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Part of the book series: Cultural Heritage Science ((CUHESC))

Abstract

The frequency band below the mid-infrared region was studied actively in the 1960s and 1970s during the development of FTIR spectroscopy. While researchers explored the use of this “far-infrared” region for spectroscopy at that time, only the mid-infrared region has become commonly used in FTIR methods. Spectra of typical art materials, such as pigments and binders, are introduced, and factors which affect the spectra are discussed.

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References

  1. R.S. McDonald, P.A. Wilks Jr., Appl. Spectrosc. 42, 151 (1998)

    Article  Google Scholar 

  2. Infrared Raman Users’ Group website, http://www.irug.org/

  3. B.A. Price, B. Pretzel, S.Q. Lomax, C. Davis, J.H. Carlson, Revised JCAMP-DX spectral file format for submissions to the infrared Raman Users Group (IRUG) spectral database, available from [2]

    Google Scholar 

  4. E.D. Palik, Handbook of Optical Constants of Solids (Academic, New York, 1997)

    Google Scholar 

  5. C. Karr Jr., J.J. Kovach, Far-infrared spectroscopy of minerals and inorganics. Appl. Spectrosc. 23, 219–223 (1969)

    Article  Google Scholar 

  6. H.D. Riccius, K.J. Siemsen, Infrared lattice bands of trigonal and cubic mercury sulfide. J. Chem. Phys. 52, 4090–4093 (1969)

    Article  Google Scholar 

  7. R.A. Nyquist, R.O. Kagel, Infrared Spectra of Inorganic Compounds (3800-45 cm −1 ) (Academic, New York, 1971)

    Google Scholar 

  8. F. Pavanello, F. Garet, M.-B. Kuppam, E. Peytavit, M. Vanwolleghem, F. Vaurette, J.-L. Coutaz, J.-F. Lampin, Broadband ultra-low-loss mesh filters on flexible cyclic olefin copolymer films for terahertz applications. Appl. Phys. Lett. 102, 111114 (2013)

    Article  Google Scholar 

  9. Y. Kishi, M. Nagai, J.C. Young, K. Takano, M. Hangyo, T. Suzuki, Terahertz laminated-structure polarizer with high extinction ratio and transmission power. Appl. Phys. Express 8, 032201 (2015)

    Article  Google Scholar 

  10. K. Liu, M.G. Brown, J.D. Cruzan, R. Saykally, Terahertz laser spectroscopy of the water pentamer: structure and hydrogen bond rearrangement dynamics. J. Phys. Chem. A 101, 9011–9021 (1997)

    Article  Google Scholar 

  11. C.A. Schmuttenmaer, Exploring dynamics in the far-infrared with terahertz spectroscopy. Chem. Rev. 104, 1759–1779 (2004)

    Article  Google Scholar 

  12. H. Yada, M. Nagai, K. Tanaka, Origin of the fast relaxation component of water and heavy water revealed by terahertz time-domain attenuated total reflection spectroscopy. Chem. Phys. Lett. 464, 166–170 (2008)

    Article  Google Scholar 

  13. M. Takahashi, Terahertz vibrations and hydrogen-bonded networks in crystals. Crystals 4, 74–103 (2014)

    Article  Google Scholar 

  14. Y. Ohki, M. Okada, N. Fuse, K. Iwai, M. Mizuno, K. Fukunaga, Terahertz time-domain spectroscopic analysis of molecular behavior in polyamide nanocomposites. Appl. Phys. Express 1, 122401 (2008)

    Article  Google Scholar 

  15. A. Bandyopadhyay, A. Sengupta, R.B. Barat, D.E. Gary, J.F. Federici, M. Chen, D.B. Tanner, Effects of scattering on THz spectra of granular solids. Int. J. Infrared Milli. Waves 28, 969–978 (2007)

    Article  Google Scholar 

  16. C.J. Strachan, T. Rades, D.A. Newnham, K.C. Gordon, M. Pepper, P.F. Taday, Using terahertz pulsed spectroscopy to study crystallinity of pharmaceutical materials. Chem. Phys. Lett. 390, 20–24 (2004)

    Article  Google Scholar 

  17. K. Fukunaga, M. Picollo, Terahertz spectroscopy applied to the analysis of artists’ materials. Appl. Phys. A 100, 591–597 (2010)

    Article  Google Scholar 

  18. J.-M. Manceau, A. Nevin, C. Fotakis, S. Tzortzakis, Terahertz time domain spectroscopy for the analysis of cultural heritage related materials. Appl. Phys. B Lasers Opt. 90, 365–368 (2008)

    Article  Google Scholar 

  19. K. Fukunaga, Y. Ogawa, S. Hayashi, I. Hosako, Application of terahertz spectroscopy for character recognition in a medieval manuscript. IEICE Electron. Expr. 5, 223–228 (2008)

    Article  Google Scholar 

  20. E. Abraham, A. Younus, A. El Fatimy, J.C. Delagnes, E. Nguéma, P. Mounaix, Broadband terahertz imaging of documents written with lead pencils. Opt. Commun. 282, 3104–3107 (2009)

    Article  Google Scholar 

  21. J. Labaune, J.B. Jackson, S. Pagès-camagna, G.A. Mourou, I.N. Duling, M. Menu, Papyrus imaging with terahertz time domain spectroscopy. Appl. Phys. A. 100, 607–612 (2010)

    Article  Google Scholar 

  22. T. Bardon, R.K. May, P.F. Taday, M. Strlic, Systematic study of terahertz time-domain spectra of historically informed black inks. Analyst 138, 4859–4869 (2013)

    Article  Google Scholar 

  23. R. Radpour, N. Bajwa, J. Garritano, S. Sung, M. Balonis-Sant, P. Tewari, W. Grundfest, I. Kakoulli, Z. Taylor, THz pulsed TDI studies of painted samples to guide cultural heritage investigations at the Enkleistra of St. Neophytos in Paphos, Cypris. Proc. SPIE. 9199(91990Q) (2014)

    Google Scholar 

  24. M. Naftaly, J.F. Molloy, G.V. Lanskii, K.A. Kokh, Y.M. Andreev, Terahertz time-domain spectroscopy for textile identification. Appl. Optics 52, 4433–4437 (2013)

    Article  Google Scholar 

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Fukunaga, K. (2016). THz Spectroscopy. In: THz Technology Applied to Cultural Heritage in Practice. Cultural Heritage Science. Springer, Tokyo. https://doi.org/10.1007/978-4-431-55885-9_3

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