Abstract
This chapter describes fundamental knowledge indispensable for hydride-based hydrogen storage, including the physical and chemical properties of hydrogen, phase diagrams of metal-hydrogen systems, hydrogen-material interaction, as well as thermodynamic stability and the reaction kinetics of hydrides.
Keywords
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsReferences
Flanagan TB, Oates WA (1988) Thermodynamics of intermetallic compound-hydrogen systems. In: Schlapbach L (ed) Hydrogen in intermetallic compounds I. Springer, Berlin, pp 49–85
Griessen R, Riesterer T (1988) Heat of formation models. In: Schlapbach L (ed) Hydrogen in intermetallic compounds I. Springer, Berlin, pp 219–284
Lynch JF, Reilly JJ (1982) Behavior of H-LaNi5 solid solutions. J Less-Common Met 87:225–236
Osumi Y, Suzuki H, Kato A, Oguro K, Nakane M (1981) Effect of metal-substitution on hydrogen storage properties for mischmetal-nickel alloys. Nippon Kagaku Kaishi 124:1493–1502
Murray JJ, Post ML, Taylor JB (1980) Differential heat flow calorimetry of the hydrides of intermetallic compounds. J Less-Common Met 73:33–40
Murray JJ, Post ML, Taylor JB (1983) The thermodynamics of the system CaNi5-H2 using differential heat conduction calorimetry. J Less-Common Met 90:65–73
Post ML, Murray JJ, Taylor JB (1984) Metal hydride studies at the National Research Council of Canada. Int J Hydrogen Energy 9:137–145
Post ML, Murray JJ, Grant DM (1989) The LaNi5—H2 System at T = 358 K: an investigation by heat-conduction calorimetry. Z Phys Chem N F 163:135–140
Wenzl H, Lebsanft E (1980) Phase diagram and thermodynamic parameters of the quasibinary interstitial alloy Fe0.5Ti0.5Hx in equilibrium with hydrogen gas. J Phys F 10:2147–2156
Murray JJ, Post ML, Taylor JB (1981) The thermodynamics of the LaNi5-H2 system by differential heat flow calorimetry I: Techniques; the α + β two-phase region. J Less-Common Met 80:201–209
Buschow KHJ, van Mal HH (1972) Phase relations and hydrogen absorption in the lanthanum-nickel system. J Less-Common Met 29:203–210
Mendelsohn (1977) LaNi5-xAlx is a versatile alloy system for metal hydride applications. Nature 269:45–47
Osumi Y, Suzuki H, Kato A, Nakane M, Miyake Y (1978) Absorption-desorption characteristics of hydrogen for mischmetal based alloys. Nihon Kagaku Kaishi 1472–1477 (in Japanese)
Reilly JJ, Wiswall (1974) Formation and properties of iron titanium hydride. Inorg Chem 13:218–222
Osumi Y, Suzuki H, Kato A, Nakane M, Miyake Y (1979) Absorption-desorption characteristics of hydrogen for titanium-cobalt alloys. Nihon Kagaku Kaishi 855–860 (in Japanese)
Gamo T, Moriwaki Y, Yanagihara N, Yamashita T, Iwaki T (1985) Formation and properties of titanium-manganese alloy hydrides. Int J Hydrogen Energy 10:39–47
Ishido Y, Nishimiya N, Suzuki Y (1977) Preparation and equilibrium study on ZrMn2Hx. Denki Kagaku 45:52–54
Shaltiel D, Jacob I, Davidov D (1977) Hydrogen absorption properties of AB2 Laves-phase pseudobinary compounds. J Less-Common Met 53:117–131
Chase MW Jr, Davis CA, Downey JR Jr, Frurip DJ, McDonald RA, Syverud AN (1985) J Phys Chem Ref Data 14, Suppl No 1:1266
Nomura K, Akiba E, Ono S, Suda S (1979) Kinteics of the reaction between Mg2Ni and H2. In: JIMIS-2 Hydrogen in Metals, Minakami, Japan. The Japan Institute of Metals, Sendai, pp 353–356
Sandrock GD, Murray JJ, Post ML, Taylor JB (1982) Hydrides and deuteride of CaNi5. Mat Res Bul 17:887–894
van Mal HH, Buschow KHJ, Miedcma AR (1974) Hydrogen absorption in LaNi5 and related compounds: experimental observations and their explanation. J Less-Common Met 35:65–76
Didisheim JJ, Zolliker P, Yvon K, Fischer P, Schefer J, Gubelmann M, Williams AF (1984) Dimagnesium iron(II) hydride, Mg2FeH6, containing octahedral FeH 4-6 anions. Inorg Chem 23:1953–1957
Zolliker P, Yvon K, Fischer P, Schefer J (1985) Dimagnesium cobalt(I) pentahydride, Mg2CoH5, containing square-pyramidal pentahydrocobaltate(4-) (CoH 4-5 ) anions. Inorg Chem 24:4177–4180
Flanagan TB (1978) Thermodynamics of metal, alloy and intermetallic/hydrogen systems. In: Andresen AF, Maeland AJ (eds) Hydrides for energy storage: proceedings of an international symposium, Geilo, August 1977. Oxford, Pergamon, pp 43–59
Rudman PS (1979) Hydrogen-diffusion-rate-limited hydriding and dehydriding kinetics. J Appl Phys 50:7195–7199
Boulet JM, Gerard N (1983) The mechanism and kinetics of hydride formation in Mg-10 wt%Ni and CeMg12. J Less-Common Met 89:151–161
Mintz MH, Bloch J (1985) Evaluation of the kinetics and mechanisms of hybriding reactions. Prog Solid State Chem 16:163–194
Rudman PS (1983) Hydriding and dehydriding kinetics. J Less-Common Met 89:93–110
Sharp JH, Brindley GW, Achar BNA (1966) Numerical data for some commonly used solid state reaction equations. J Am Ceram Soc 49:379–382
Hancock JD, Sharp JH (1972) Method of comparing solid-state kinetic data and its application to the decomposition of Kaolinite, Brucite and BaCO3. J Am Ceram Soc 55:74–77
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2016 Springer Japan
About this chapter
Cite this chapter
Akiba, E. (2016). Fundamentals. In: Sasaki, K., Li, HW., Hayashi, A., Yamabe, J., Ogura, T., Lyth, S. (eds) Hydrogen Energy Engineering. Green Energy and Technology. Springer, Tokyo. https://doi.org/10.1007/978-4-431-56042-5_13
Download citation
DOI: https://doi.org/10.1007/978-4-431-56042-5_13
Published:
Publisher Name: Springer, Tokyo
Print ISBN: 978-4-431-56040-1
Online ISBN: 978-4-431-56042-5
eBook Packages: EnergyEnergy (R0)