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Sum Frequency Generation (SFG)

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Molecular Soft-Interface Science

Abstract

Sum frequency generation (SFG) vibrational spectroscopy has been used to study molecular structures at surfaces and interfaces [1,2,3,4,5,6,7]. To obtain SFG signals, centrosymmetry of the system must be broken. This condition can be satisfied only at interfaces, leading to an SFG signal that is highly interface specific.

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References

  1. Zhu XD, Suhr H, Shen YR (1987) Surface vibrational spectroscopy by infrared-visible sum frequency generation. Phys Rev B 35(6):3047–3050. https://doi.org/10.1103/PhysRevB.35.3047

    Article  CAS  Google Scholar 

  2. Shen YR (1989) Surface-properties probed by 2nd-harmonic and sum-frequency generation. Nature 337(6207):519–525. https://doi.org/10.1038/337519a0

    Article  CAS  Google Scholar 

  3. Zhuang X, Miranda PB, Kim D, Shen YR (1999) Mapping molecular orientation and conformation at interfaces by surface nonlinear optics. Phys Rev B 59(19):12632–12640. https://doi.org/10.1103/PhysRevB.59.12632

    Article  CAS  Google Scholar 

  4. Chen Z, Shen YR, Somorjai GA (2002) Studies of polymer surfaces by sum frequency generation vibrational spectroscopy. Annu Rev Phys Chem 53:437–465. https://doi.org/10.1146/annurev.physchem.53.091801.115126

    Article  CAS  Google Scholar 

  5. Richmond GL (2002) Molecular bonding and interactions at aqueous surfaces as probed by vibrational sum frequency spectroscopy. Chem Rev 102(8):2693–2724. https://doi.org/10.1021/cr0006876

    Article  CAS  Google Scholar 

  6. Chen Z (2007) Understanding surfaces and buried interfaces of polymer materials at the molecular level using sum frequency generation vibrational spectroscopy. Polym Int 56(5):577–587. https://doi.org/10.1002/pi.2201

    Article  CAS  Google Scholar 

  7. Lu X, Shephard N, Han J, Xue G, Chen Z (2008) Probing molecular structures of polymer/metal interfaces by sum frequency generation vibrational spectroscopy. Macromolecules 41(22):8770–8777. https://doi.org/10.1021/ma801680f

    Article  CAS  Google Scholar 

  8. Wilks PA (1962) Infrared analysis by attenuated total reflectance. Spectrochim Acta 18(6):884

    Google Scholar 

  9. Chen YJ, Chen WP, Burstein E (1976) Surface-electromagnetic-wave-enhanced Raman-scattering by overlayers on metals. Phys Rev Lett 36(20):1207–1210. https://doi.org/10.1103/PhysRevLett.36.1207

    Article  CAS  Google Scholar 

  10. Noguchi H, Hiroshi M, Tominaga T, Gong JP, Osada Y, Uosaki K (2008) Interfacial water structure at polymer gel/quartz interfaces investigated by sum frequency generation spectroscopy. PCCP 10(32):4987–4993. https://doi.org/10.1039/b807297n

    Article  CAS  Google Scholar 

  11. Tateishi Y, Kai N, Noguchi H, Uosaki K, Nagamura T, Tanaka K (2010) Local conformation of poly(methyl methacrylate) at nitrogen and water interfaces. Polym Chem 1(3):303–311. https://doi.org/10.1039/b9py00227h

    Article  CAS  Google Scholar 

  12. Bellamy LJ (1975) The infra-red spectra of complex molecules, 3d edn. Chapman and Hall, Wiley, London, New York

    Book  Google Scholar 

  13. Hirose C, Akamatsu N, Domen K (1992) Formulas for the analysis of the surface SFG spectrum and transformation coefficients of cartesian SFG tensor components. Appl Spectrosc 46(6):1051–1072. https://doi.org/10.1366/0003702924124385

    Article  Google Scholar 

  14. Hirose C, Akamatsu N, Domen K (1992) Formulas for the analysis of surface sum-frequency generation spectrum by CH stretching modes of methyl and methylene groups. J Chem Phys 96(2):997–1004. https://doi.org/10.1063/1.462120

    Article  CAS  Google Scholar 

  15. Akamatsu N, Domen K, Hirose C (1993) SFG study of 2-dimensional orientation of surface methyl-groups on cadmium arachidate Langmuir-Blodgett-films. J Phys Chem 97(39):10070–10075. https://doi.org/10.1021/j100141a029

    Article  CAS  Google Scholar 

  16. Hirose C, Yamamoto H, Akamatsu N, Domen K (1993) Orientation analysis by simulation of vibrational sum-frequency generation spectrum - CH stretching bands of the methyl-group. J Phys Chem 97(39):10064–10069. https://doi.org/10.1021/j100141a028

    Article  CAS  Google Scholar 

  17. Watanabe N, Yamamoto H, Wada A, Domen K, Hirose C, Ohtake T, Mino N (1994) Vibrational sum-frequency generation (VSFG) spectra of N-alkyltrichlorosilanes chemisorbed on quartz plate. Spectrochim Acta Part A Mol Biomol Spectrosc 50(8–9):1529–1537. https://doi.org/10.1016/0584-8539(94)e0064-h

    Article  Google Scholar 

  18. Wang J, Chen CY, Buck SM, Chen Z (2001) Molecular chemical structure on poly(methyl methacrylate) (PMMA) surface studied by sum frequency generation (SFG) vibrational spectroscopy. J Phys Chem B 105(48):12118–12125. https://doi.org/10.1021/jp013161d

    Article  CAS  Google Scholar 

  19. Simpson GJ, Rowlen KL (1999) An SHG magic angle: dependence of second harmonic generation orientation measurements on the width of the orientation distribution. J Am Chem Soc 121(11):2635–2636. https://doi.org/10.1021/ja983683f

    Article  CAS  Google Scholar 

  20. Wei X, Zhuang XW, Hong SC, Goto T, Shen YR (1999) Sum-frequency vibrational spectroscopic study of a rubbed polymer surface. Phys Rev Lett 82(21):4256–4259. https://doi.org/10.1103/PhysRevLett.82.4256

    Article  CAS  Google Scholar 

  21. Ye S, Morita S, Li GF, Noda H, Tanaka M, Uosaki K, Osawa M (2003) Structural changes in poly (2-methoxyethyl acrylate) thin films induced by absorption of bisphenol A. An infrared and sum frequency generation (SFG) study. Macromolecules 36 (15):5694–5703. https://doi.org/10.1021/ma026007d

    Article  CAS  Google Scholar 

  22. Fleischer CA, Morales AR, Koberstein JT (1994) Interfacial modification through end group complexation in polymer blends. Macromolecules 27(2):379–385. https://doi.org/10.1021/ma00080a010

    Article  CAS  Google Scholar 

  23. Li GF, Ye S, Morita S, Nishida T, Osawa M (2004) Hydrogen bonding on the surface of poly(2-methoxyethyl acrylate). J Am Chem Soc 126(39):12198–12199. https://doi.org/10.1021/ja046183x

    Article  CAS  Google Scholar 

  24. Chen CY, Clarke ML, Wang J, Chen Z (2005) Comparison of surface structures of poly (ethyl methacrylate) and poly (ethyl acrylate) in different chemical environments. PCCP 7(11):2357–2363. https://doi.org/10.1039/b501910a

    Article  CAS  Google Scholar 

  25. Wan L-S, Huang X-J, Xu Z-K (2007) Diffusion and structure of water in polymers containing N-vinyl-2-pyrrolidone. J Phys Chem B 111(5):922–928. https://doi.org/10.1021/jp065152g

    Article  CAS  Google Scholar 

  26. Du Q, Superfine R, Freysz E, Shen YR (1993) Vibrational spectroscopy of water at the vapor water interface. Phys Rev Lett 70(15):2313–2316. https://doi.org/10.1103/PhysRevLett.70.2313

    Article  CAS  Google Scholar 

  27. Du Q, Freysz E, Shen YR (1994) Surface vibrational spectroscopic studies of hydrogen-bonding and hydrophobicity. Science 264(5160):826–828. https://doi.org/10.1126/science.264.5160.826

    Article  CAS  Google Scholar 

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Correspondence to Keiji Tanaka .

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Kawaguchi, D., Tanaka, K. (2019). Sum Frequency Generation (SFG). In: Maeda, M., Takahara, A., Kitano, H., Yamaoka, T., Miura, Y. (eds) Molecular Soft-Interface Science. Springer, Tokyo. https://doi.org/10.1007/978-4-431-56877-3_5

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