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Electrochemical Reduction of Some [(η5-Cyclopentadienyl) (η6-Arene) Iron(II)][PF6] Complexes Bearing an Imine or a Nitrone Function in Benzylic Position of the Arene Ligand

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Novel Trends in Electroorganic Synthesis

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Abstract

We report the selective electrochemical reduction of some mixtures of [(η5-Cp) (η6-benzophenone-N-(aryl)nitrone) Fe]+ and [(n5-Cp) (n6-benzophenone anil) Fe]+ complexes into the corresponding [η5-Cp) (η6-α-(arylamino)diphenylmethane) Fe]+ cations. In a similar manner, various [(η5-Cp) (η6-9-(arylamino)fluorene) Fe]+ cations are synthesized from the corresponding [((η5-Cp) ((η6-fluorenone anil) Fe]+ derivatives. The electrochemical process allows the simultaneous reduction of both nitrone and imine functions with preservation of the organometallic moiety.

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Authors and Affiliations

  1. Laboratoire:“Electrochimie et Organométalliques”, UMR CNRS N°6509, Université de Rennes 1, Campus de Beaulieu, F-35042, Rennes Cedex, France

    Fabrice Pierre & Claude Moinet

Authors
  1. Fabrice Pierre
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  2. Claude Moinet
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Editor information

Editors and Affiliations

  1. Department of Applied Chemistry, Faculty of Engineering, Okayama University, 3-1-1 Tsushima-naka, 700-8530, Okayama, Japan

    Sigeru Torii

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© 1998 Springer Japan

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Pierre, F., Moinet, C. (1998). Electrochemical Reduction of Some [(η5-Cyclopentadienyl) (η6-Arene) Iron(II)][PF6] Complexes Bearing an Imine or a Nitrone Function in Benzylic Position of the Arene Ligand. In: Torii, S. (eds) Novel Trends in Electroorganic Synthesis. Springer, Tokyo. https://doi.org/10.1007/978-4-431-65924-2_116

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  • DOI: https://doi.org/10.1007/978-4-431-65924-2_116

  • Publisher Name: Springer, Tokyo

  • Print ISBN: 978-4-431-65926-6

  • Online ISBN: 978-4-431-65924-2

  • eBook Packages: Springer Book Archive

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