Abstract
Photochromism by way of isomerization around the C═C double bond and/or intramolecular hydrogen atom transfer is discussed from the viewpoint of how large the structural change taking place is for the photochemical reaction processes of organic compounds. The large structural change could be achieved by introduction of highly rigid large substituent such as polyphenylene at the photoresponsive core or by introduction of hydrophilic substituent at the peripheries of large dendritic molecules. The occurrence of large structural change can be monitored by fluorescence spectroscopy as well as transient spectroscopy and GPC analysis. The intramolecular hydrogen bonding affects the electronic state to change the color between the isomer having intramolecular hydrogen bonding and the isomer not having intramolecular hydrogen bonding. These hydrogen-bonded compounds underwent intramolecular hydrogen atom transfer, which is a small structural change, to give the tautomer with different color from the normal form. The large structural change of dendritic molecules and the color change of hydrogen-bonded compounds are summarized in this chapter.
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Kataoka, K., Kobayashi, T., Arai, T. (2013). Photochromism of Organic Compounds Undergoing Isomerization Around the C═C Double Bond and/or Intramolecular Hydrogen Atom Transfer: Small and Large Structural Change. In: Irie, M., Yokoyama, Y., Seki, T. (eds) New Frontiers in Photochromism. Springer, Tokyo. https://doi.org/10.1007/978-4-431-54291-9_13
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