Abstract
This chapter briefly reviews the use of inorganic nanosheets for a conversion of photoenergy into other forms of energies such as chemical, electrical, mechanical, and photoenergy. Some representative works have achieved efficient photoenergy conversion as well as the effective utilization of unique advantages of two-dimensional nanosheets such as highly crystalline two-dimensional surfaces, high aspect ratios, and the separation of the front and back sides by atomically thin surfaces. Since the modern world is highly reliant on energies in various forms, novel and more efficient energy conversion systems using inorganic nanosheets are desired toward future sustainable society.
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References
Fujishima A, Honda K (1972) Electrochemical photolysis of water at a semiconductor electrode. Nature 238:37–38
Osterloh FE (2013) Inorganic nanostructures for photoelectrochemical and photocatalytic water splitting. Chem Soc Rev 42:2294–2320
Wang L, Sasaki T (2014) Titanium oxide nanosheets: graphene analogues with versatile functionalities. Chem Rev 114:9455–9486
Paek S-M, Jung H, Lee Y-J, Park M, Hwang S-J, Choy J-H (2006) Exfoliation and reassembling route to mesoporous titania nanohybrids. Chem Mater 18:1134–1140
Liu G, Wang L, Sun C, Chen Z, Yan X, Cheng L et al (2009) Nitrogen-doped titania nanosheets towards visible light response. Chem Commun 1383–1383
Allen MR, Thibert A, Sabio EM, Browning ND, Larsen DS, Osterloh FE (2010) Evolution of physical and photocatalytic properties in the layered titanates A2Ti4O9 (A = K, H) and in nanosheets derived by chemical exfoliation. Chem Mater 22:1220–1228
Domen K, Kudo A, Shibata M, Tanaka A, Maruya KI, Onishi T (1986) Novel photocatalysts, ion-exchanged K4Nb6O17, with a layer structure. J Chem Soc Chem Commun 1706–1712
Sayama K, Tanaka A, Domen K (1991) Photocatalytic decomposition of water over platinum-intercalated potassium niobate (K4Nb6O17). J Phys Chem 95:1345–1348
Compton OC, Mullet CH, Chiang S, Osterloh FE (2008) A building block approach to photochemical water-splitting catalysts based on layered niobate nanosheets. J Phys Chem C 112:6202–6208
Tan B, Wu Y (2006) Dye-sensitized solar cells based on anatase TiO2 nanoparticle/nanowire composites. J Phys Chem B 110:15932–15938
Akatsuka K, Ebina Y, Muramatsu M, Sato T, Hester H, Kumaresan D et al (2007) Photoelectrochemical properties of alternating multilayer films composed of titania nanosheets and Zn porphyrin. Langmuir 23:6730–6736
Akatsuka K, Takanashi G, Ebina Y, Haga M-A, Sasaki T (2012) Electronic band structure of exfoliated titanium- and/or niobium-based oxide nanosheets probed by electrochemical and photoelectrochemical measurements. J Phys Chem C 116:12426–12433
Irie M, Kobatake S, Horichi M (2001) Reversible surface morphology changes of a photochromic diarylethene single crystal by photoirradiation. Science 291:1769–1772
Yu Y, Nakano M, Ikeda T (2003) Directed bending of a polymer film by light. Nature 425:145–145
Nabetani Y, Takamura H, Hayasaka Y, Shimada T, Takagi S, Tachibana H et al (2011) A photoactivated artificial muscle model unit: reversible, photoinduced sliding of nanosheets. J Am Chem Soc 133:17130–17133
Nabetani Y, Takamura H, Hayasaka Y, Sasamoto S, Tanamura Y, Shimada T et al (2013) An artificial muscle model unit based on inorganic nanosheet sliding by photochemical reaction. Nanoscale 5:3182
Perrin JB (1924) Fluorescence et lois générales relatives aux vitesses de réaction. Comptes rendus hebdomadaires des séances de l’Académie des Sci 178:1401–1406
Förster Th (1946) Energiewanderung und Fluoreszenz. Naturwissenschaften 6:166–175
Förster Th (1948) Zwischenmolekulare Energiewanderung und Fluoreszenz. Ann Phys 1–2:55–75
Baumann J, Fayer MD (1986) Excitation transfer in disordered two-dimensional and anisotropic three-dimensional systems: effects of spatial geometry on time-resolved observables. J Chem Phys 85:4087
Kelley RF, Lee SJ, Wilson TM, Nakamura Y, Tiede DM, Osuka A et al (2008) Intramolecular energy transfer within butadiyne-linked chlorophyll and porphyrin dimer-faced, self-assembled prisms. J Am Chem Soc 130:4277–4284
Hoffman JB, Choi H, Kamat PV (2014) Size-dependent energy transfer pathways in cdse quantum dot-squaraine light-harvesting assemblies: förster versus dexter. J Phys Chem C 118:18453–18461
Zhang X, Marocico CA, Lunz M, Gerard VA, Gun’ko YK, Lesnyak V et al (2014) Experimental and theoretical investigation of the distance dependence of localized surface plasmon coupled förster resonance energy transfer. ACS Nano 8:1273–1283
Becker K, Lupton JM, Müller J, Rogach AL, Talapin DV, Weller H et al (2006) Electrical control of Förster energy transfer. Nat Mater 5:777–781
Inagaki S, Ohtani O, Goto Y, Okamoto K, Ikai M, Yamanaka K-I et al (2009) Light harvesting by a periodic mesoporous organosilica chromophore. Angew Chem Int Ed 48:4042–4046
Hildebrandt N, Wegner KD, Algar WR (2014) Luminescent terbium complexes: superior Förster resonance energy transfer donors for flexible and sensitive multiplexed biosensing. Coord Chem Rev 273–274:125–138
Frischmann PD, Mahata K, Würthner F (2013) Powering the future of molecular artificial photosynthesis with light-harvesting metallosupramolecular dye assemblies. Chem Soc Rev 42:1847–1870
Silvi S, Credi A (2015) Luminescent sensors based on quantum dot-molecule conjugates. Chem Soc Rev 44:4275–4289
McDermott G, Prince SM, Freer AA, Hawthornthwaite-Lawless AM, Papiz MZ, Cogdell RJ et al (1995) Crystal structure of an integral membrane light-harvesting complex from photosynthetic bacteria. Nature 374:517–521
Takagi S, Tryk DA, Inoue H (2002) Photochemical energy transfer of cationic porphyrin complexes on clay surface. J Phys Chem B 106:5455–5460
Ishida Y, Shimada T, Takagi S (2014) Surface-fixation induced emission of porphyrazine dye by a complexation with inorganic nanosheets. J Phys Chem C 118:20466–20471
Villemure G, Detellier C, Szabo AG (1986) Fluorescence of clay-intercalated methylviologen. J Am Chem Soc 108:4658–4659
Shichi T, Takagi K (2000) Clay minerals as photochemical reaction fields. J Photochem Photobiol C Photochem Rev 1:113–130
Bujdák J (2006) Effect of the layer charge of clay minerals on optical properties of organic dyes. A review. Appl Clay Sci 34:58–73
Ghosh PK, Bard AJ (1984) Photochemistry of tris (2, 2′-bipyridyl) ruthenium (II) in colloidal clay suspensions. J Phys Chem 88:5519–5526
Takagi S, Shimada T, Eguchi M, Yui T, Yoshida H, Tryk DA et al (2002) High-density adsorption of cationic porphyrins on clay layer surfaces without aggregation: the size-matching effect. Langmuir 18:2265–2272
Takagi S, Shimada T, Ishida Y, Fujimura T, Masui D, Tachibana H et al (2013) Size-matching effect on inorganic nanosheets: control of distance, alignment, and orientation of molecular adsorption as a bottom-up methodology for nanomaterials. Langmuir 29:2108–2119
Ishida Y, Shimada T, Masui D, Tachibana H, Inoue H, Takagi S (2011) Efficient excited energy transfer reaction in clay/porphyrin complex toward an artificial light-harvesting system. J Am Chem Soc 133:14280–14286
Ishida Y, Kulasekharan R, Shimada T, Ramamurthy V, Takagi S (2014) Supramolecular-surface photochemistry: supramolecular assembly organized on a clay surface facilitates energy transfer between an encapsulated donor and a free acceptor. J Phys Chem C 118:10198–10203
Ishida Y, Kulasekharan R, Shimada T, Takagi S, Ramamurthy V (2013) Efficient singlet-singlet energy transfer in a novel host-guest assembly composed of an organic cavitand, aromatic molecules, and a clay nanosheet. Langmuir 29:1748–1753
Kulasekharan R, Ramamurthy V (2011) New water-soluble organic capsules are effective in controlling excited-state processes of guest molecules. Org Lett 13:5092–5095
Ishida Y, Shimada T, Takagi S (2013) Artificial light-harvesting model in a self-assembly composed of cationic dyes and inorganic nanosheet. J Phys Chem C 117:9154–9163
Ishida Y, Shimada T, Tachibana H, Inoue H, Takagi S (2012) Regulation of the collisional self-quenching of fluorescence in clay/porphyrin complex by strong host-guest interaction. J Phys Chem A 116:12065–12072
Ishida Y, Fujimura T, Masui D, Shimada T, Tachibana H, Inoue H et al (2011) What lowers the efficiency of an energy transfer reaction between porphyrin dyes on clay surface? Clay Sci 15:169–174
Rao CNR, Sood AK, Subrahmanyam KS, Govindaraj A (2009) Graphene: the new two-dimensional nanomaterial. Angew Chem Int Ed 48:7752–7777
Morales-Narváez E, Merkoçi A (2012) Graphene oxide as an optical biosensing platform. Adv Mater 24:3298–3308
Piao Y, Liu F, Seo TS (2011) The photoluminescent graphene oxide serves as an acceptor rather than a donor in the fluorescence resonance energy transfer pair of Cy3.5-graphene oxide. Chem Commun 47:12149–12151
Liu F, Choi JY, Seo TS (2010) Graphene oxide arrays for detecting specific DNA hybridization by fluorescence resonance energy transfer. Biosens Bioelectron 25:2361–2365
Balapanuru J, Yang J-X, Xiao S, Bao Q, Jahan M, Polavarapu L et al (2010) A graphene oxide-organic dye ionic complex with DNA-sensing and optical-limiting properties. Angew Chem Int Ed 49:6549–6553
Dong H, Gao W, Yan F, Ji H, Ju H (2010) Fluorescence resonance energy transfer between quantum dots and graphene oxide for sensing biomolecules. Anal Chem 82:5511–5517
Zhu C, Zeng Z, Li H, Li F, Fan C, Zhang H (2013) Single-layer MoS2-based nanoprobes for homogeneous detection of biomolecules. J Am Chem Soc 135:5998–6001
Ha HD, Han DJ, Choi JS, Park M, Seo TS (2014) Dual role of blue luminescent MoS2 quantum dots in fluorescence resonance energy transfer phenomenon. Small 10:3858–3862
Scheuschner N, Ochedowski O, Kaulitz A-M, Gillen R, Schleberger M, Maultzsch J (2014) Photoluminescence of freestanding single- and few-layer MoS2. Phys Rev B 89:125406
Prins F, Goodman AJ, Tisdale WA (2014) Reduced dielectric screening and enhanced energy transfer in single- and few-layer MoS2. Nano Lett 14:6087–6091
Wang Q, Wang W, Lei J, Xu N, Gao F, Ju H (2013) Fluorescence quenching of carbon nitride nanosheet through its interaction with DNA for versatile fluorescence sensing. Anal Chem 85:12182–12188
Song L, Ci L, Lu H, Sorokin PB, Jin C, Ni J et al (2010) Large scale growth and characterization of atomic hexagonal boron nitride layers. Nano Lett 10:3209–3215
Sakamoto J, van Heijst J, Lukin O, Schlüter AD (2009) Two-dimensional polymers: just a dream of synthetic chemists? Angew Chem Int Ed 48:1030–1069
Sakamoto R, Takada K, Sun X, Pal T, Tsukamoto T, Phua EJH et al (2016) The coordination nanosheet (CONASH). Coordin Chem Rev 320–321:118–128
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Ishida, Y., Takagi, S. (2017). Photoenergy Conversion. In: Nakato, T., Kawamata, J., Takagi, S. (eds) Inorganic Nanosheets and Nanosheet-Based Materials. Nanostructure Science and Technology. Springer, Tokyo. https://doi.org/10.1007/978-4-431-56496-6_14
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DOI: https://doi.org/10.1007/978-4-431-56496-6_14
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