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Characteristics of Cyclometalation Reactions for Organometallic Intramolecular-Coordination Five-Membered Ring Compounds

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Cyclometalation Reactions

Abstract

One of the characteristics of cyclometalation reactions for the production of organometallic intramolecular-coordination five-membered ring compounds is high reaction rates. Many reactions consequently proceed under mild reaction conditions, and their reaction products are very easily isolated from the reaction mixtures, since five-membered rings are generally stable. Many kinds of metal elements, a total of 69 kinds of both transition metal and main group metal compounds, are utilized for these reactions. Many substrates are also used.

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  1. Omae Research Laboratories, Sayama, Japan

    Iwao Omae

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Omae, I. (2014). Characteristics of Cyclometalation Reactions for Organometallic Intramolecular-Coordination Five-Membered Ring Compounds. In: Cyclometalation Reactions. Springer, Tokyo. https://doi.org/10.1007/978-4-431-54604-7_5

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