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Infrared Spectroscopy of Water Cluster Radical Cations (H2O) + n  (n ≤ 11)

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Spectroscopic Investigations of Hydrogen Bond Network Structures in Water Clusters

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Abstract

Studies on reactive water networks provide us with substantive information on the radiation chemistry of water. Water cluster radical cations (H2O) + n have been probed with IR spectroscopy. Observed spectra were systematically analyzed and characteristic structural trends were established: Nominal water cluster cations (H2O) + n form proton-transferred type clusters H+(H2O)n−1(OH). Shapes of the hydrogen bond network are quite similar to those of H+(H2O) n . Structures of (H2O) + n can be constructed from the structures of H+(H2O) n by substituting one of the next neighbor molecules from the protonated site with an OH radical. Reactivity of water exposed to ionizing radiation should depend on hydrogen bond network structures around the created radicals. We therefore hope the findings in this study may be helpful in understanding the detailed processes of ionizing radiation-initiated reactions in liquid water and aqueous solutions.

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  1. Institute for Molecular Science, Photo-Molecular Science I, National Institutes of Natural Sciences, 38 Nishigo-Naka, Myodaiji, Okazaki, 444-8585, Japan

    Kenta Mizuse

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Mizuse, K. (2013). Infrared Spectroscopy of Water Cluster Radical Cations (H2O) + n  (n ≤ 11). In: Spectroscopic Investigations of Hydrogen Bond Network Structures in Water Clusters. Springer Theses. Springer, Tokyo. https://doi.org/10.1007/978-4-431-54312-1_5

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