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Recent Progress in the Electrochemical Synthesis of Polysilanes

  • Shigenori Kashimura
Conference paper

Abstract

Polymers containing silicon in the main chain have attracted considerable attention due to their usefulness as the precursors for thermally stable ceramics or materials for microlithography, and also due to their potentiality in the preparation of new types of material showing conducting, photoconducting, or nonlinear optical property. One of the most important innovation required in this field is the introduction of suitable functional groups into the polymer since the property of silicon containing polymers must remarkably be modified by such functional groups. We have recently found that the electroreduction ofchlorosilanes with Mg electrodes is highly useful for the practical method for the synthesis of polysilane (PS) high polymers (Scheme 1).1,2

Keywords

Alkyl Group Nonlinear Optical Property High Polymer Grignard Reagent Important Innovation 
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References

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    Kashimura, M. Ishifune, H. Murase, R. Nishida, and T. Shono, J. Org. Chem, 62, in press (1997).Google Scholar
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    Kashimura, M. Ishifune, H. Murase, R. Nishida, S.Kawasaki, and T. Shono, Tetrahedron Lett, 38, 4607 (1997).CrossRefGoogle Scholar

Copyright information

© Springer Japan 1998

Authors and Affiliations

  • Shigenori Kashimura
    • 1
  1. 1.Department of Metallurgy, Faculty of Science and EngineeringKin-dai UniversityHigashiosaka 577Japan

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