    • 1
  • Vakhid A. Mamedov
    • 1
  • Eugene A. Berdnikov
    • 2
  1. 1.A. E. Arbuzov Institute of Organic and Physical ChemistryRussian Academy of SciencesKazanRussia
  2. 2.Department of Organic ChemistryKazan State UniversityKazanRussia

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