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Luminescence Properties of Thermostable Lanthanide Coordination Polymers with Intermolecular Interactions

  • Kohei MiyataEmail author
Chapter
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Part of the Springer Theses book series (Springer Theses)

Abstract

The novel thermostable organo-phosphors composed of coordination polymers with phosphine oxides, 1,4-bis(diphenylphosphoryl)benzene (dpb), 4,4′-bis(diphenylphosphoryl)biphenyl (dpbp), 4,4′-bis(diphenylphosphoryl)bithiophe- ne) (dpbt), 3,6-bis(diphenylphosphoryl)-9-phenylcarbazole (dppcz), and low-vibrational frequency hexafluoroacetylacetonato (hfa) ligands are reported. Tight-binding structures with weak intermolecular interactions of the coordination polymer induce both high thermostability (decomposition point >300 °C) and emission quantum yield (Φ Ln = 83 %). The characteristic structures, thermogravimetric analyses and remarkable photophysical properties are presented for the first time.

Keywords

Phosphine oxide Coordination polymer Thermostability 

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Copyright information

© Springer Japan 2014

Authors and Affiliations

  1. 1.ADEKA CorporationTokyoJapan

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