Abstract
There are two types of solid-state reactions keeping the single crystal form: single crystal-to-single crystal (SCSC) transformations and crystalline-state reactions. In the former reactions, the crystal structures before and after the reaction are very similar to each other, but the crystallinity is not kept during the reaction. In the latter reactions, the crystallinity is kept in a whole process of the reaction. The reaction cavity was defined to estimate the void space around the reactive group. For the crystalline-state reaction, it was easy to understand the way how the void space is effectively utilized in the process of the reaction, comparing the void space before and after the reaction.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Ohashi Y, Sasada Y (1977) Nature 267:142
Ohashi Y, Yanagi K, Kurihara T, Sasada Y, Ohgo Y (1981) J Am Chem Soc 103:5805
Ohashi Y, Sasada Y, Ohgo Y (1978) Chem Lett 457
Nakanishi H, Hasegawa M, Sasada Y (1977) J Polym Sci Polymer Phys Ed 15:173
Hasegawa M (1995) Adv Phys Org Chem 30:117
Enkelmann V, Schleier G, Wegner G, Eichele H, Schwoerer M (1977) Chem Phys Lett 52:314
Enkelmann V, Leyrer RJ, Schleier G, Wegner G (1980) J Mater Sci 15:168
Nakanishi H, Jones W, Thomas JM, Hursthouse MB, Motevalli M (1981) J Phys Chem 85:3636
Honda K, Nakanishi F, Feeder N (1999) J Am Chem Soc 121:8246
Miller E, Brill TB, Rheingold AL, Fultz WC (1983) J Am Chem Soc 105:7580
Tokitoh N, Arai Y, Sasamori T, Okazaki R, Nagase S, Uekusa H, Ohashi Y (1998) J Am Chem Soc 120:433
Lauher JW, Fowler FW, Goroff NS (2008) Acc Chem Res 41:1215
Nakai H, Mizuno M, Nishioka T, Koga N, Shiomi K, Miyano Y, Irie M, Breedlove BK, Kinoshita I, Hayashi Y, Ozawa Y, Yonezawa T, Toriumi K, Isobe K (2006) Angew Chem Int Ed 45:6473
Nakai H, Nonaka T, Miyano Y, Mizuno M, Ozawa Y, Toriumi K, Koga N, Nishioka T, Irie M, Isobe K (2008) J Am Chem Soc 130:17836
Lee B, Richards FM (1971) J Mol Biol 55:379
Cohen MD (1975) Angew Chem Int Ed 14:386
Arad-Yellin R, Brunie S, Green BS, Knossow M, Tsoucalis G (1979) J Am Chem Soc 101:7529
Gavezzotti A (1983) J Am Chem Soc 105:5220
Ariel A, Askari S, Evans SV, Hwang C, Jay J, Scheffer JR, Trotter J, Walsh L, Wong YF (1987) Tetrahedron 43:1253
McBride JM (1983) Acc Chem Res 16:304
Luty T, Eckhardt CJ (1995) J Am Chem Soc 117:2441
Zimmerman HE, Zhu Z (1995) J Am Chem Soc 117:5245
Author information
Authors and Affiliations
Rights and permissions
Copyright information
© 2014 Springer Japan
About this chapter
Cite this chapter
Ohashi, Y. (2014). Crystalline-State Reaction and Reaction Cavity. In: Crystalline State Photoreactions. Springer, Tokyo. https://doi.org/10.1007/978-4-431-54373-2_2
Download citation
DOI: https://doi.org/10.1007/978-4-431-54373-2_2
Published:
Publisher Name: Springer, Tokyo
Print ISBN: 978-4-431-54372-5
Online ISBN: 978-4-431-54373-2
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)