Skip to main content

Vertically Aligned Nanowire Array-Based Sensors and Their Catalytic Applications

  • Chapter
  • First Online:
Nanobiosensors and Nanobioanalyses
  • 1434 Accesses

Abstract

This chapter investigates the fabrication of metallic nanowire arrays and their application as sensors or biosensors to determine glucose, glutamate and H2O2. Nanowire-based material provides a very high electrochemically active surface area, thereby leading to very high detection sensitivity. To date, noble metals, such as platinum (Pt), gold (Au), silver (Ag) and their alloys, have been extensively investigated as anodic materials in the design of non-enzymatic sensor surfaces. Vertically aligned structures such as free-standing nanowire arrays are particularly useful for sensing and biosensing applications due to their high sensitivity to surface interactions. Although nanowires have been fabricated by various methods, a simple fabrication technique which incurs reasonable costs for practical applications is highly desired. In this chapter, a template-based fabrication of nanowire arrays of Au, Pt and nickel (Ni) will be described. These materials have been characterized using X-ray diffraction, scanning electron microscopy and transmission electron microscopy. The catalytic activity and the suitability of these materials as electrochemical sensors have been investigated by cyclic voltammetry and amperometry.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  • Amjad M, Pletcher D, Smith C (1977) The oxidation of alcohols at a nickel anode in alkaline t-butanol/water mixtures. J Electrochem Soc 124:203–206

    Article  CAS  Google Scholar 

  • Anandan V, Rao YL, Zhang GG (2006) Nanopillar array structures for enhancing biosensing performance. Int J Nanomedicine 1(1):73–79

    Article  PubMed Central  CAS  PubMed  Google Scholar 

  • Chakraborty S, Retna Raj C (2009) Pt nanoparticle-based highly sensitive platform for the enzyme-free amperometric sensing of H2O2. Biosens Bioelectron 24(11):3264–3268

    Article  CAS  PubMed  Google Scholar 

  • Chen J, Zhang W-D, Ye J-S (2008) Nonenzymatic electrochemical glucose sensor based on MnO2/MWNTs nanocomposite. Electrochem Commun 10(9):1268–1271

    Article  CAS  Google Scholar 

  • Cui HF, Ye JS, Zhang WD, Li CM, Luong JHT, Sheu FS (2007) Selective and sensitive electrochemical detection of glucose in neutral solution using platinum-lead alloy nanoparticle/carbon nanotube nanocomposites. Anal Chim Acta 594(2):175–183

    Article  CAS  PubMed  Google Scholar 

  • Cui XL, Li ZZ, Yang YC, Zhang W, Wang QF (2008) Low-potential sensitive hydrogen peroxide detection based on nanotubular TiO2 and platinum composite electrode. Electroanalysis 20(9):970–975

    Article  CAS  Google Scholar 

  • De Leo M, Kuhn A, Ugo P (2007) 3D-ensembles of gold nanowires: preparation, characterization and electroanalytical peculiarities. Electroanalysis 19(2–3):227–236

    Google Scholar 

  • Gu BX, Xu CX, Zhu GP, Liu SQ, Chen LY, Wang ML, Zhu JJ (2009) Layer by layer immobilized horseradish peroxidase on zinc oxide nanorods for biosensing. J Phys Chem B 113(18):6553–6557

    Article  CAS  PubMed  Google Scholar 

  • Hasan M, Jamal M, Razeeb KM (2012) Coaxial NiO/Ni nanowire arrays for high performance pseudocapacitor applications. Electrochim Acta 60:193–200

    Article  CAS  Google Scholar 

  • Jamal M, Worsfold O, McCormac T, Dempsey E (2009) Biosens Bioelectron 24(9):2926–2930

    Article  CAS  PubMed  Google Scholar 

  • Jamal M, Xu J, Razeeb KM (2010) Disposable biosensor based on immobilisation of glutamate oxidase on Pt nanoparticles modified Au nanowire array electrode. Biosens Bioelectron 26(4):1420–1424

    Article  CAS  PubMed  Google Scholar 

  • Jamal M, Hasan M, Mischieri J, Mathewson A, Razeeb KM (2011) Fabrication of horseradish peroxidase modified 3D Pt nanowire array electrode and its electro-catalytical activity towards H2O2. ECS Trans 35(26):53–59

    Article  CAS  Google Scholar 

  • Jamal M, Hasan M, Schmidt M, Petkov N, Mathewson A, Razeeb KM (2013) Shell@Core coaxial NiO@Ni nanowire arrays as high performance enzymeless glucose sensor. J Electrochem Soc 160(11):B207–B212

    Article  CAS  Google Scholar 

  • Kang Q, Yang LX, Cai QY (2008) An electro-catalytic biosensor fabricated with Pt-Au nanoparticle-decorated titania nanotube array. Bioelectrochemistry 74(1):62–65

    Article  CAS  PubMed  Google Scholar 

  • Karam P, Halaoui LI (2008) Sensing of H2O2 at low surface density assemblies of Pt nanoparticles in polyelectrolyte. Anal Chem 80(14):5441–5448

    Article  CAS  PubMed  Google Scholar 

  • Lan D, Li BX, Zhang ZJ (2008) Chemiluminescence flow biosensor for glucose based on gold nano particle-enhanced activities of glucose oxidase and horseradish peroxidase. Biosens Bioelectron 24(4):934–938

    Article  CAS  Google Scholar 

  • Liu Y, Teng H, Hou H, You T (2009) Nonenzymatic glucose sensor based on renewable electrospun Ni nanoparticle-loaded carbon nanofiber paste electrode. Biosens Bioelectron 24(11):3329–3334

    Article  CAS  PubMed  Google Scholar 

  • Lu L-M, Zhang L, Qu F-L, Lu H-X, Zhang X-B, Wu Z-S, Huan S-Y, Wang Q-A, Shen G-L, Yu R-Q (2009) A nano-Ni based ultrasensitive nonenzymatic electrochemical sensor for glucose: enhancing sensitivity through a nanowire array strategy. Biosens Bioelectron 25(1):218–223

    Article  CAS  PubMed  Google Scholar 

  • Nelson PA, Elliott JM, Attard GS, Owen JR (2002) Mesoporous nickel/nickel oxidea nanoarchitectured electrode. Chem Mater 14:524–529

    Article  CAS  Google Scholar 

  • Nie H, Yao Z, Zhou X, Yang Z, Huang S (2011) Nonenzymatic electrochemical detection of glucose using well-distributed nickel nanoparticles on straight multi-walled carbon nanotubes. Biosens Bioelectron 30(1):28–34

    Article  CAS  PubMed  Google Scholar 

  • Pang XY, He DM, Luo SL, Cai QY (2009) An amperometric glucose biosensor fabricated with Pt nanoparticle-decorated carbon nanotubes/TiO2 nanotube arrays composite. Sens Actuators B Chem 137(1):134–138

    Article  Google Scholar 

  • Safavi A, Maleki N, Farjami E (2009) Fabrication of a glucose sensor based on a novel nanocomposite electrode. Biosens Bioelectron 24(6):1655–1660

    Article  CAS  PubMed  Google Scholar 

  • Umar A, Rahman MM, Al-Hajry A, Hahn YB (2009) Enzymatic glucose biosensor based on flower-shaped copper oxide nanostructures composed of thin nanosheets. Electrochem Commun 11(2):278–281

    Article  CAS  Google Scholar 

  • Wang J, Bao W, Zhang L (2012) A nonenzymatic glucose sensing platform based on Ni nanowire modified electrode. Anal Methods 4(12):4009–4013

    Article  CAS  Google Scholar 

  • Wen ZH, Ci SQ, Li JH (2009) Pt nanoparticles inserting in carbon nanotube arrays: nanocomposites for glucose biosensors. J Phys Chem C 113(31):13482–13487

    Article  CAS  Google Scholar 

  • Xu J, Shang F, Luong JHT, Razeeb KM, Glennon JD (2010) Direct electrochemistry of horseradish peroxidase immobilized on a monolayer modified nanowire array electrode. Biosens Bioelectron 25(6):1313–1318

    Article  CAS  PubMed  Google Scholar 

  • Yang MH, Yang YH, Liu YL, Shen GL, Yu RQ (2006) Platinum nanoparticles-doped sol-gel/carbon nanotubes composite electrochemical sensors and biosensors. Biosens Bioelectron 21(7):1125–1131

    Article  CAS  PubMed  Google Scholar 

  • You T, Niwa O, Chen Z, Hayashi K, Tomita M, Hirono S (2003) An amperometric detector formed of highly dispersed Ni nanoparticles embedded in a graphite-like carbon film electrode for sugar determination. Anal Chem 75(19):5191–5196

    Article  CAS  PubMed  Google Scholar 

  • You CP, Li X, Zhang S, Kong JL, Zhao DY, Liu BH (2009) Electrochemistry and biosensing of glucose oxidase immobilized on Pt-dispersed mesoporous carbon. Microchim Acta 167(1–2):109–116

    Article  CAS  Google Scholar 

  • Yu SF, Li NC, Wharton J, Martin CR (2003) Nano wheat fields prepared by plasma-etching gold nanowire-containing membranes. Nano Lett 3(6):815–818

    Article  CAS  Google Scholar 

  • Yu S, Peng X, Cao G, Zhou M, Qiao L, Yao J, He H (2012) Ni nanoparticles decorated titania nanotube arrays as efficient nonenzymatic glucose sensor. Electrochim Acta 76:512–517

    Article  CAS  Google Scholar 

  • Zhu YH, Cao HM, Tang LH, Yang XL, Li CZ (2009) Immobilization of horseradish peroxidase in three-dimensional macroporous TiO2 matrices for biosensor applications. Electrochim Acta 54(10):2823–2827

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was financially supported by The European Union FP7 scheme (e-BRAINS-FP7-ICT-257488).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Kafil M. Razeeb .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2015 Springer Japan

About this chapter

Cite this chapter

Razeeb, K.M., Jamal, M., Hasan, M., Mathewson, A. (2015). Vertically Aligned Nanowire Array-Based Sensors and Their Catalytic Applications. In: Vestergaard, M., Kerman, K., Hsing, IM., Tamiya, E. (eds) Nanobiosensors and Nanobioanalyses. Springer, Tokyo. https://doi.org/10.1007/978-4-431-55190-4_2

Download citation

Publish with us

Policies and ethics