Palladium-Catalyzed Carboxylation of Vinyl Triflates. Electrosynthesis of α,β-Unsaturated Carboxylic Acids

  • Anny Jutand
  • Serge Negri
Conference paper


The palladium-catalyzed electrocarboxylation of vinyl triflates affords α,β-unsaturated carboxylic acids. The reactivity of vinyl triflates has been reversed in the presence of an electron source, since they now react with electrophiles such as CO2.


Carbon Dioxide Electron Transfer Carboxylic Acid Catalytic Amount Quantitative Yield 
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  1. 1).
    A. Jutand, and S. Négri, Synlett, 1997, 719.Google Scholar

Copyright information

© Springer Japan 1998

Authors and Affiliations

  • Anny Jutand
    • 1
  • Serge Negri
    • 1
  1. 1.Ecole Normale Supérieure, Département de ChimieCNRS URA 1679Paris Cedex 5France

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