Skip to main content
SpringerLink
Log in
Book cover

Visualization of Hydrogen-Bond Dynamics pp 11–31Cite as

Principles and Techniques

  • Chapter
  • First Online:

  • 785 Accesses

Part of the book series: Springer Theses ((Springer Theses,volume 125))

Abstract

I describe a brief summary of quantum mechanics and principles of scanning tunneling microscopy (STM) in this chapter. Quantum tunneling is an important concept to describe the transportation of small particles, like electron and hydrogen. In Sect. 2.1 I focus on H-atom tunneling in a double minimum potential that is the simplest but a ubiquitous system in physics and chemistry. Quantum tunneling of electron directly relates to the principle of the STM. In Sect. 2.2 the principles and applications of STM are described. I focus on the inelastic electron tunneling process in an STM junction, which can be applied to the vibration spectroscopy and reaction control of single molecules.

This is a preview of subscription content, log in via an institution.

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   84.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD   109.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

References

  1. J. Brickmann, H. Zimmermann, J. Chem. Phys. 50, 1608 (1969)

    Article  CAS  Google Scholar 

  2. K. Liu, J.D. Gruzan, R.S. Saykally, Science 271, 929 (1996)

    Article  CAS  Google Scholar 

  3. F. Hund, Z. Phys. 43, 803 (1927)

    Google Scholar 

  4. A.C.P. Alves, J.M. Hollas, Mol. Phys. 23, 927 (1972)

    Article  CAS  Google Scholar 

  5. A.C.P. Alves, J.M. Hollas, Mol. Phys. 25, 1305 (1973)

    Article  CAS  Google Scholar 

  6. T. Baba, T. Tanaka, I. Morino, K.M.T. Yamada, K. Tanaka, J. Chem. Phys. 110, 4131 (1999)

    Article  CAS  Google Scholar 

  7. W.F. Rowe Jr, R.W. Duerst, E.B. Wilson, J. Am. Chem. Soc. 98, 4021 (1976)

    Article  CAS  Google Scholar 

  8. S.L. Baughcum, Z. Smith, E.B. Wilson, R.W. Duerst, J. Am. Chem. Soc. 106, 2260 (1984)

    Article  CAS  Google Scholar 

  9. D. Borgis, J.T. Hynes, J. Chem. Phys. 94, 3619 (1991)

    Article  CAS  Google Scholar 

  10. D. Borgis, J.T. Hynes, Chem. Phys. 170, 315 (1993)

    Article  CAS  Google Scholar 

  11. G. Binnig, H. Rohler, Helv. Phys. Acta 55, 725 (1982)

    Google Scholar 

  12. R. Wiesemdanger, Scanning Probe Microscopy and Spectroscopy (Cambridge University Press, Cambridge, 1994)

    Google Scholar 

  13. J.A. Strocsio, W.J. Kaiser, T. Lucatorto, M.D. Graef, Scanning Tunneling Microscopy (Academic Press, Methods of Experimental Physics, 1994)

    Google Scholar 

  14. C. Bai, Scanning tunneling microscopy and its applications (Springer, Berlin, 2000)

    Google Scholar 

  15. C.J. Chen, Introduction to Scanning Tunneling Microscopy (Oxford University Press, Monograph on the Physics and Chemistry of Materials, 2007)

    Book  Google Scholar 

  16. J. Tersoff, D.R. Hamann, Phys. Rev. Lett. 50, 1998 (1983)

    Article  CAS  Google Scholar 

  17. R.C. Jaklevic, J. Lambe, Phys. Rev. Lett. 17, 1139 (1966)

    Article  CAS  Google Scholar 

  18. J. Lambe, R.C. Jaklevic, Phys. Rev. 165, 821 (1968)

    Article  CAS  Google Scholar 

  19. P.K. Hansma, Phys. Rep. 30C, 145 (1977)

    Article  CAS  Google Scholar 

  20. W.H. Weinberg, Annu. Rev. Phys. Chem. 29, 115 (1978)

    Article  CAS  Google Scholar 

  21. T. Wolfram (ed.), Inelastic Electron Tunneling Spectroscopy (Springer-Verlag, Berlin, 1978)

    Google Scholar 

  22. P.K. Hansma (ed.), Tunneling Spectroscopy (Plenum, NewYork, 1982)

    Google Scholar 

  23. B.C. Stipe, M.A. Rezaei, W. Ho, Science 280, 1732 (1998)

    Article  CAS  Google Scholar 

  24. B.N.J. Persson, J.E. Demuth, Solid State Commun. 57, 769 (1986)

    Article  CAS  Google Scholar 

  25. B.N.J. Persson, A. Baratoff, Phys. Rev. Lett. 59, 339 (1987)

    Article  CAS  Google Scholar 

  26. N.D. Lang, A.R. Williams, PRB 18, 616 (1977)

    Article  Google Scholar 

  27. M. Kawai, T. Komeda, Y. Kim, Y. Sainoo, S. Katano, Phil. Trans. R. Soc. Lond. A 362, 1163 (2004)

    Article  CAS  Google Scholar 

  28. M. Ohara, Y. Kim, S. Yanagisawa, Y. Morikawa, M. Kawai, Phys. Rev. Lett. 100, 136104 (2008)

    Article  Google Scholar 

  29. N. Lorente, M. Persson, Phys. Rev. Lett. 85, 2997 (2000)

    Article  CAS  Google Scholar 

  30. N. Mingo, K. Makoshi, Phys. Rev. Lett. 84, 3694 (2000)

    Article  CAS  Google Scholar 

  31. T. Mii, S. Tikhodeev, H. Ueba, Surf. Sci. 502, 26 (2002)

    Article  Google Scholar 

  32. T. Mii, S.G. Tikhodeev, H. Ueba, Phys. Rev. B 68, 205406 (2003)

    Article  Google Scholar 

  33. M. Paulsson, T. Frederiksen, H. Ueba, N. Lorente, M. Brandbyge, Phys. Rev. Lett. 100, 226604 (2008)

    Article  Google Scholar 

  34. J.R. Hahn, H.J. Lee, W. Ho, Phys. Rev. Lett. 85, 1914 (2000)

    Article  CAS  Google Scholar 

  35. M. Alducin, D. Sánchez-Portal, A. Arnau, N. Lorente, Phys. Rev. Lett. 104, 136101 (2010)

    Article  Google Scholar 

  36. M. Galperin, M.A. Ratner, A. Nitzan, J. Chem. Phys. 121, 11965 (2004)

    Article  CAS  Google Scholar 

  37. L.J. Lauhou, W. Ho, Rev. Sci. Instrum. 72, 216 (2001)

    Article  Google Scholar 

  38. N. Lorente, M. Persson, L.J. Lauhon, W. Ho, Phys. Rev. Lett. 86, 2593 (2001)

    Article  CAS  Google Scholar 

  39. N. Okabayashi, M. Paulsson, H. Ueba, Y. Konda, T. Komeda, Phys. Rev. Lett. 104, 077801 (2010)

    Article  Google Scholar 

  40. A. Troisi, M.A. Ratner, J. Chem. Phys. 125, 214709 (2006)

    Article  Google Scholar 

  41. B.C. Stipe, M.A. Rezaei, W. Ho, S. Gao, M. Persson, B.I. Lundqvist, Phys. Rev. Lett. 78, 4410 (1997)

    Article  CAS  Google Scholar 

  42. B.C. Stipe, M.A. Rezaei, W. Ho, Science 279, 1907 (1998)

    Article  CAS  Google Scholar 

  43. B.C. Stipe, M.A. Rezaei, W. Ho, Phys. Rev. Lett. 81, 1263 (1998)

    Article  CAS  Google Scholar 

  44. L. Bartels, M. Wolf, T. Klamroth, P. Saalfrank, A. Kühnle, G. Meyer, K.-H. Rieder, Chem. Phys. Lett. 313, 544 (1999)

    Article  CAS  Google Scholar 

  45. N. Lorente, J.I. Pascual, Phil. Trans. 362, 1227 (2004)

    Article  CAS  Google Scholar 

  46. J.I. Pascual, N. Lorente, Z. Song, H. Conrad, H.-P. Rust, Nature 423, 525 (2003)

    Article  CAS  Google Scholar 

  47. N. Lorente, J.I. Pascual, H. Ueba, Surf. Sci. 593, 122 (2005)

    Article  CAS  Google Scholar 

  48. L.J. Lauhon, W. Ho, Surf. Sci. 451, 219 (2000)

    Article  CAS  Google Scholar 

  49. L.J. Lauhon, W. Ho, J. Phys. Chem. A 104, 2463 (2000)

    Article  CAS  Google Scholar 

  50. Y. Kim, T. Komeda, M. Kawai, Surf. Sci. 502, 7 (2002)

    Article  Google Scholar 

  51. Y. Kim, T. Komeda, M. Kawai, Phys. Rev. Lett. 89, 126104 (2002)

    Article  Google Scholar 

  52. F. Moresco, G. Meyer, K.-H. Rieder, H. Tang, A. Gourdon, C. Joachim, Phys. Rev. Lett. 86, 672 (2001)

    Article  CAS  Google Scholar 

  53. Y. Sainoo, Y. Kim, T. Okawa, T. Komeda, H. Shigekawa, M. Kawai, Phys. Rev. Lett. 95, 246102 (2005)

    Article  Google Scholar 

  54. J.R. Hahn, W. Ho, J. Chem. Phys. 131, 044706 (2009)

    Article  CAS  Google Scholar 

  55. M. Parschau, D. Passerone, K.-H. Rieder, a. H. J. Hug, and K.-H. Ernst. Angew. Chem. Int. Ed. 48, 4065 (2009)

    Article  CAS  Google Scholar 

  56. S. Katano, Y. Kim, Y. Kagata, M. Kawai, J. Phys. Chem. C 113, 19277 (2009)

    Article  CAS  Google Scholar 

  57. S. Katano, Y. Kim, Y. Kagata, M. Kawai, J. Phys. Chem. C 114, 3003 (2010)

    Article  CAS  Google Scholar 

  58. H.-J. Shin, J. Jung, K. Motobayashi, S. Yanagisawa, Y. Morikawa, Y. Kim, M. Kawai, Nature Mater. 9, 442 (2010)

    Article  CAS  Google Scholar 

  59. V. Simic-Milosevic, M. Mehlhorn, K.-H. Rieder, J. Meyer, K. Morgenstern, Phys. Rev. Lett. 98, 116102 (2007)

    Article  CAS  Google Scholar 

  60. V. Simic-Milosevic, K. Morgenstern, J. Am. Chem. Soc. 131, 416 (2009)

    Article  CAS  Google Scholar 

  61. V. Simic-Milosevic, J. Meyer, K. Morgenstern, Angew. Chem. Int. Ed. 48, 4061 (2009)

    Article  CAS  Google Scholar 

  62. V. Simic-Milosevic, J. Meyer, K. Morgenstern, Phys. Chem. Chem. Phys. 10, 1916 (2008)

    Article  CAS  Google Scholar 

  63. W. Wang, X. Shi, M. Jin, C. Minot, M.A. Van Hove, J.-P. Collin, N. Lin, ACS Nano 4, 4929 (2010)

    Article  CAS  Google Scholar 

  64. K. Motobayashi, Y. Kim, H. Ueba, and Maki Kawai. Phys. Rev. Lett. 105, 076101 (2010)

    Article  Google Scholar 

  65. D.M. Eigler, C.P. Lutz, W.E. Rudge, Nature 352, 600 (1991)

    Article  CAS  Google Scholar 

  66. R.E. Walkup, D.M. Newns, P. Avouris, Phys. Rev. B 48, 1858 (1993)

    Article  CAS  Google Scholar 

  67. S. Gao, M. Persson, B.I. Lundqvist, Phys. Rev. B 55, 4825 (1997)

    Article  CAS  Google Scholar 

  68. T. Komeda, Y. Kim, Maki Kawai, B. N. J. Persson, and H. Ueba, Science, 295, 2055 (2002)

    Google Scholar 

  69. H. Ueba, T. Mii, N. Lorente, B.N.J. Persson, J. Chem. Phys. 123, 084707 (2005)

    Article  CAS  Google Scholar 

  70. B.N.J. Persson, H. Ueba, Surf. Sci. 502, 18 (2002)

    Article  Google Scholar 

  71. A.J. Mayne, G. Dujardin, G. Comtet, D. Riedel, Chem. Rev. 106, 4355 (2006)

    Article  CAS  Google Scholar 

  72. A. van Houselt, H.J.W. Zandvliet, Rev Mod Phys 82, 1593 (2010)

    Article  Google Scholar 

  73. P. Liljeroth, J. Repp, G. Meyer, Science 317, 1206 (2007)

    Article  Google Scholar 

  74. T.-C. Shen, C. Wang, G.C. Abeln, J.R. Tucker, J.W. Lyding, Ph Avouris, R.E. Walkup, Science 268, 1590 (1995)

    Article  CAS  Google Scholar 

  75. D.M. Eigler, E.K. Schweizer, Nature 344, 524 (1990)

    Article  CAS  Google Scholar 

  76. J.A. Stroscio, D.M. Eigler, Science 254, 1319 (1991)

    Article  CAS  Google Scholar 

  77. U. Dürig, O. Züger, D.W. Pohl, J. Microscopy 152, 259 (1988)

    Article  Google Scholar 

  78. L. Bartels, G. Meyer, K.-H. Rieder, Phys. Rev. Lett. 79, 697 (1997)

    Article  CAS  Google Scholar 

  79. P.H. Beton, A.W. Dunn, P. Moriarty, Appl. Phys. Lett. 67, 1075 (1995)

    Article  CAS  Google Scholar 

  80. J.K. Gimzewski, C. Joachim, R.R. Schlittler, V. Langlais, H. Tang, I. Johannsen, Science 281, 531 (1998)

    Article  CAS  Google Scholar 

  81. F. Moresco, G. Meyer, K.-H. Rieder, H. Tang, A. Gourdon, C. Joachim, Phys. Rev. Lett. 87, 088302 (2001)

    Article  CAS  Google Scholar 

  82. L. Grill, K.-H. Rieder, F. Moresco, G. Rapenne, S. Stojkovic, X. Bouju, C. Joachim, Nat. Nanotech. 2, 95 (2007)

    Article  CAS  Google Scholar 

  83. M. Ternes, C.P. Lutz, C.F. Hirjibehedin, F.J. Giessibl, A.J. Heinrich, Science 319, 1066 (2008)

    Article  CAS  Google Scholar 

  84. N. Oyabu, Y. Sugimoto, M. Abe, Ó. Custance, S. Morita, Nanotechnology 16, S112 (2005)

    Article  CAS  Google Scholar 

  85. Y. Sugimoto et al., Nat. Mater. 4, 156 (2005)

    Article  CAS  Google Scholar 

  86. Y. Sugimoto et al., Phys. Rev. Lett. 98, 106104 (2007)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Fritz-Haber Institute of the Max-Planck Society, Berlin, Germany

    Dr. Takashi Kumagai

Authors
  1. Dr. Takashi Kumagai
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Takashi Kumagai .

Rights and permissions

Reprints and permissions

Copyright information

© 2012 Springer Japan

About this chapter

Cite this chapter

Kumagai, T. (2012). Principles and Techniques. In: Visualization of Hydrogen-Bond Dynamics. Springer Theses, vol 125. Springer, Tokyo. https://doi.org/10.1007/978-4-431-54156-1_2

Download citation

Publish with us

Policies and ethics

Search

Navigation