Abstract
This describes fuel cell-based power generation using biofuels. After giving an overview of biofuels which are available, such as biogas, bioethanol, and biodiesel oil, hydrogen production and power generation with solid oxide fuel cells are explained based on cell performance data. Technological issues such as carbon deposition and impurity poisoning are discussed.
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References
Divya D, Gopinath LR, Christy PM (2015) A review on current aspects and diverse prospects for enhancing biogas production in sustainble means. Renew Sustain Energy Rev 42:690–699
Alves HJ (2013) Overview of hydrogen production technologies from biogas and the applications in fuel cells. Int J Hydrogen Energy 38:5215–5225
Magomnang AASM, Villanueva EP (2014) Removal of hydrogen sulfide from biogas using dry desulfurization systems. In: Proceedings of international conference on agricultural, environmental and biological sciences, Phuket, Thailand, pp 65–68
Wyman CE (1996) Handbook of bioethanol. Taylor & Francis, London, pp 4–5
Nahar G, Dupont V (2012) Hydrogen via steam reforming of liquid biofeedstock. Biofuels 3:167–191
Leung DYC, Wu X, Leung MKH (2010) A review recent advancement in catalytic materials for biodiesel production. Appl Energy 87:1083–1095
Karmakar A, Karmakar S, Mukherjee S (2010) Properties of various plants and animals feedstocks for biodiesel production. Bioresour Technol 101:7201–7210
Nahar GA (2010) Hydrogen rich gas production by the autothermal reforming of biodiesel (FAME) for utilization in the solid-oxide fuel cells: a thermodynamic analysis. Int J Hydrogen Energy 35:8891–8911
Hoekman SK, Broch A, Robbins C, Ceniceros E, Natarajan M (2012) Review of biodiesel composition, properties, and specifications. Renew Sustain Energy Rev 16:143–169
Miyachi K, Miyagawa M, Katagiri M, Kanda N, Norinaga K (2010) Identification of tar chemical species obtained from pyrolysis of grass biomass. Mitsui Zosen Tech Rev 199:47–53
Effendi A, Hellgardt K, Zhang Z-G, Yoshida T (2005) Optimising H2 production from model biogas via combined steam reforming and CO shift reactions. Fuel 84:869–874
Muradov N, Smith F (2008) Thermocatalytic conversion of landfill gas and biogas to fuels. Energy Fuels 22:2053–2060
Zhang B, Tang X, Li Y, Cai Y, Xu Y, Shen W (2006) Steam reforming of bio-ethanol for the production of hydrogen over ceria-supported Co, Ir and Ni catalysts. Catal Commun 7:367–372
Mondal T, Pant KK, Dalai AK (2015) Catalytic oxidative steam reforming of bio-ethanol for hydrogen production over Rh promoted Ni/CeO2-ZrO2 catalyst. Int J Hydrogen Energy 40:2529–2544
Basagiannis AC, Verykios XE (2007) Steam reforming of the aqueous fraction of bio-oil over structured Ru/MgO/Al2O3 catalysts. Catal Today 127:256–264
Vagia EC, Lemonidou AA (2008) Hydrogen production via steam reforming of bio-oil components over calcium aluminate supported nickel and noble metal catalysts. Appl Catal A Gen 351:111–121
Laosiripojana N, Kiatkittipong W, Charojrochkul S, Assabumrungrat S (2010) Effects of support and co-fed elements on steam reforming of palm fatty acid distillate (PFAD) over Rh-based catalysts. Appl Catal A Gen 383:50–57
Shiratori Y, Tran TQ, Umemura Y, Kitaoka T, Sasaki K (2013) Paper-structured catalyst for the steam reforming of biodiesel fuel. Int J Hydrogen Energy 38:11278–11287
Lercher JA, Bitter JH, Hally W, Niessen W, Seshan K (1996) Design of stable catalysts for methane-carbon dioxide reforming. Stud Surf Sci Catal 101:463–472
Nakayama T, Ichikuni N, Sato S, Nozaki F (1997) Ni/MgO catalyst prepared using citric acid for hydrogenation of carbon dioxide. Appl Catal A Gen 158:185–199
Tomishige K, Chen Y, Fujimoto K (1999) Studies on carbon deposition in CO2 reforming of CH4 over nickel-magnesia solid solution catalysts. J Catal 181:91–103
Hou Z, Yashima T (2004) Meso-porous Ni/Mg/Al catalysts for methane reforming with CO2. Appl Catal A Gen 261:205–209
Sun J, Qiu XP, Wu F, Zhu WT (2005) H2 from steam reforming of ethanol at low temperature over Ni/Y2O3, Ni/La2O3 and Ni/Al2O3 catalysts for fuel-cell application. Int J Hydrogen Energy 30:437–445
Urasaki K, Sekine Y, Kawabe S, Kikuchi E, Matsukata M (2005) Catalytic activities and coking resistance of Ni/perovskites in steam reforming of methane. Appl Catal A Gen 286:23–29
Narula CK, Haack LP, Chun W, Jen HW, Graham GW (1999) Single-phase PrOy-ZrO2 materials and their oxygen storage capacity: a comparison with single-phase CeO2-ZrO2, PrOy-CeO2, and PrOy-CeO2-ZrO2 materials. J Phys Chem B 103:3634–3639
Takeguchi T, Furukawa SN, Inoue M (2001) Hydrogen spillover from NiO to the large surface Area CeO2–ZrO2 solid solutions and activity of the NiO/CeO2–ZrO2 catalysts for partial oxidation of methane. J Catal 202:14–24
Srinivas D, Satyanarayana CVV, Potdar HS, Ratnasamy P (2003) Structural studies on NiO-CeO2-ZrO2 catalysts for steam reforming of ethanol. Appl Catal A Gen 246:323–334
Shotipruk A, Assabumrungrat S, Pavasant P, Laosiripojana N (2009) Reactivity of CeO2 and Ce–ZrO2 toward steam reforming of palm fatty acid distilled (PFAD) with co-fed oxygen and hydrogen. Chem Eng Sci 64:459–466
Shishido T, Sukenobu M, Morioka H, Furukawa R, Shirahase H, Takehira K (2001) CO2 reforming of CH4 over Ni/Mg-Al oxide catalysts prepared by solid phase crystallization method from Mg-Al hydrotalcite-like precursors. Catal Lett 73:21–26
Li D, Wang L, Koike M, Nakagawa Y, Nakagawa Y, Tomishige K (2011) Steam reforming of tar from pyrolysis of biomass over Ni/Mg/Al catalysts prepared from hydrotalcite-like precursors. Appl Catal B Environ 102:528–538
Tran TQ, Kaida T, Sakamoto M, Sasaki K, Shiratori Y (2015) Effectiveness of paper-structured catalyst for the operation of biodiesel-fueled solid oxide fuel cell. J Power Sources 283:320–327
Horny C, Renken A, Kiwi-Minsker L (2007) Compact string reactor for autothermal hydrogen production. Catal Today 120:45–53
Twigg MV, Richadson JT (2007) Fundamentals and applications of structured ceramic foam catalysts. Ind Eng Chem Res 46:4166–4177
Nishihara H, Mukai SR, Yamashita D, Tamon H (2005) Ordered macroporous silica by ice templating. Chem Mater 17:683–689
Patcas FC, Garrido GI, Kraushaar-Czarnetzki B (2007) CO oxidation over structured carriers: a comparison of ceramic foams, honeycombs and beads. Chem Eng Sci 62:3984–3990
Fukahori S, Kitaoka T, Tomoda A, Suzuki R, Wariishi H (2006) Methanol steam reforming over paper-like composites of Cu/ZnO catalyst and ceramic fiber. Appl Catal A 300:155–161
Fukahori S, Koga H, Kitaoka T, Nakamura M, Wariishi H (2008) Steam reforming behavior of methanol using paper-structured catalysts: experimental and computational fluid dynamic analysis. Int J Hydrogen Energy 33:1661–1670
Koga H, Umemura Y, Ishihara H, Kitaoka T, Tomoda A, Suzuki R, Wariishi H (2009) Paper-structured fiber composites impregnated with platinum nanoparticles synthesized on a carbon fiber matrix for catalytic reduction of nitrogen oxides. Appl Catal B Environ 90:699–704
Ishihara H, Koga H, Kitaoka T, Wariishi H, Tomoda A, Suzuki R (2010) Paper-structured catalyst for catalytic NOx removal from combustion exhaust gas. Chem Eng Sci 65:208–213
Shiratori Y, Ogura T, Nakajima H, Sakamoto M, Takahashi Y, Wakita Y, Kitaoka T, Sasaki K (2013) Study on paper-structured catalyst for direct internal reforming SOFC fueled by the mixture of CH4 and CO2. J Hydrogen Energy 38:10542–10551
Wachsman ED, Marlowe CA, Lee KT (2012) Role of solid oxide fuel cells in a balanced energy strategy. Energy Environ Sci 5:5498–5509
Ge XM, Chan SH, Liu QL, Sun Q (2012) Solid oxide fuel cell anode materials for direct hydrogen carbon utilization. Adv Energy Mater 2:1156–1181
Liu J, Barnett SA (2003) Operation of anode-supported solid oxide fuel cells on methane and natural gas. Solid State Ionics 158(1–2):11–16
Liu J, Madsen BD, Ji Z, Barnett SA (2002) A fuel-flexible ceramic-based anode for solid oxide fuel cells. Electrochem Solid-State Lett 5:A122–A124
Iida T, Kawano M, Matsui T, Kikuchi R, Eguchi K (2007) Internal reforming of SOFCs: carbon deposition on fuel electrode and subsequent deterioration of cell. J Electrochem Soc 154(2):B234–B241
Kishimoto H, Yamaji K, Horita T, Xiong Y, Sakai N, Brito M, Yokokawa H (2007) Feasibility of liquid hydrocarbon fuels for SOFC with Ni-ScSZ anode. J Power Sources 172:67–71
Kim H, Park S, Vohs JM, Gorte RJ (2001) Direct oxidation of liquid fuels in a solid oxide fuel cell. J Electrochem Soc 148(7):A693–A695
Hou X, Marin-Flores O, Kwon BW, Kim J, Norton MG, Ha S (2014) Gasoline-fueled solid oxide fuel cell with high power density. J Power Sources 268:546–549
Zhou ZF, Gallo C, Pargue MB, Schobert H, Lvov SN (2004) Direct oxidation of jet fuels and Pennsylvania crude oil in a solid oxide fuel cell. J Power Sources 133:181–187
Shiratori Y, Oshima T, Sasaki K (2008) Feasibility of direct-biogas SOFC. Int J Hydrogen Energy 33:6316–6321
Shiratori Y, Ijichi T, Oshima T, Sasaki K (2010) Internal reforming SOFC running on biogas. Int J Hydrogen Energy 35:7905–7912
Tran TQ, Shiratori Y, Sasaki K (2013) Feasibility of palm-biodiesel fuel for a direct internal reforming solid oxide fuel cell. Int J Energy Res 37:609–616
Staniforth J, Kendall K (1998) Biogas powering a small tubular solid oxide fuel cell. J Power Sources 71:275–277
Staniforth J, Kendall K (2000) Cannock landfill gas powering a small tubular solid oxide fuel cell—a case study. J Power Sources 86:401–403
Staniforth J, Ormerod RM (2003) Running solid oxide fuel cells on biogas. Ionics 9:336–341
Nahar G, Kendall K (2011) Biodiesel formulations as fuel for internally reforming solid oxide fuel cell. Fuel Process Technol 92:1345–1354
Lanzini A, Leone P (2010) Experimental investigation of direct internal reforming of biogas in solid oxide fuel cells. J Power Sources 35:2463–2476
Guerra C, Lanzini A, Leone P, Santarelli M, Beretta D (2013) Experimental study of dry reforming of biogas in a tubular anode-supported solid oxide fuel cell. Int J Hydrogen Energy 38:10559–10566
Yentekakis IV (2006) Open- and closed-circuit study of an intermediate temperature SOFC directly fueled with simulated biogas mixtures. J Power Sources 160:422–425
Papadam T, Goula G, Yentekakis IV (2012) Long-term operation stability tests of intermediate and high temperature Ni-based anodes’ SOFCs directly fueled with simulated biogas mixtures. Int J Hydrogen Energy 37:16680–16685
Xu C, Zondlo JW, Gong M, Elizalde-Blancas F, Liu X, Celik IB (2010) Tolerance tests of H2S-laden biogas fuel on solid oxide fuel cells. J Power Sources 195:4583–4592
McPhee WAG, Boucher M, Stuart J, Parnas RS, Koslowske M, Tao T, Wilhite BA (2009) Demonstration of a liquid-tin anode solid-oxide fuel cell (LTA-SOFC) operating from biodiesel fuel. Energy Fuels 23:5036–5041
Wang F, Wang W, Ran R, Tade MO, Shao Z (2014) Alumina oxide as a dual-functional modifier of Ni-based anodes of solid oxide fuel cells for operating on simulated biogas. J Power Sources 268:787–793
Wang W, Su C, Ran R, Park HJ, Kwak C, Shao Z (2011) Physically mixed LiLaNi-Al2O3 and copper as conductive anode catalysts in a solid oxide fuel cell for methane internal reforming and partial oxidation. Int J Hydrogen Energy 36:5632–5643
Wang W, Ran R, Shao Z (2011) Combustion-synthesized Ru-Al2O3 composites as anode catalyst layer of a solid oxide fuel cell operating on methane. Int J Hydrogen Energy 36:755–764
Szymcewska D, Karcrewski J, Bochentyn B, Chrzan A, Gazda M, Jasinski P (2015) Investigation of catalytic layer on anode solid oxide fuel cells operating with synthetic biogas. Solid State Ionics 271:109–115
Assabumrungrat S, Laosiripojana N, Piroonlerkgul P (2006) Determination of the boundary of carbon formation for dry reforming of methane in a solid oxide fuel cell. J Power Sources 159:1274–1284
Takahashi Y, Shiratori Y, Furuta S, Sasaki K (2012) Thermo-mechanical reliability and catalytic activity of Ni-zirconia anode supports in internal reforming SOFC running on biogas. Solid State Ionics 225:113–117
Smith TR, Wood A, Birss VI (2009) Effect of hydrogen sulfide on the direct internal reforming of methane in solid oxide fuel cells. Appl Catal A 354:1–7
Silva ALD, Heck NC (2015) Oxide incorporation into Ni-based solid oxide fuel cell anodes for enhanced sulfur tolerance during operation on hydrogen or biogas fuels: a comprehensive thermodynamic study. Int J Hydrogen Energy 40:2334–2353
Zhan Z, Barnett SA (2005) An octane-fueled solid oxide fuel cell. Science 308:844–847
Shiratori Y, Ijichi T, Oshima T, Sasaki K (2009) Generation of electricity from organic bio-wastes using solid oxide fuel cell. ECS Trans 25:1051–1060
Liu JH, Fu XZ, Luo JL, Chuang KT, Sanger AR (2012) Application of BaTiO3 as anode materials for H2S-containing CH4 fueled solid oxide fuel cells. J Power Sources 213:69–77
Kim H, Lu C, Worrell WL, Vohs JM, Gorte RJ (2002) Cu-Ni cermet anodes for direct oxidation of methane in solid-oxide fuel cells. J Electrochem Soc 149:A247–A250
Singh A, Hill JM (2012) Carbon tolerance, electrochemical performance and stability of solid oxide fuel cells with Ni/yttria stabilized zirconia anodes impregnated with Sn and operated with methane. J Power Sources 214:185–194
ShiratoriY Tran TQ, Sasaki K (2013) Performance enhancement of biodiesel fueled SOFC using paper-structured catalyst. Int J Hydrogen Energy 38:9856–9866
Shiratori Y, Tran TQ, Takahashi Y, Sasaki K (2011) Application of biofuels to solid oxide fuel cell. ECS Trans 35:2641–2651
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Shiratori, Y., Tran, QT. (2016). Fuel Cells with Biofuels. In: Sasaki, K., Li, HW., Hayashi, A., Yamabe, J., Ogura, T., Lyth, S. (eds) Hydrogen Energy Engineering. Green Energy and Technology. Springer, Tokyo. https://doi.org/10.1007/978-4-431-56042-5_38
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DOI: https://doi.org/10.1007/978-4-431-56042-5_38
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