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Photoinduced Electron-Transfer Functions of π-Electron Donor–Acceptor Supramolecular Complexes

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Chemical Science of π-Electron Systems

Abstract

This chapter describes the recent development of supramolecular π-electron donor–acceptor complexes linked by noncovalent bonds for light harvesting and charge separation. Carbon nanomaterials such as carbon nanohorns and graphene oxides act as π-electron donors to construct π-electron donor–acceptor supramolecular nanohybrids linked with π-electron acceptors such as fullerenes and perylenediimide, which undergo efficient charge separation. Multiple reaction center models have been constructed using multiporphyrin assemblies (porphyrin dendrimers and porphyrin polypeptides), which are noncovalently linked with π-electron acceptors, affording efficient energy migration, followed by long-lived charge separation. Bimolecular charge recombination of charge-separated states has been prohibited in supramolecular complexes between cationic and anionic porphyrins, affording the long-lived charge-separated states in solution.

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Acknowledgments

The author gratefully acknowledges the contributions of their collaborators and coworkers mentioned in the cited references and support by a Grant-in-Aid (No. 20108010 to SF) from MEXT, Japan.

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Authors and Affiliations

  1. Department of Chemistry and Nano Science, Ewha Womans University, Seoul, 120–750, Korea

    Shunichi Fukuzumi

  2. Faculty of Science and Engineering, ALCA and SENTAN, Japan Science and Technology Agency (JST), Meijo University, Nagoya, Aichi, 468-0073, Japan

    Shunichi Fukuzumi

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  1. Shunichi Fukuzumi
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Correspondence to Shunichi Fukuzumi .

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Editors and Affiliations

  1. Foundation for Advancement of International Science, Tsukuba, Japan

    Takeshi Akasaka

  2. Kyoto University, Kyoto, Japan

    Atsuhiro Osuka

  3. Department of Chemistry and Nano Science,, Ewha Womans University, Seoul, Korea (Republic of)

    Shunichi Fukuzumi

  4. Nagoya Institute of Technology, Nagoya, Japan

    Hideki Kandori

  5. Osaka University, Suita, Japan

    Yoshio Aso

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Fukuzumi, S. (2015). Photoinduced Electron-Transfer Functions of π-Electron Donor–Acceptor Supramolecular Complexes. In: Akasaka, T., Osuka, A., Fukuzumi, S., Kandori, H., Aso, Y. (eds) Chemical Science of π-Electron Systems. Springer, Tokyo. https://doi.org/10.1007/978-4-431-55357-1_31

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