Abstract
Cyclometalation reactions have been carried out with most transition metal compounds. The first article on these reactions is generally thought to be a 1963 article on the reaction of an azobenzene with a nickel compound. However, the verification of the intramolecular bond was incorrectly assigned in that article as the N=N π-coordination bond to the nickel atom. For this reason, an article on the reaction of azobenzene with a Pd or Pt atom published in 1965 did not include verification of the coordination of nitrogen lone electron pair with a Pd or Pt atom, although the chemical equations were shown. Consequently, the verification of intramolecular-coordination bonds of azobenzene with the transition metals was delayed until 1969, which was later than the abovementioned report on our research on main group metal compounds in 1966.
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Omae, I. (2014). Verification of the Formation of Intramolecular-Coordination Bonds in Cyclometalation Reactions with Transition Metal Compounds. In: Cyclometalation Reactions. Springer, Tokyo. https://doi.org/10.1007/978-4-431-54604-7_3
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DOI: https://doi.org/10.1007/978-4-431-54604-7_3
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