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Repeatable Copper(II)/(I) Redox Potential Switching Driven Visible Light-Induced Coordinated Ring Rotation

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Photofunctionalization of Molecular Switch Based on Pyrimidine Ring Rotation in Copper Complexes

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Abstract

Repeatable PET-driven rotational isomerization is described. I demonstrated the conversion of light stimuli into electrochemical potential via reversibly working artificial molecular rotation, using two strategies, DMFc+ system and partial oxidation system. In both systems, photoinduced electron transfer from copper complex to electron acceptor plays a key role for the photo- and heat-driven rotation.

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References

  1. Armaroli N, Accorsi G, Cardinali F, Listorti A (2007) Top Curr Chem 280:69–115

    Article  CAS  Google Scholar 

  2. Schmittel M, Michel C, Wiegrefe A, Kalsani V (2001) Synthesis 10:1561–1567

    Article  Google Scholar 

  3. Schmittel M, Ganz A (1997) Chem Commun 999–1000

    Google Scholar 

  4. Schmittel M, Michel C, Liu S-X, Schildbach D, Fenske D (2001) Eur J Inorg Chem 1155–1166

    Google Scholar 

  5. Pallenberg AJ, Koenig KS, Barnhart DM (1995) Inorg Chem 34:2833–2840

    Article  CAS  Google Scholar 

  6. Hsieh H-Y, Lin C-H, Tu G-M, Chi Y, Lee G-H (2009) Inorg Chim Acta 362:4734–4739

    Article  CAS  Google Scholar 

  7. Medwid JB, Paul R, Baker JS, Brockman JA, Du MT, Hallett WA, Hanifin JW, Hardy RA, Tarrant ME, Torley LW, Wrenn S (1990) J Med Chem 33:1230–1241

    Article  CAS  Google Scholar 

  8. Merrill CL, Wilson LJ, Thamann TJ, Loehr TM, Ferris NS, Woodruff WH (1984) J Chem Soc Dalton Trans 10:2207–2221

    Google Scholar 

  9. Tabbi G, Cassino C, Cavigiolio G, Colangelo D, Ghiglia A, Viano I, Osella D (2002) J Med Chem 45:5786–5796

    Article  CAS  Google Scholar 

  10. Lafferty JJ, Case FH (1967) J Org Chem 32:1591–1596

    Article  CAS  Google Scholar 

  11. Altomare A, Cascarano G, Giacovazzo C, Guagliardi A, Burla MC, Polidori G, Camalli M (1994) J Appl Cryst 27:435

    Google Scholar 

  12. Sheldrick GM (2008) Acta Cryst A64:112–122

    Article  Google Scholar 

  13. Farrugia LJ (1999) J Appl Cryst 32:837–838

    Article  CAS  Google Scholar 

  14. Fulmer GR, Miller AJM, Sherden NH, Gottlieb HE, Nudelman A, Stoltz BM, Bercaw JE, Goldberg KI (2010) Organometallics 29:2176–2179

    Article  CAS  Google Scholar 

  15. Nomoto K, Kume S, Nishihara H (2009) J Am Chem Soc 131:3830–3831

    Article  CAS  Google Scholar 

  16. Kume S, Nomoto K, Kusamoto T, Nishihara H (2009) J Am Chem Soc 131:14198–14199

    Article  CAS  Google Scholar 

  17. Kume S, Nishihara H (2011) Chem Commun 47:415–417

    Article  CAS  Google Scholar 

  18. Kume S, Nishihara H (2011) Dalton Trans 40:2299–2305

    Article  CAS  Google Scholar 

  19. Ruthkosky M, Kelly CA, Castellano FN, Meyer GJ (1998) Coord Chem Rev 171:309–322

    Article  CAS  Google Scholar 

  20. Ruthkosky M, Castellano FN, Meyer GJ (1996) Inorg Chem 35:6406–6412

    Article  CAS  Google Scholar 

  21. Le Poul N, Campion M, Douziech B, Rondelez Y, Le Clainche L, Reinaud O, Le Mest Y (2007) J Am Chem Soc 129:8801–8810

    Article  Google Scholar 

  22. Bard AJ, Faulkner LR (2001) Electrochemical methods, fundamentals and applications, 2nd edn. Wiley, New York

    Google Scholar 

  23. Jacq J (1971) J Electroanal Chem 29:149–180

    Article  CAS  Google Scholar 

  24. Carano M, Echegoyen L (2003) Chem Eur J 9:1974–1981

    Article  CAS  Google Scholar 

  25. Lerke SA, Evans DH, Feldberg SW (1990) J Electroanal Chem 296:299–315

    Article  CAS  Google Scholar 

  26. Connelly NG, Geiger WE (1996) Chem Rev 96:877–910

    Article  CAS  Google Scholar 

  27. Everly RM, Ziessel R, Suffert J, McMillin DR (1991) Inorg Chem 30:559–561

    Article  CAS  Google Scholar 

  28. Cunningham CT, Cunningham KLH, Michalec JF, McMillin DR (1999) Inorg Chem 38:4388–4392

    Article  CAS  Google Scholar 

  29. Durr H (1990) Photochromism: molecules and systems. Elsevier, Amsterdam

    Google Scholar 

  30. Juris A, Balzani V, Barigelletti F, Campagna S, Belser P, von Zelewsky A (1988) Coord Chem Rev 84:85–277

    Article  CAS  Google Scholar 

  31. Fery-Forgues S, Delavaux-Nicot B (2000) J Photochem Photobiol A 132:137–159

    Article  CAS  Google Scholar 

  32. Kubatkin S, Danilov A, Hjort M, Cornil J, Brédas J-L, Stuhr-Hansen N, Hedegård P, Bjørnholm T (2003) Nature 425:698–701

    Article  CAS  Google Scholar 

  33. Park J, Pasupathy AN, Goldsmith JI, Chang C, Yaish Y, Petta JR, Rinkoski M, Sthena JP, Abruña HD, McEuen PL, Ralph DC (2002) Nature 417:722–725

    Article  CAS  Google Scholar 

  34. Green JE, Wook Choi J, Boukai A, Bunimovich Y, Johnston-Halperin E, DeIonno E, Luo Y, Sheriff BA, Xu K, Shik Shin Y, Tseng H-R, Stoddart JF, Heath JR (2007) Nature 445:414–417

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Seikei University, Musashino, Japan

    Michihiro Nishikawa

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  1. Michihiro Nishikawa
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Correspondence to Michihiro Nishikawa .

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Nishikawa, M. (2014). Repeatable Copper(II)/(I) Redox Potential Switching Driven Visible Light-Induced Coordinated Ring Rotation. In: Photofunctionalization of Molecular Switch Based on Pyrimidine Ring Rotation in Copper Complexes. Springer Theses. Springer, Tokyo. https://doi.org/10.1007/978-4-431-54625-2_4

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