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Stereoselectivity in the Electroreductive Syntheses with Aryl and Alkenyl Halides Catalyzed by Nickel Complexes

  • Muriel Durandetti
  • Sylvie Condon-Gueugnot
  • Jacques Perichon
  • Jean-Yves Nedelec
Conference paper

Abstract

The nickel-catalyzed electroreductive coupling between aryl halides and 2-chloropropionic acid derivatives bearing chiral auxiliaries leads to chiral 2-arylpropionic acids with high enantiomeric excesses. The electrochemical alkenylation of activated olefins catalyzed by nickel complexes occurs with complete transfer of the streochemistry of the starting alkenyl halide onto the product.

Keywords

Nickel Complex Aryl Halide Complete Transfer Chiral Auxiliary Sacrificial Anode 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1).
    M. Durandetti, S.Sibille, J.Y. Nédélec, J. Périchon, J. Org . Chem. 1996, 61, 1748.CrossRefGoogle Scholar
  2. 2).
    M. Durandetti, J. Périchon, J.Y. Nédélec, J.Org.Chem., submitted.Google Scholar
  3. 3).
    S. Condon- Gueugnot, D. Dupré, J. Y. Nédélec, J. Périchon, Synthesis, in press.Google Scholar

Copyright information

© Springer Japan 1998

Authors and Affiliations

  • Muriel Durandetti
    • 1
  • Sylvie Condon-Gueugnot
    • 1
  • Jacques Perichon
    • 1
  • Jean-Yves Nedelec
    • 1
  1. 1.Laboratoire d’Electrochimie, Catalyse, et Synthèse OrganiqueThiaisFrance

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