Abstract
This chapter investigates the fabrication of metallic nanowire arrays and their application as sensors or biosensors to determine glucose, glutamate and H2O2. Nanowire-based material provides a very high electrochemically active surface area, thereby leading to very high detection sensitivity. To date, noble metals, such as platinum (Pt), gold (Au), silver (Ag) and their alloys, have been extensively investigated as anodic materials in the design of non-enzymatic sensor surfaces. Vertically aligned structures such as free-standing nanowire arrays are particularly useful for sensing and biosensing applications due to their high sensitivity to surface interactions. Although nanowires have been fabricated by various methods, a simple fabrication technique which incurs reasonable costs for practical applications is highly desired. In this chapter, a template-based fabrication of nanowire arrays of Au, Pt and nickel (Ni) will be described. These materials have been characterized using X-ray diffraction, scanning electron microscopy and transmission electron microscopy. The catalytic activity and the suitability of these materials as electrochemical sensors have been investigated by cyclic voltammetry and amperometry.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Amjad M, Pletcher D, Smith C (1977) The oxidation of alcohols at a nickel anode in alkaline t-butanol/water mixtures. J Electrochem Soc 124:203–206
Anandan V, Rao YL, Zhang GG (2006) Nanopillar array structures for enhancing biosensing performance. Int J Nanomedicine 1(1):73–79
Chakraborty S, Retna Raj C (2009) Pt nanoparticle-based highly sensitive platform for the enzyme-free amperometric sensing of H2O2. Biosens Bioelectron 24(11):3264–3268
Chen J, Zhang W-D, Ye J-S (2008) Nonenzymatic electrochemical glucose sensor based on MnO2/MWNTs nanocomposite. Electrochem Commun 10(9):1268–1271
Cui HF, Ye JS, Zhang WD, Li CM, Luong JHT, Sheu FS (2007) Selective and sensitive electrochemical detection of glucose in neutral solution using platinum-lead alloy nanoparticle/carbon nanotube nanocomposites. Anal Chim Acta 594(2):175–183
Cui XL, Li ZZ, Yang YC, Zhang W, Wang QF (2008) Low-potential sensitive hydrogen peroxide detection based on nanotubular TiO2 and platinum composite electrode. Electroanalysis 20(9):970–975
De Leo M, Kuhn A, Ugo P (2007) 3D-ensembles of gold nanowires: preparation, characterization and electroanalytical peculiarities. Electroanalysis 19(2–3):227–236
Gu BX, Xu CX, Zhu GP, Liu SQ, Chen LY, Wang ML, Zhu JJ (2009) Layer by layer immobilized horseradish peroxidase on zinc oxide nanorods for biosensing. J Phys Chem B 113(18):6553–6557
Hasan M, Jamal M, Razeeb KM (2012) Coaxial NiO/Ni nanowire arrays for high performance pseudocapacitor applications. Electrochim Acta 60:193–200
Jamal M, Worsfold O, McCormac T, Dempsey E (2009) Biosens Bioelectron 24(9):2926–2930
Jamal M, Xu J, Razeeb KM (2010) Disposable biosensor based on immobilisation of glutamate oxidase on Pt nanoparticles modified Au nanowire array electrode. Biosens Bioelectron 26(4):1420–1424
Jamal M, Hasan M, Mischieri J, Mathewson A, Razeeb KM (2011) Fabrication of horseradish peroxidase modified 3D Pt nanowire array electrode and its electro-catalytical activity towards H2O2. ECS Trans 35(26):53–59
Jamal M, Hasan M, Schmidt M, Petkov N, Mathewson A, Razeeb KM (2013) Shell@Core coaxial NiO@Ni nanowire arrays as high performance enzymeless glucose sensor. J Electrochem Soc 160(11):B207–B212
Kang Q, Yang LX, Cai QY (2008) An electro-catalytic biosensor fabricated with Pt-Au nanoparticle-decorated titania nanotube array. Bioelectrochemistry 74(1):62–65
Karam P, Halaoui LI (2008) Sensing of H2O2 at low surface density assemblies of Pt nanoparticles in polyelectrolyte. Anal Chem 80(14):5441–5448
Lan D, Li BX, Zhang ZJ (2008) Chemiluminescence flow biosensor for glucose based on gold nano particle-enhanced activities of glucose oxidase and horseradish peroxidase. Biosens Bioelectron 24(4):934–938
Liu Y, Teng H, Hou H, You T (2009) Nonenzymatic glucose sensor based on renewable electrospun Ni nanoparticle-loaded carbon nanofiber paste electrode. Biosens Bioelectron 24(11):3329–3334
Lu L-M, Zhang L, Qu F-L, Lu H-X, Zhang X-B, Wu Z-S, Huan S-Y, Wang Q-A, Shen G-L, Yu R-Q (2009) A nano-Ni based ultrasensitive nonenzymatic electrochemical sensor for glucose: enhancing sensitivity through a nanowire array strategy. Biosens Bioelectron 25(1):218–223
Nelson PA, Elliott JM, Attard GS, Owen JR (2002) Mesoporous nickel/nickel oxidea nanoarchitectured electrode. Chem Mater 14:524–529
Nie H, Yao Z, Zhou X, Yang Z, Huang S (2011) Nonenzymatic electrochemical detection of glucose using well-distributed nickel nanoparticles on straight multi-walled carbon nanotubes. Biosens Bioelectron 30(1):28–34
Pang XY, He DM, Luo SL, Cai QY (2009) An amperometric glucose biosensor fabricated with Pt nanoparticle-decorated carbon nanotubes/TiO2 nanotube arrays composite. Sens Actuators B Chem 137(1):134–138
Safavi A, Maleki N, Farjami E (2009) Fabrication of a glucose sensor based on a novel nanocomposite electrode. Biosens Bioelectron 24(6):1655–1660
Umar A, Rahman MM, Al-Hajry A, Hahn YB (2009) Enzymatic glucose biosensor based on flower-shaped copper oxide nanostructures composed of thin nanosheets. Electrochem Commun 11(2):278–281
Wang J, Bao W, Zhang L (2012) A nonenzymatic glucose sensing platform based on Ni nanowire modified electrode. Anal Methods 4(12):4009–4013
Wen ZH, Ci SQ, Li JH (2009) Pt nanoparticles inserting in carbon nanotube arrays: nanocomposites for glucose biosensors. J Phys Chem C 113(31):13482–13487
Xu J, Shang F, Luong JHT, Razeeb KM, Glennon JD (2010) Direct electrochemistry of horseradish peroxidase immobilized on a monolayer modified nanowire array electrode. Biosens Bioelectron 25(6):1313–1318
Yang MH, Yang YH, Liu YL, Shen GL, Yu RQ (2006) Platinum nanoparticles-doped sol-gel/carbon nanotubes composite electrochemical sensors and biosensors. Biosens Bioelectron 21(7):1125–1131
You T, Niwa O, Chen Z, Hayashi K, Tomita M, Hirono S (2003) An amperometric detector formed of highly dispersed Ni nanoparticles embedded in a graphite-like carbon film electrode for sugar determination. Anal Chem 75(19):5191–5196
You CP, Li X, Zhang S, Kong JL, Zhao DY, Liu BH (2009) Electrochemistry and biosensing of glucose oxidase immobilized on Pt-dispersed mesoporous carbon. Microchim Acta 167(1–2):109–116
Yu SF, Li NC, Wharton J, Martin CR (2003) Nano wheat fields prepared by plasma-etching gold nanowire-containing membranes. Nano Lett 3(6):815–818
Yu S, Peng X, Cao G, Zhou M, Qiao L, Yao J, He H (2012) Ni nanoparticles decorated titania nanotube arrays as efficient nonenzymatic glucose sensor. Electrochim Acta 76:512–517
Zhu YH, Cao HM, Tang LH, Yang XL, Li CZ (2009) Immobilization of horseradish peroxidase in three-dimensional macroporous TiO2 matrices for biosensor applications. Electrochim Acta 54(10):2823–2827
Acknowledgments
This work was financially supported by The European Union FP7 scheme (e-BRAINS-FP7-ICT-257488).
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2015 Springer Japan
About this chapter
Cite this chapter
Razeeb, K.M., Jamal, M., Hasan, M., Mathewson, A. (2015). Vertically Aligned Nanowire Array-Based Sensors and Their Catalytic Applications. In: Vestergaard, M., Kerman, K., Hsing, IM., Tamiya, E. (eds) Nanobiosensors and Nanobioanalyses. Springer, Tokyo. https://doi.org/10.1007/978-4-431-55190-4_2
Download citation
DOI: https://doi.org/10.1007/978-4-431-55190-4_2
Published:
Publisher Name: Springer, Tokyo
Print ISBN: 978-4-431-55189-8
Online ISBN: 978-4-431-55190-4
eBook Packages: Biomedical and Life SciencesBiomedical and Life Sciences (R0)