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Grundlagen der metallorganischen Komplexkatalyse pp 72–94Cite as

Hydroformylierung von Olefinen und Fischer-Tropsch-Synthese

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Zusammenfassung

Im Zusammenhang mit Untersuchungen, unter den Bedingungen der Fischer-Tropsch-Synthese (Synthese von Kohlenwasserstoffen aus CO/H2) sauerstoffhaltige Verbindungen als Hauptprodukte zu erhalten, wurde 1938 von Otto Roelen bei der Ruhrchemie die Umsetzung von Ethen mit Synthesegas (CO/H2) zu Propionaldehyd in Gegenwart eines heterogenen Cobalt–Thorium-Katalysators entdeckt und bis zur technischen Reife entwickelt. Beim Einsatz terminaler Olefine als Substrat werden entweder n-Aldehyde oder – die zumeist unerwünschten – Isoaldehyde gebildet.

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Authors
  1. Prof.Dr. Dirk Steinborn
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Steinborn, D. (2010). Hydroformylierung von Olefinen und Fischer-Tropsch-Synthese. In: Grundlagen der metallorganischen Komplexkatalyse. Vieweg+Teubner. https://doi.org/10.1007/978-3-8348-9375-8_5

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