Abstract
Transport properties of ions in gases (i.e. ion mobilities and diffusion coefficients) are of intrinsic, fundamental and applied interest /1/. On the one hand they can give information about the ion-neutral interaction potential; on the other hand they can be used to describe quantitatively the behavior of ions moving in a neutral buffer gas and related charge transport phenomena and are required together with ionization cross section data /2/ for a quantitative understanding of electrical discharges.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Mc Daniel, E.W., Mason, E.A.: The mobility and diffusion of ions in gases. New York: Wiley 1973.
Märk, T.D., Dunn, G.H.: Electron impact ionization. Wien: Springer. 1984.
Nernst, W.: Zur Kinetik der in Lösung befindlicher Körper. Z. Phys. Chem. 2, 613–637 (1888).
Townsend, J.S.: The diffusion of ions into gases. Phil. Trans. A 193, 129–158 (1900).
Townsend, J.S.: The charges on positive and negative ions in gases. Proc. Roy. Soc. A 80, 207–211 (1908), and, The charges on ions in gases, and the effect of water vapor on the motion of negative ions. Proc. Roy. Soc. A 81, 464–471 (1908).
Thomson, J.J., Thomson, G.P.: Conduction of electricity through gases. Vol. I (unrevised reprint of 1928 3rd edition). New York: Dover. 1969.
Loeb, L.B.: Basic processes of gaseous electronics. Berkeley: Univ. Calif. Press. 1960.
Massey, H.S.W.: Electronic and ionic impact phenomena. Vol. III. Oxford: Clarendon. 1971
Viehland, L.A., Mason, E.A., Morrison, W.F., Flannery, M.R.: Tables of transport collision integrals for (n, 6,4) ion-neutral potentials. Atom. Data Nucl. Data Tabl. 16, 495–514 (1975)
Ellis, H.W., Pai, R.Y., Mc Daniel, E.W., Mason, E.A., Viehland, L.A.: Transport properties of gaseous ions over a wide energy range. Atom. Data Nucl. Data Tabl. 16, 177–210 (1976).
Ellis, H.W., Mc Daniel, E.W., Albritton, D.L., Viehland, L.A., Lin, S.L., Mason, E.A.: Transport properties of gaseous’ions over a wide energy range. Part II. Atom. Data Nucl. Data Tabl. 22, 179–217 (1978).
Viehland, L.A., Mason, E.A.: Gaseous ion mobility and diffusion in electric fields of arbitrary strength. Ann. Phys. 110, 287–328 (1978).
Kumar, K., Skullerud, H.R., Robson, R.E.: Kinetic theory of charged particle swarms in neutral gases. Aust. J. Phys. 33, 343–448 (1980).
Märk, T.D., Castieman, Jr. A.W.: Experimental studies on cluster ions. Adv. Atom. Molec. Phys. 20 (1984).
Crompton, R.W., Elford, M.T., Gascoigne, J.: Precision measurements of the Townsend energy ratio for electron swarms in highly uniform electric fields. Austral. J. Phys. 18, 409–436 (1965)
Dutton, J., Llewellyn Jones, F., Rees, W.D., Williams, E.M.: Drift and diffusion of ions in hydrogen. Phil. Trans. Roy, A 259, 339–354 (1966).
Dutton, J., Howells, P.: The motion of oxygen ion in oxygen. J. Phys. B1, 1160–1170 (1968).
Skullerud, H.R.: Measurement of positive ion diffusion in argon and hydrogen. In: Proc. 7th Int. Conf. Phenom. ionized Gases, p. 50–53 Belgrade: Gradevinska Knjiga. 1965.
Tunnicliffe, R.J., Rees, J.A.: The determination of Townsend energy ratio (k.) for positive potassium ions in hdydrogen and nitrogen. in: Proc. 8th Int. Conf. Phenom. Ionized Gases, p. 14. Wien: Springer. 1967.
Fleming, I.A., Tunnicliffe, R.J., Rees, J.A.: The drift and diffusion of potassium ions in nitrogen. J. Phys. D2, 551–556 (1969).
Fleming, I.A., Tunnicliffe, R.J., Rees, J.A.: Concerning determinations of the drift velocity and lateral diffusion of positive ions in hydrogen. J.Phys. B2, 780–789 (1969).
Miller, T.M., Moseley, J.T., Martin, D.W., Mc Daniel, E.W.: Reactions of H+ in H2 and D+ in D2; Mobilities of hydrogen and alkali ions in H2 and D2 gases. Phys. Rev. 173, 115–122 (1968).
Moseley, J.T., Snuggs, R.M., Martin, D.W., Mc Daniel, E.W.: Longitudinal agd transyerse diffusion coefficients of mass identified N and N2 ions in nitrogen. Phys. Rev. Lett. 21, 873–878 (1968).
Moseley, J.T., Gatland, I.R., Martin, D.W., Mc Daniel, E.W.: Measurement of transport properties of ions in gases: Results for K+ ions in N2. Phys. Rev. 178, 234–239 (1969).
Moseley, J.T., Snuggs, R.M., Martin, D.W., Mc Daniel, E.W.: Mobilities, diffusion coefficients, and reaction rates of mass-identified nitrogen ions in nitrogen. Phys. Rev. 178, 240–248 (1969).
Gray, D.R., Rees, J.A.: The lateral diffusion of mass identified positive ions in oxygen. J. Phys. B5, 1048–1055 (1972).
Alger, S.R., Stefansson, T. Rees, J.A.: Measurements of the lateral diffusion of O2 + ions in oxygen, N3 + and N4 + ions in nitrogen, and CO+.CO ions in carbon monoxide. J. Phys. B11, 3289–3297 (1978).
Varney, R.N., Helm, H., Alge, E., Störi, H., Lindinger, W.: Transverse diffusion of Ar+ and Ar2+ in Ar at 298 K. J. Phys. B14, 1695–1705 (1981)
Sejkora, G., Hilchenbach, M., Grössl, M., Helm, H., Elford, M.T., Lindinger, W., Märk, T.D.: Lateral diffusion of mass identified ions: experimental. In: Proc. 3rd Symp. Atom. Surf. Phys. (Lindinger, W., et al., Eds.) p. 322–326. Maria Aim. 1982.
Sejkora, G., Hilchenbach, M., Elford, M.T., Märk, T.D.: Lateral diffusion of mass identified ions; low current stable ion source. Europhys. Conf. Abstr. 6D, 143,1982)
Girstmair, P., Sejkora, G., BryanJ, H.C., Märk, T.D.: Transverse diffusion of the (N2) 2 + cluster ion. In: Proc. XIIIth Int. Conf. Phys. Electr. Atom. Coll., post deadline paper, p. 11, Berlin. 1983.
Sejkora, G., Bryant, H.C., Girstmair, P., Hesche, M., Djuric, N., Märk, T.D.: Transverse diffusion of mass identified ions in their parent gas. In: Proc. 3rd Intern. Swarm Seminar (Lindinger, W., et al., Eds.) p. 201–205. Innsbruck. 1983.
Sejkora, G., Ijlärk, T.D.: Transverse diffusion of mass identified N2 ions in nitrogen. Chem. Phys. Lett. 97, 123–126 (1983).
Sejkora, G., Girstmair, P., Bryant, H.C, Märk, T.D.: The transverse diffusion of Ar+ and Ar2+ in Ar. Phys. Rev. A, in print (1984).
Märk, T.D., Sejkora, G., Girstmair, P., Hesche, M., Märk, E., Bryant, H.C., Elford, M.T.: Transverse ion diffusion studied with the radial ion distribution method. In: Proc. 4th Symp. Atom. Surf. Phys. (Howorka, F et al., Eds.), 144–154, Maria Aim. (1984).
MSrk, T.D., Girstmair, P., Sejkora, G., Hesche, M., Mark, E., Bryant, H.C.: Transverse ion diffusion in rare gases. In: Proc. 7th ESCAMPIG, Bari. 1984.
Stefannson, T.: Diffusion of lithium ions in argon. In: Proc. 3rd Intern. Swarm Seminar (Lindinger, W., et al., Eds) p. 227–233. Innsbruck. 1983.
Mc Daniel, E.W., Moseley, J.T.: Tests of the Wannier expressions for diffusion coefficients of gaseous ions in electric fields. Phys. Rev. A3, 1040–1044 (1971).
Robson, R.E.: A thermodynamic treatment of anisotropic diffusion in an electric field. Aust. J. Phys. 25, 685–693 (1972).
Wannier, G.H.: On a conjecture about diffusion of gaseous ions. Austr. J. Phys. 26, 897–900 (1973).
Skullerud, H.R.: Monte-Carlo investigations of the motion of gaseous ions in electrostatic fields. J. Phys. B6, 728–742 (1973).
Whealton, J.H., Mason, E.A., Robson, R.E.: Composition dependence of ion-transport coefficients in gas mixtures. Phys. Rev. A9, 1017–1020 (1974).
Whealton, J.H., Mason, E.A.: Transport coefficients of gaseous ions in an electric field. Ann. Phys. 84, 8–38 (1974).
Viehland, L.A., Mason, E.A.: On the relation between gaseous ion mobility and diffusion coefficients at arbitrary electric field strengths. J. Chem. Phys. 63, 2913–2915 (1975).
Viehland, L.A., Mason, E.A.: Gaseous ion mobility in electric fields of arbitrary strength. Ann. Phys. 91, 499–533 (1975).
Skullerud, H.R.: On the relation between the diffusion and mobility of gaseous ions moving in strong electric fields. J. Phys. B9, 535–546 (1976).
Robson, R.E.: On the generalized Einstein relation for gaseous ions in an electrostatic field. J. Phys. B9, L 337-L 339 (1976).
Skullerud, H.R.: Progress in the transport theory of weakly ionized gases. In: Proc. 13th Int. Conf. Phys. Ionized Gases, p. 303–319. Berlin, 1977.
Viehland, L.A., Lin, S.L.: Application of the three- temperature theory of gaseous ion transport. Chem. Phys. 43, 135–144 (1979).
Lin, S.L., Viehland, L.A., Mason, E.A.: Three-temperature theory of gaseous ion transport- Chem. Phys. 37, 411–424 (1979).
Sinha, S., Lin, S.L., Bardsley, J.N.: The mobility of He+ in He. J. Phys. B12, 1613–1622 (1979).
Skullerud, H.R., Forsth, L.R.: Perturbation treatment of thermal motions in gaseous ion-transport theory. J. Phys. B12, 1881–1888 (1979).
Waldman, M., Mason, E.A.: Generalized Einstein relations from a three-temperature theory of gasous ion transport. Chem. Phys. 58, 121–144 (1981)
Viehland, L.A., Mason, E.A. Lin, S.L.: Test of the interaction potentials of H- and Br ions with He atoms and of Cl- ions with Ar atoms. Phys. Rev. A 24, 3004–3009 (1981).
Viehland, L.A., Mason, E.A.: Well depths of XeF- and XeCl- from ion transport data. Chem. Phys. Lett. 83, 298–300 (1981).
Viehland, L.A.: Gaseous ion transport coefficients. Chem. Phys. 70, 149–156 (1982).
Waldman, M., Mason, E.A., Viehland, L.A.: Influence of resonant charge transfer on ion diffusion and generalized Einstein relations. Chem. Phys. 66, 339–349 (1982).
Skullerud, H.R.: Calculation of ion drift and diffusion basis set expansions with non-gaussian weight functions. In: Proc. 3rd Intern. Swarm Seminar (Lindinger, W., et al., Eds) p. 212–217. Innsbruck. 1983.
Pai, R.Y., Ellis, H.W., Akridge, G.R., McDaniel, E.W.: Longitudinal diffusion coefficients of Li+ and Na+ ions in He, Ne and Ar: Experimental test of the generalized Einstein relation. J. Chem. Phys. 63, 2916–2918 (1975).
Pai, R.Y., Ellis, H.W., Akridge, G.R., Mc Daniel, E.W.: Generalized Einstein relation: Application to ions in molecular gases. Phys. Rev. A12, 1781–1784 (1975).
Ellis, H.W., Thackston, M.G., Pai, R.Y., Mc Daniel, E.W.: Longitudinal diffusion coefficients of Rb+ ions in He, Ne, Ar, H2, N2, O2 and CO2 J. Chem. Phys. 65, 3390–3391 (1976)
Pai, R.Y., Ellis, H.W., Mc Daniel, E.W.: Th generalized Einstein relation-application to Li and Na ions in hydrogen gas. J. Chem. Phys. 64, 4238–4239 (1976).
Eisele, F.L., Thackston, M.G., Pope, W.M., Gatland, I.R., Ellis, H.W., Mc Daniel, E.W.: Experimental test of the generalized Einstein relation for Cs ions in molecular gases: H2, N2, O2, CO, and CO2 J. Chem. Phys. 67, 1278- 1279 (1977)
Thackston, M.G., Eisele, F.L., Pope, W.M., Ellis, H.W., Mc Daniel, E.W.: Farther tests of the generalized Einstein relation: Cs+ ions in Ar, Kr, and Xe. J. Chem. Phys.68, 3950–3951 (1978).
Morrison, W.F., Akridge, G.R., Ellis, H.W., Pai, R.Y., Mc Danel, E.W., Viehland, L.A., Mason, E.A.: Test of the Li -He interaction potential. J. Chem. Phys. 63, 2238–2241 (1975).
Viehland, L.A. Mason, E.A., Stevens, T.H., Monchik, L.: Test of the H2 + He interaction poteçtial. Comparison of the interactions of He with H+, H2 +, and H3 +. Chem. Phys. Lett. 44, 360–362 (1976).
Viehland, L.A., Harrington, M.M., Mason, E.A.: Direct determination of ion-neutral molecule interaction potentials from gaseous ion mobility measurements. Chem. Phys. 22, 433–441 (1976).
Gatland, I.R., Morrison, W.F., Ellis, H.W., Thackston, M.G., Mc Daniel, E.W., Alexander, M.H., Viehland, L.A., Mason, E.A.: The Li +-He interaction potential. J. Chem. Phys. 66, 5121–5125 (1977).
Gatland, I.R., Viehland, L.A., Mason, E.A.: Tests of alkali ion-inert gas interaction potentials by gaseous ion mobility experiments. J. Chem. Phys. 66, 537–541 (1977)
Gatland, I.R., Thackston, M.G., Pope, W.M., Eisele, F.L., Ellis, H.W., Mc Daniel, E.W.: Mobilities and inter- action potentials for Cs+ -Ar, Cs+ -Kr, and Cs+ -Xe. J. Chem. Phys. 68, 2775–2778 (1978).
Gatland, I.R., Lamm, D.R., Thackston, M.G., Pope, W.M., Eisele, F.L., Ellis, H.W., Mc Danjel, E.W: Mobilitie and interaction potentials for Rb+ -Ar, Rb+ -Kr, and Rb+ -Xe. J. Chem. Phys. 69, 4951–4954 (1978).
Thackston, M.G., Eisele, F.L., Pope, W.M., Ellis, H.W., Mc Daniel, E.W., Gatland, I.R.: Mobility of Cl ions in Xe gas and the CI- -Xe interaction potential. J. Chem. Phys. 73, 3183–3185 (1980).
Lamm, D.R., Thackston, M.G., Eisele, F.L., Ellis, H.W., Twist, J.R., Pope, W.M., Gatland, I.R., Mc Janiel, E.W.: Mobilities and interaction potentials for K+ -Ar, K+ -Kr, and K+ -Xe. J. chem. Phys. 74, 3042–3045 (1981).
Takebe, M.: The generalized mobility curve for alkali- ions in rare gases: Clustering reactions and mobility curves. J. Chem. Phys. 78, 7223–7226 (1983).
Cassidy, R.A., Elford, M.T.: The mobility of Li+ and K+ ions in helium and argon at 294 and 80 K and derived interaction potentials. In: Proc. 3rd Intern. Swarm Seminar (Lindinger, W., et al., Eds) p. 222–226. Innsbruck. 1983.
Llewellyn Jones, F.: The energy of agitation of positive ions in argon. Proc. Phys. Soc. 47, 74–85 (1935).
Crompton, R.W.: The present status of the Townsend- Huxley experiment in theory and practice. Aust. J. Phys. 25, 409–417 (1972).
Mc Daniel, E.W., Cermak, V., Dalgarno, A., Ferguson, E.E., Friedman, L.: Ion-molecule reactions. New York: Wiley. 1969.
Mc Daniel, E.W., Mc Dowell, M.R.C.: Case Studies in Atomic Collision Physics I (Eds.). Amsterdam: North Holland. 1969.
Rees, J.A., Alger, B.A.: Transport properties of mass- identified ions in oxygen, nitrogen, carbon dioxide and carbon monoxide. Proc. lEE 126, (1979) 356–360.
Huxley, L.G.H., Crompton, R.W.: The diffusion and drift of electrons in gases. New York: Wiley. 1974.
Elford, M.T.: Private communication. 1981.
Hilchenbach, M.: Radioaktive lonenquelle mit Townsend- lawinenverStärkung. Diplomarbeit. Universität Innsbruck. 1982.
Sejkora, G.: Bestimmung transversaler Diffusionskoeffizienten als Funktion der reduzierten Feldstärke. Aufbau einer mikroprozessorgesteuerten Apparatur und Messungen in Argon und Stickstoff. Dissertation. Universität Innsbruck. 1982.
Märk, T.D., Helm, H.: Mass spectrometry as a technique for studying atomic properties of low pressure plasmas (particle extraction and detection system). Acta Physica Austriaca 40, 158–180 (1974).
Helm, H., Märk, T.D., Lindinger, W.: Plasma sampling -a versatile tool in plasma chemistry. J. Pure Appi. Chem. 52, 1739–1757 (1980).
Grossi, M., Langenwalter, M., Helm, H., Märk, T.D.: Molecular ion formation in decaying plasmas produced in pure argon and krypton, J. Chem. Phys. 74, 1728–1735 (1981)
Wannier, G.H.: Motion of gaseous ions in strong electric fields. Bell Syst. Techn. J. 32, 170–254 (1953)
Varney, R.N., Pal, Märk,T.D.: Properties of the ionic systems N4, O4 and O4 -. Acta Physica Austriaca 38, 287–294 (1973).
Rees, J.A.: Transport properties of ions in electronegative gases. Vacuum 24, 603–607 (1974).
Naidu, M.S., Prasad, A.N.: Mobility and diffusion of negative ions in sulphur hexafluoride. J. Phys. D3, 951–956 (1970).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1984 Springer-Verlag/Wien
About this chapter
Cite this chapter
Märk, E., Märk, T.D. (1984). Transverse Ion Diffusion in Gases. In: Lindinger, W., Märk, T.D., Howorka, F. (eds) Swarms of Ions and Electrons in Gases. Springer, Vienna. https://doi.org/10.1007/978-3-7091-8773-9_5
Download citation
DOI: https://doi.org/10.1007/978-3-7091-8773-9_5
Publisher Name: Springer, Vienna
Print ISBN: 978-3-7091-8775-3
Online ISBN: 978-3-7091-8773-9
eBook Packages: Springer Book Archive