Abstract
This chapter describes syntheses methods, crystal structures, de-/re-hydrogenation properties as well as their improvement from both thermodynamic and kinetic aspects of typical non-interstitial hydrides, such as complex hydrides including alanates, amides and borohydrides, magnesium hydride, aluminum hydride and ammonia borane.
Keywords
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsReferences
Bogdanović B, Schwickardi M (1997) Ti-doped alkali metal aluminum hydrides as potential novel reversible hydrogen storage materials. J Alloys Compd 253–254:1–9
Fichtner M, Fuhr O, Kircher O (2003) Magnesium alanate-a material for reversible hydrogen storage. J Alloys Compd 356–357:418–422
Ashby EC, Brendel GJ, Redman HE (1963) Direct synthesis of complex metal hydrides. Inorg Chem 2:499–506
Sato T, Ikeda K, Li H-W, Yukawa H, Morinaga M, Orimo S (2009) Direct dry syntheses and thermal analyses of a series of aluminum complex hydrides. Mater Trans 50:182–186
Lauher JW, Dougherty D, Herley PJ (1979) Sodium tetrahydroaluminate. Acta Crystallogr B35:1454–1456
Hauback BC, Brinks HW, Jensen CM, Murphy K, Maeland AJJ (2003) Neutron diffraction structure determination of NaAlD4. J Alloys Compd 358:142–145
Bogdanović B, Brand RA, Marjanović A, Schwickardi M, Tölle J (2000) Metaldoped aluminium hydrides as potential new hydrogen storage materials. J Alloys Compd 302:36–58
Ashby EC, Kobetz P (1966) The direct synthesis of Na3AlH6. Inorg Chem 5:1615–1617
Dymova TN, Eliseeva NG, Bakum SI, Dergachev YM (1974) Direct synthesis of alkali metal aluminum hydrides in the melt. Dokl Akad Nauk SSSR 215:1369–1372
Block J, Gray AP (1965) The thermal decomposition of lithium aluminum hydride. Inorg Chem 4:304–305
Jang J-W, Shim J-H, Cho YW, Lee BJ (2006) Thermodynamic calculation of LiH ↔ Li3AlH6 ↔ LiAlH4 reactions. J Alloys Compd 420:286–290
Wang J, Ebner AD, Ritter JA (2006) Physiochemical pathway for cyclic dehydrogenation and rehydrogenation of LiAlH4. J Am Chem Soc 128:5949–5954
Anton DL (2003) Hydrogen desorption kinetics in transition metal modified NaAlH4. J Alloys Compd 356–357:400–404
Gross KJ, Majzoub EH, Spangler SW (2003) The effects of titanium precursors on hydriding properties of alanates. J Alloys Compd 356–357:423–428
Graetz J, Reilly JJ, Johnson J, Ignatov AYu, Tyson TA (2004) X-ray absorption study of Ti-activated sodium aluminum hydride. Appl Phys Lett 85:500–502
Moysés Araújo C, Li S, Ahuja R, Jena P (2005) Vacancy-mediated hydrogen desorption in NaAlH4. Phy Rev B 72:165101
Gunaydin H, Houk KN, Ozolinš V (2008) Vacancy-mediated dehydrogenation of sodium alanate. PNAS 105:3673–3677
Balde CP, Mijovilovich AE, Koningsberger DC, van der Eerden AMJ, Smith AD, de Jong KP, Bitter JH (2007) XAFS study of the Al K-edge in NaAlH4. J Phys Chem C 111:2797–2802
Kadono R, Shimomura K, Satoh KH, Takeshita S, Koda A, Nishiyama K, Akiba E, Ayabe RM, Kuba M, Jensen CM (2008) Hydrogen bonding in sodium alanate: a muon spin rotation study. Phys Rev Lett 100:26401
Frankcombe TJ (2012) Proposed mechanisms for the catalytic activity of Ti in NaAlH4. Chem Rev 112:2164–2178
Johnson TA, Jorgensen SW, Dedrick DE (2011) Performance of a full-scale hydrogen-storage tank based on complex hydrides. Faraday Discuss 151:327–352
Bellosta von Colbe JM, Metz O, Lozano GA, Pranzas PK, Schmitz HW, Beckmann F, Schreyer A, Klassen T, Dornheim M (2012) Behavior of scaled-up sodium alanate hydrogen storage tanks during sorption. Int J Hydrogen Energy 37:2807–2811
Gay-Lussac JL, Thénard IJ (1809) Notiz über das Kali - und das Natron – Metall. Ann Phys 32:23–39
Chen P, Xiong ZT, Luo JZ, Li JY, Tan KL (2002) Interaction of hydrogen with metal nitrides and imides. Nature 420:302–304
Greenlee KW, Henne AL, Fernelius WC (1946) Inorganic syntheses, vol II. Wiley, Hoboken, pp 128–135
Bergstrom FW (1955) Sodium amide. Org Synth CV 3, P 778
Xiong ZT, Hu JJ, Wu GT, Chen P, Luo WF, Gross K, Wang J (2005) Thermodynamic and kinetic investigations of the hydrogen storage in the Li-Mg-N-H system. J Alloys Compd 398:235–239
Hu YH, Ruckenstein E (2006) Hydrogen storage of Li2NH prepared by reacting Li with NH3. Ind Eng Chem Res 45:182–186
Nakamori Y, Kitahara G, Ninomiya A, Aoki M, Noritake T, Towata S, Orimo S (2005) Guidelines for developing amide-based hydrogen storage materials. Mater Trans 46:2093–2097
Kojima Y, Ichikawa T, Fujii H (2009) Fuels-hydrogen storage | complex hydrides, Elsevier, Encyclopedia of Electrochemical Power Sources. pp 473–483
Hu YH, Ruckenstein E (2003) Ultra-fast reaction between LiH and NH3 during H2 storage in Li3N. J Phys Chem A 107:9737–9739
Leng HY, Ichikawa T, Hino S, Hanada N, Isobe S, Fujii H (2004) New metal-NH system composed of Mg(NH2)2 and LiH for hydrogen storage. J Phys Chem B 108:8763–8765
Nakamori Y, Kitahara G, Orimo S (2004) Synthesis and dehydriding studies of Mg–N–H systems. J Power Sources 138:309–312
Dafert FW, Miklanz R (1910) Uber einige neue verbindungen von stickstoff und wasserstoff mit lithium. Manotsh Chem 31:981–996
Ruff O, Geoges H, Über das lithium-imid und einige Bemerkungen zu der arbeit von dafert und miklauz: “Über einige neue verbindungen von stickstoff und wasserstoff mit lithium”. Ber Dtsch Chem Ges 44:502–506
Orimo S, Nakamori Y, Kitahara G, Miwa K, Ohba N, Noritake T, Towata S (2004) Destabilization and enhanced dehydriding reaction of LiNH2. Appl Phys A 79:1765–1767
Kojima Y, Kawai Y (2004) Hydrogen storage of metal nitride by a mechanochemical reaction. Chem Commun 2210–2211
Wang J, Li H-W, Chen P (2013) Amides and borohydrides for high-capacity solid-state hydrogen storage-materials design and kinetic improvements. MRS Bull 38:480–487
Pinkerton FE, Meisner GP, Meyer MS, Balogh MP, Kundrat MD (2005) Hydrogen desorption exceeding ten weight percent from the new quaternary hydride Li3BN2H8. J Phys Chem B 109:6–8
Vajo JJ, Mertens F, Ahn CC, Bowman RC, Fultz B (2004) Altering hydrogen storage properties by hydride destabilization through alloy formation: LiH and MgH2 destabilized with Si. J Phys Chem B 108:13977–13983
Gosalawit-Utke R, Colbe J, Gornheim M, Jensen TR, Cerenius Y, Bonatto CM, Peschke M, Bormann R (2010) LiF-MgB2 system for reversible hydrogen storage. J Phys Chem C 114:10291–10296
Chen P, Xiong ZT, Yang LF, Wu GT, Luo WF (2006) Mechanistic investigations on the heterogeneous solid-state reaction of magnesium amides and lithium hydrides. J Phys Chem B 110:14221–14225
Shaw LL, Ren R, Markmaitree T, Osborn W (2008) Effects of mechanical activation on dehydrogenation of the lithium amide and lithium hydride system. J Alloys Compd 448:263–271
Liu YF, Zhong K, Luo K, Gao MX, Pan HG, Wang QD (2009) Size-dependent kinetic enhancement in hydrogen absorption and desorption of the Li–Mg–N–H System. J Am Chem Soc 131:1862–1870
Wang JH, Liu T, Wu GT, Li W, Liu YF, Araujo CM, Scheicher RH, Blomqvist A, Ahuja R, Xiong ZT, Yang P, Gao MX, Pan HG, Chen P (2009) Potassium-modified Mg(NH2)2/2 LiH system for hydrogen storage. Angew Chem Int Ed 48:5828–5832
Li H-W, Yan Y, Orimo S, Züttel A, Jensen CM (2011) Recent progress in metal borohydrides for hydrogen storage. Energies 4:185–214
Rude LH, Nielsen TK, Ravnsbæk DB, Bösenberg U, Ley MB, Richter B, Arnbjerg LM, Dornheim M, Filinchuk Y, Besenbacher F, Jensen TR (2011) Tailoring properties of borohydrides for hydrogen storage: a review. Phys Status Solidi A 208:1754–1773
Schlesinger HI, Brown HC, Metallo borohydrides. (1940) III. Lithium borohydride. J Am Chem Soc 62:3429–3435
Schlesinger HI, Brown HC, Hoekstra HR, Rapp LR (1953) New developments in the chemistry of diborane and the borohydrides. J Am Chem Soc 75:199–204
Friedrichs O, Borgschulte A, Kato S, Buchter F, Gremaud R, Remhof A, Züttel A (2009) Low-temperature synthesis of LiBH4 by gas-solid reaction. Chem Eur J 15:5531–5534
Konoplev VN, Bakulina VM (1971) Some properties of magnesium borohydride. Rus Chem Soc 20:136–138
Li H-W, Kikuchi K, Nakamori Y, Miwa K, Towata S, Orimo S (2007) Effects of ball milling and additives on dehydriding behaviors of well-crystallized Mg(BH4)2. Scripta Mater 57:679–682
Matsunaga T, Buchter F, Miwa K, Towata S, Orimo S, Züttel A (2008) Magnesium borohydride: a new hydrogen storage material. Renewable Energy 33:193–196
Cěrny R, Filinchuk Y, Hagemann H, Yvon K (2007) Magnesium borohydride: synthesis and crystal structure. 46:5765–5767
Sato T, Miwa K, Nakamori Y, Ohoyama K, Li H-W, Noritake T, Aoki M, Towata S, Orimo S (2008) Experimental and computational studies on solvent-free rare-earth metal borohydrides R(BH4)3 (R=Y, Dy, and Gd). Phys Rev B 77:104114
Yan Y, Li H-W, Sato T, Umeda N, Miwa K, Towata S, Orimo S (2009) Dehydriding and rehydriding properties of yttrium borohydride Y(BH4)3 prepared by liquid-phase synthesis. Int J Hydrogen Energy 34:5732–5736
Köster R, Schoeller K (1957) Neue herstellungsmethoden für metallborhydride. Angew Chem 69:94
Harris PM, Meibohm EP (1947) The crystal structure of lithium borohydride LiBH4. J Am Chem Soc 69:1231–1232
Soulie J-Ph, Renaudin G, Cerny R, Yvon K (2002) Lithium boro-hydride LiBH4 I. crystal structure. J Alloys Compd 346:200–205
Filinchuk Y, Chernyshov D, Cerny R (2008) Lightest borohydride probed by synchrotron X-ray diffraction: experiment calls for a new theoretical revision. J Phys Chem C 112:10579–10584
Tekin A, Caputo R, Züttel A (2010) First-principles determination of the ground-state structure of LiBH4. Phys Rev Lett 104:215501
Li H-W, Kikuchi K, Nakamori Y, Ohba N, Miwa K, Towata S, Orimo S (2008) Dehydriding and rehydriding processes of well-crystallized Mg(BH4)2 accompanying with formation of intermediate compounds. Acta Mater 56:1342–1347
Hwang SJ, Bowman RC, Reiter JW, Rijssenbeek J, Soloverchik GL, Zhao J-C, Kabbour H, Ahn CC (2008) NMR confirmation for formation of [B12H12]2− complexes during hydrogen desorption from metal borohydrides. J Phys Chem C 112:3164–3169
Ozolin V, Majzoub EH, Wolverton C (2009) First-principles prediction of thermodynamically reversible hydrogen storage reactions in the Li-Mg-Ca-B-H System. J Am Chem Soc 131:230–237
Chong M, Karkamkar A, Autrey T, Orimo S, Jalisatgi S, Jensen CM (2011) Reversible dehydrogenation of magnesium borohydride to magnesium triborane in the solid state under moderate conditions. Chem Commun 47:1330–1332
Yan Y, Li H-W, Maekawa H, Aoki M, Noritake T, Matsumoto M, Miwa K, Towata S, Orimo S (2011) Formation process of [B12H12]2− from [BH4]− during the dehydrogenation reaction of Mg(BH4)2. Mater Trans 52:1443–1446
Orimo S, Nakamori Y, Kitahara G, Miwa K, Ohba N, Towata S, Züttel A (2005) Dehydriding and rehydriding reactions of LiBH4. J Alloys Compd 404:427–430
Li H-W, Akiba E, Orimo S (2013) Comparative study on the reversibility of pure metal borohydrides. J Alloy Compd 580:S292–S295
Nakamori Y, Miwa K, Ninoyiya A, Li H-W, Ohba N, Towata S, Züttel A, Orimo S (2006) Correlation between thermodynamical stabilities of metal borohydrides and cation electronegativites: first-principles calculations and experiments. Phys Rev B 74:045126
Li H-W, Orimo S, Nakamori Y, Miwa K, Ohba N, Towata S, Züttel A (2007) Materials designing of metal borohydrides: viewpoints from thermodynamical stabilities. J Alloys Compd 446–447:315–318
Vajo JJ, Olson GL (2007) Hydrogen storage in destabilized chemical systems. Scripta Mater 56:829–834
Vajo JJ, Skeith SL, Mertens F (2005) Reversible storage of hydrogen in destabilized LiBH4. J Phys Chem B 109:3719–3722
Bösenberg U, Doppiu S, Mosegaard L, Barkhordarian G, Eigen N, Borgschulte A, Jensen TR, Cerenius Y, Gutfleisch O, Klassen T, Dornheim M, Bormann R (2007) Hydrogen sorption properties of MgH2 + 2LiBH4. Acta Mater 55:3951–3958
Pinkerton FE, Meyer MS, Meisner GP, Balogh MP, Vajo JJ (2007) Phase boundaries and reversibility of LiBH4/MgH2 hydrogen storage material. J Phys Chem C 111:12881–12885
Yan Y, Li H-W, Maekawa H, Miwa K, Towata S, Orimo S (2011) Formation of intermediate compound Li2B12H12 during the dehydrogenation process of the LiBH4-MgH2 system. J Phys Chem C 115:19419–19423
Price TE, Grant DM, Weston D, Hansen T, Arnbjerg LM, Ravnsbæk DB, Jensen TR, Walker GS (2011) The effect of H2 partial pressure on the reaction progression and reversibility of lithium-containing multicomponent destabilized hydrogen storage systems. J Am Chem Soc 133:13534–13538
Shim JH, Lim JH, Rather SU, Lee YS, Reed D, Kim Y, Book D, Cho YW (2010) Effect of hydrogen back pressure on dehydrogenation behavior of LiBH4-based reactive hydride composites. J Phys Chem Lett 1:59–63
Jin SA, Lee YS, Shim JH, Cho YW (2008) Reversible hydrogen storage in LiBH4–MH2 (M=Ce, Ca) composites. J Phys Chem C 112:9520–9524
Spatz P, Aebischer HA, Krozer A, Schlapbach L (1993) The diffusion of H in Mg and the nucleation and growth of MgH2 in thin films. Z Phys Chem 181:393–397
Bogdanovic B (1985) Catalytic synthesis of organo-lithium and organomagnesium compounds and of lithium and magnesium hydrides—applications in organic-synthesis and hydrogen storage. Angew Chem Itn Edit 24:262–273
Uesugi H, Sugiyama T, Nii H, Ito T, Nakatsugawa I (2011) Industrial production of MgH2 and its application. J Alloys Compd 509:S650–S653
Vajeeston P, Ravindran P, Kjekshus A, Fjellvåg H (2002) Pressure-induced structural transitions in MgH2. Phys Rev Lett 89:175506
Noritake T, Aoki M, Towata S, Seno Y, Hirose Y, Nishibori E, Takata M, Sakata M (2002) Chemical bonding of hydrogen in MgH2. Appl Phys Lett 81:2008–2010
Zhu M, Lu Y, Ouyang L, Wang H (2013) Thermodynamic tuning of Mg-based hydrogen storage alloys: a review. Materials 6:4654–4674
Wagemans RWP, van Lenthe JH, de Jongh PE, van Dillen AJ, de Jong KP (2005) Hydrogen storage in magnesium clusters: quantum chemical study. J Am Chem Soc 127:16675–16680
Huot J, Liang G, Boily S, Van Nesteb A, Schulza R (1999) Structural study and hydrogen sorption kinetics of ball-milled magnesium hydride. J Alloys Compd 293–295:495–500
Nielsen TK, Manickam K, Hirscher M, Besenbacher F, Jensen TR (2009) Confinement of MgH2 nanoclusters within nanoporous aerogel scaffold materials. ACS Nano 3:3521–3528
Barkhordarian G, Klassen T, Bormann R (2003) Fast hydrogen sorption kinetics of nanocrystalline Mg using Nb2O5 as catalyst. Scr Mater 49:213–217
Barkhordarian G, Klassen T, Bormann R (2004) Effect of Nb2O5 content on hydrogen reaction kinetics of Mg. J Alloys Compd 364:242–246
Finholt AE, Bond AC, Schlesinger HI (1947) Lithium aluminum hydride, aluminum hydride and lithium gallium hydride, and some of their applications in organic and inorganic chemistry. J Am Chem Soc 69:1199–1203
Chizinsky G, Evans GG, GibbJr TPP, RiceJr MJ (1955) Non-solvated aluminum hydride. J Am Chem Soc 77:3164–3165
Brower FM, Matzek NE, Reigler PF, Rinn HW, Roberts CB, Schmidt DL, Snover JA, Terada K (1976) Preparation and properties of aluminum hydride. J Am Chem Soc 98:2450–2453
Bulychev BM, Verbetskii VN, Storozhenko PA (2008) “Direct” synthesis of unsolvated aluminum hydride involving Lewis and Bronsted acids. Russ J Inorg Chem 53:1000–1005
Bulychev BM, Storozhenko PA, Fokin VN (2009) “One-step” synthesis of nonsolvated aluminum hydride. Russ Chem Bull Inter Ed 58:1817–1823
Graetz J, Reilly JJ, Yartys VA, Maehlen JP, Bulychev BM, Antonov VE, Tarasov BP, Gabis IE (2011) Aluminum hydride as a hydrogen and energy storage material: past, present and future. J Alloys Comp 509:S517–S528
Saitoh H, Machida A, Katayama Y, Aoki K (2008) Formation and decomposition of AlH3 in the aluminum-hydrogen system. Appl Phys Lett 93:151918
Clasen H (1962) German Patent 1141:623
Zidan R, Garcia-Diaz BL, Fewox CS, Stowe AC, Gray JR, Harter AG (2009) Aluminium hydride: a reversible material for hydrogen storage. Chem Commun 25:3717–3719
Murib JH, Horvitz D (1972) US Patent 3,642,853
Stecher O, Wiberg E (1942) Über einen nichtflüchtigen, polymeren aluminiumwasserstoff (AlH3)x und einige flüchtige verbindungen des monomeren AlH3. Ber Dtsch Chem Ges 75B:2003–2012
Graetz J, Chaudhuri S, Wegrzyn J, Celebi Y, Johnson JR, Zhou W, Reilly JJ (2007) Direct and reversible synthesis of AIH3-triethylenediamine from Al and H2. J Phys Chem C 111:19148–19152
Lacina D, Wegrzyn J, Reilly J, Celebi Y, Graetz J (2010) Characterization of dimethylethylamine-alane and the regeneration of aluminum hydride. Energy Environ Sci 3:1099–1105
Turley JW, Rinn HW (1969) The crystal structure of aluminum hydride. Inorg Chem 8:18–22
Brinks HW, Istad-Lem A, Hauback BC (2006) Mechanochemical synthesis and crystal structure of alpha′-AlD3 and alpha-AlD3. J Phys Chem B 110:25833–25837
Brinks HW, Langley W, Jensen CM, Graetz J, Reilly JJ, Hauback BC (2007) Synthesis and crystal structure of β-AlD3. J Alloys Compd 433:180–183
Yartys VA, Denys RV, Maehlen JP, Frommen C, Fichtner M, Bulychev BM, Emerich H (2007) Double-bridge bonding of aluminium and hydrogen in the crystal structure of gamma-AlH3. Inorg Chem 46:1051–1055
Brinks HW, Brown C, Jensen CM, Graetz J, Reilly JJ, Hauback BC (2007) The crystal structure of gamma-AlD3. J Alloys Compd 441:364–367
Sartori S, Opalka SM, Løvvik OM, Guzik MN, Tang X, Hauback BC (2008) Experimental studies of α-AlD3 and α′-AlD3 versus first-principles modelling of the alane isomorphs. J Mater Chem 18:2361–2370
Graetz J, Reilly JJ (2006) Thermodynamics of the α, β and γ polymorphs of AlH3. J Alloys Compd 424:262–265
Sinke GC, Walker LC, Oetting FL, Stull DR (1967) Thermodynamic properties of aluminum hydride. J Chem Phys 47:2759–2761
Tkacz M, Filipek S, Baranowski B (1983) High pressure synthesis of aluminium hydride from the elements. Pol J Chem 57:651–653
Baranowski B, Tkacz M (1983) The equilibrium between solid aluminium hydride and gaseous hydrogen. Z Phys Chem NF 135:27–38
Konovalov SK, Bulychev BM (1995) The P, T-state diagram and solid phase synthesis of aluminum hydride. Inorg Chem 34:172–175
Herley PJ, Chrlstofferson O, Irwin R (1981) Decomposition of.alpha.-aluminum hydride powder. 1. Thermal decomposition. J Phys Chem 85:1874–1881
Graetz J, Reilly JJ (2005) Decomposition kinetics of the AlH3 polymorphs. J Phys Chem B 109:22181–22185
Graetz J, Reilly JJ, Kulleck JG, Bowman RC (2007) Kinetics and thermodynamics of the aluminum hydride polymorphs. J Alloys Compd 446–447:271–275
Maehlen JP, Yartys VA, Denys RV, Fichtner M, Frommen C, Bulychev BM, Pattison P, Emerich H, Filinchuk YE, Chernyshov D (2007) J Alloys Compd 446–447:280–289
Sandrock G, Reilly J, Graetz J, Zhou WM, Johnson J, Wegrzyn J (2005) Accelerated thermal decomposition of AlH3 for hydrogen-fueled vehicles. Appl Phys A 80:687–690
Sandrock G, Reilly J, Graetz J, Zhou WM, Johnson J, Wegrzyn J (2006) Alkali metal hydride doping of α-AlH3 for enhanced H2 desorption kinetics. J Alloys Compd 421:185–189
Orimo S, Nakamori Y, Kato T, Brown C, Jensen CM (2006) Intrinsic and mechanically modified thermal stabilities of α-, β- and γ-aluminum trihydrides AlH3. Appl Phys A 83:5–8
Kato S, Bielmann M, Ikeda K, Orimo S, Borgschulte A, Zuttel A (2010) Surface changes on AlH3 during the hydrogen desorption. Appl Phys Lett 96:051912
Staubitz A, Robertson APM, Manners I (2010) Ammonia—borane and related compounds as dihydrogen sources. Chem Rev 110:4079–4124
Stephens FH, Pons V, Baker RT (2007) Ammonia-borane, the hydrogen storage source par excellence. Dalton Trans 25:2613–2626
Shore SG, Parry RW (1955) The crystalline compound ammonia-borane, H3NBH3. J Am Chem Soc 77:6084–6085
Lippert EL, Lipscomb WN (1956) The structure of H3NBH3. J Am Chem Soc 78:503–504
Hoon CF, Reynhardt EC (1983) Molecular-dynamics and structures of amine boranes of the type R3N BH3. I. X-ray investigation of H3N BH3 at 295 K and 110 K. J Phys C 16:6129–6136
Klooster WT, Koetzle TF, Siegbahn PEM, Richardson TB, Crabtree RH (1999) Study of the N–H H–B dihydrogen bond including the crystal structure of BH3NH3 by neutron diffraction. J Am Chem Soc 121:6337–6343
Hu MG, Geanangel RA, Wendlandt WW (1978) The thermal decomposition of ammonia borane. Thermochim Acta 23:249–255
Wolf G, Baumann J, Baitalow F, Hoffmann FP (2000) Calorimetric process monitoring of thermal decomposition of B–N–H compounds. Thermochim Acta 343:19–25
Baitalow F, Baumann J, Wolf G, Jaenicke-Röβler K, Leitner G (2002) Thermal decomposition of B–N–H compounds investigated by using combined thermoanalytical methods. Thermochim Acta 391:159–168
Stowe AC, Shaw WJ, Linehan JC, Schmid B, Autrey T (2007) In situ solid state 11B MAS-NMR studies of the thermal decomposition of ammonia borane: mechanistic studies of the hydrogen release pathways from a solid state hydrogen storage material. Phys Chem Chem Phys 9:1831–1836
Shaw WJ, Linehan JC, Szymczak NK, Heldebrant D, Yonker C, Camaioni D, Baker RT, Autrey T (2008) In situ multinuclear NMR spectroscopic studies of the thermal decomposition of ammonia borane in solution. Angew Chem Int Ed 47:7493–7496
Heldebrant DJ, Karkamkar A, Hess NJ, Bowden M, Rassat S, Zheng F, Rappe K, Autrey T (2008) The effects of chemical additives on the induction phase in solid-state thermal decomposition of ammonia borane. Chem Mater 20:5332–5336
Denney MC, Pons V, Hebden TJ, Heinekey DM, Goldberg KI (2006) Efficient catalysis of ammonia borane dehydrogenation. J Am Chem Soc 128:12048–12049
Paul A, Musgrave C (2007) Catalyzed dehydrogenation of ammonia–borane by iridium dihydrogen pincer complex differs from ethane dehydrogenation. Angew Chem Int Ed 46:8153–8156
Stephens FH, Baker RT, Matus MH, Grant DJ, Dixon DA (2007) Acid initiation of ammonia–borane dehydrogenation for hydrogen storage. Angew Chem Int Ed 46:746–749
Himmelberger DW, Yoon CW, Bluhm ME, Carroll PJ, Sneddon LG (2009) Base-promoted ammonia borane hydrogen-release. J Am Chem Soc 131:14101–14110
Staubitz A, Soto AP, Manners I (2008) Iridium-catalyzed dehydrocoupling of primary amine–borane adducts: a route to high molecular weight polyaminoboranes, boron–nitrogen analogues of polyolefins. Angew Chem Int Ed 47:6212–6215
Boddeker KW, Shore SG, Bunting RK (1966) Boron-nitrogen chemistry. 1. Syntheses and properties of new cycloborazanes, (BH2NH2)n. J Am Chem Soc 88:4396–4401
Jaska CA, Temple K, Lough AJ, Manners I (2001) Rhodium-catalyzed formation of boron–nitrogen bonds: a mild route to cyclic aminoboranes and borazines. Chem Commun 11:962–963
Keaton RJ, Blacquiere JM, Baker RT (2007) Base metal catalyzed dehydrogenation of ammonia—borane for chemical hydrogen storage. J Am Chem Soc 129:1844–1845
He T, Xiong Z, Wu G, Chu H, Wu C, Zhang T, Chen P (2009) Nanosized Co- and Ni-catalyzed ammonia borane for hydrogen storage. Chem Mater 21:2315–2318
He T, Wang J, Liu T, Wu G, Xiong Z, Yin J, Chu H, Zhang T, Chen P (2011) Quasi in situ Mössbauer and XAS studies on FeB nanoalloy for heterogeneous catalytic dehydrogenation of ammonia borane. Catal Today 170:69–75
Gutowska A, Li L, Shin Y, Wang CM, Li XS, Linehan JC, Smith RS, Kay BD, Schmid B, Shaw W, Gutowski M, Autrey T (2005) Nanoscaffold mediates hydrogen release and the reactivity of ammonia borane. Angew Chem Int Ed 44:3578–3582
Feaver A, Sepehri S, Shamberger P, Stowe A, Autrey T, Cao G (2007) Coherent carbon cryogel-ammonia borane nanocomposites for H2 storage. J Phys Chem B 111:7469–7472
Li Z, Zhu G, Lu G, Qiu S, Yao X (2010) Ammonia Borane Confined by a Metal—organic framework for chemical hydrogen storage: enhancing kinetics and eliminating ammonia. J Am Chem Soc 132:1490–1491
Schlesinger HI, Burg AB (1938) Hydrides of boron. VIII. The structure of the diammoniate of diborane and its relation to the structure of diborane. J Am Chem Soc 60:290–299
Myers AG, Yang BH, David KJ (1996) Lithium amidotrihydroborate, a powerful new reductant. Transformation of tertiary amides to primary alcohols. Tetrahedron Lett 37:3623–3626
Diyabalanage HVK, Shrestha RP, Semelsberger TA, Scott BL, Bowden ME, Davis BL, Burrell AK (2007) Calcium amidotrihydroborate: A hydrogen storage material. Angew Chem Int Ed 46:8995–8997
Xiong Z, Yong CK, Wu G, Chen P, Shaw W, Karkamkar A, Autrey T, Jones MO, Johnson SR, Edwards PP, David WIF (2008) High-capacity hydrogen storage in lithium and sodium amidoboranes. Nat Mater 7:138–141
Diyabalanage HVK, Nakagawa T, Shrestha RP, Semelsberger TA, Davis BL, Scott BL, Burrell AK, David WIF, Ryan KR, Jones MO, Edwards PP (2010) Potassium(I) amidotrihydroborate: structure and hydrogen release. J Am Chem Soc 132:11836–11837
Luo J, Kang X, Wang P (2013) Synthesis, formation mechanism, and dehydrogenation properties of the long-sought Mg(NH2BH3)2 compound. Energy Environ Sci 6:1018–1025
Zhang QA, Tang CX, Fang CH, Fang F, Sun D, Ouyang LZ, Zhu M (2010) Synthesis, crystal structure and thermal decomposition of strontium amidoborane. J Phys Chem C 114:1709–1714
Genova RV, Fijalkowski KJ, Budzianowski A, Grochala W (2010) Towards Y(NH2BH3)3: Probing hydrogen storage properties of YX3/MNH2BH3 (X=F, Cl; M=Li, Na) and YHx∼3/NH3BH3 composites. J Alloys Compd 499:144–148
Fijalkowski KJ, Genova RV, Filinchuk Y, Budzianowski A, Derzsi M, Jaron T, Leszczynski PJ, Grochala W (2011) Na[Li(NH2BH3)2]—the first mixed-cation amidoborane with unusual crystal structure. Dalton Trans 40:4407–4413
Wu H, Zhou W, Pinkerton FE, Meyer MS, Yao Q, Gadipelli S, Udovic TJ, Yildirim T, Rush JJ (2011) Sodium magnesium amidoborane: the first mixed-metal amidoborane. Chem Commun 47:4102–4104
Xia G, Yu X, Guo Y, Wu Z, Yang C, Liu H, Dou S (2010) Amminelithium amidoborane Li(NH3)NH2BH3: a new coordination compound with favorable dehydrogenation characteristics. Chem Eur J 16:3763–3769
Chua YS, Wu G, Xiong Z, He T, Chen P (2009) Calcium amidoborane ammoniate-synthesis, structure, and hydrogen storage properties. Chem Mater 21:4899–4904
Chua YS, Li W, Shaw WJ, Wu G, Autrey T, Xiong Z, Wong MW, Chen P (2012) Mechanistic investigation on the formation and dehydrogenation of calcium amidoborane ammoniate. ChemSusChem 5:927–931
Chua YS, Wu G, Xiong Z, Karkamkar A, Guo J, Jian M, Wong MW, Autrey T, Chen P (2010) Chem Commun 46:5752–5754
Luo J, Kang X, Fang Z, Wang P (2011) Promotion of hydrogen release from ammonia borane with magnesium nitride. Dalton Trans 40:6469–6474
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2016 Springer Japan
About this chapter
Cite this chapter
Li, HW., Wu, G., He, T., Chen, P. (2016). Solid Hydrogen Storage Materials: Non-interstitial Hydrides. In: Sasaki, K., Li, HW., Hayashi, A., Yamabe, J., Ogura, T., Lyth, S. (eds) Hydrogen Energy Engineering. Green Energy and Technology. Springer, Tokyo. https://doi.org/10.1007/978-4-431-56042-5_15
Download citation
DOI: https://doi.org/10.1007/978-4-431-56042-5_15
Published:
Publisher Name: Springer, Tokyo
Print ISBN: 978-4-431-56040-1
Online ISBN: 978-4-431-56042-5
eBook Packages: EnergyEnergy (R0)