Skip to main content
SpringerLink
Log in

Enrichment Techniques for Inorganic Micro- and Trace Analysis

  • Conference paper
Book cover Nature, Aim and Methods of Microchemistry

Abstract

Although modern instrumental techniques of determination are highly sensitive and selective, enrichment techniques are generally required before the determination in micro- and trace analysis to extend the lower limit of determination, to improve the precision and accuracy of analytical results, and to widen the scope of the determination techniques.

This paper reviews the present status of enrichment techniques, special emphasis being given to multi element techniques and to techniques for differentiating various chemical states of a trace element. Also, microscale operations and mechanization and automation of enrichment techniques are briefly discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. A. Mizuike, in G.H. Morrison, ed., “Trace Analysis: Physical Methods”, Wiley, New York (1965) p. 103.

    Google Scholar 

  2. J. Minczewski, in W.W. Meinke and B. F. Scribner, eds., “Trace Characterization: Chemical and Physical”, NBS Monograph 100 (1967), p.385

    Google Scholar 

  3. A. Mizuike, “Trace Analysis”, Tokyo Kagaku Dojin, Tokyo (1968).

    Google Scholar 

  4. O.G. Koch and G.A. Koch-Dedic, “Handbuch der Spurenanalyse”, 2. Aufl., Springer, Berlin (1974).

    Google Scholar 

  5. E.B. Sandel and H. Onishi, “Photometrie Determination of Traces of Metals: General Aspects”, 4th ed., Wiley, New York (1978).

    Google Scholar 

  6. Yu.A. Zolotov, Pure & Appl. Chem., 50, 129 (1978).

    Article  CAS  Google Scholar 

  7. G. Tölg, Pure & Appl. Chem., 50, 1075 (1978).

    Article  Google Scholar 

  8. E. Jackwerth, A. Mizuike, Yu.A. Zolotov, H. Berndt, R. Höhn, and N.M. Kuzmin, Pure & Appl. Chem., 51, 1195 (1979).

    Article  Google Scholar 

  9. M. Zief and R. Speights, eds., “U1trapurity: Methods and Techniques”, Marcel Dekker, New York (1972).

    Google Scholar 

  10. M. Zief and J.W. Mitchell, “Contamination Control in Trace Element Analysis”, Wiley, New York (1976).

    Google Scholar 

  11. A. Mizuike and M. Pinta, Pure & Appl. Chem., 50, 1519 (1978).

    Article  Google Scholar 

  12. M.P. Semov, in Kh. I. Zil’bershtein, ed., “Spectrochemical Analysis of Pure Substances”, English translation by J.H. Dixon, Adam Hilger Ltd., Bristol (1977) p. 231.

    Google Scholar 

  13. Yu.A. Zolotov, “Extraction of Chelate Compounds”, Japanese translation by M. Tanaka et al., Baifukan, Tokyo (1972) p. 229.

    Google Scholar 

  14. H. Ärmannsson, Anal. Chim. Acta, 110, 21 (1979).

    Article  Google Scholar 

  15. K.M. Bone and W.D. Hibbert, Anal. Chim. Acta, 1.07, 219 (1979).

    Google Scholar 

  16. A. Dornemann and H. Kleist, Z. Anal. Chem., 291, 349 (1978).

    Article  CAS  Google Scholar 

  17. L.G. Danielsson, B. Magnusson, and S. Westerlund, Anal. Chim. Acta, 98, 47 (1978).

    Article  CAS  Google Scholar 

  18. E.A. Startseva, N.M. Popova, I.G. Yudelevich, N.G. Vanifatova, and Yu.A. Zolotov, Z.Anal.Chem., 300, 28 (1980).

    Article  CAS  Google Scholar 

  19. E. Jackwerth and A. Kulok, Z. Anal. Chem., 257, 28 (1971).

    Article  CAS  Google Scholar 

  20. E. Jackwerth, E. Döring, J. Lohmar, and G. Schwark, Z. Anal.Chem., 260, 177 (1972).

    Article  CAS  Google Scholar 

  21. E. Jackwerth, R. Höhn, and K. Koos, Z. Anal.Chem., 264, 1 (1973).

    Article  CAS  Google Scholar 

  22. R. Höhn, E. Jackwerth, and K. Koos, Spectrochim. Acta, 29B, 225 (1974).

    Google Scholar 

  23. E. Jackwerth and J. Messerschmidt, Z. Anal. Chem., 274, 205 (1975).

    Article  CAS  Google Scholar 

  24. R. Höhn and E. Jackwerth, Z. Anal. Chem., 282, 21 (1976).

    Article  Google Scholar 

  25. R. Höhn and E. Jackwerth, Erzmetall, 29, 279 (1976).

    Google Scholar 

  26. E. Jackwerth and J. Messerschmidt, Anal. Chim. Acta, 87, 341 (1976).

    Article  CAS  Google Scholar 

  27. E. Jackwerth, J. Messerschmidt, and R. Höhn, Anal. Chim.Acta, 94, 225 (1977).

    Article  CAS  Google Scholar 

  28. A. Mizuike, H. Kawaguchi, and T. Kono, Mikrochim. Acta (Wien), 1970, 1095.

    Google Scholar 

  29. A. Mizuike and K. Fukuda, Mikrochim. Acta (Wien), 1972, 257.

    Google Scholar 

  30. A. Mizuike, K. Fukuda, and Y. Ochiai, Talanta, 19, 527 (1972).

    Article  CAS  Google Scholar 

  31. K. Fukuda, Y. Ochiai, and A. Mizuike, Japan Analyst, 23, 75 (1974).

    Article  CAS  Google Scholar 

  32. A. Mizuike and K. Fukuda, Mikrochim. Acta (Wien), 1975 I, 281.

    Google Scholar 

  33. E. Jackwerth, Pure & Appl. Chem., 51, 1149 (1979).

    Article  Google Scholar 

  34. M. Hiraide, Y. Yoshida, and A. Mizuike, Anal. Chim. Acta, 81, 185 (1976).

    Article  CAS  Google Scholar 

  35. M. Hiraide, T. Ito, M. Baba, H. Kawaguchi, and A. Mizuike, Anal.Chem., 52, 804 (1980).

    Article  CAS  Google Scholar 

  36. M. Hiraide and A. Mizuike, Japan Analyst, 26, 47, 655 (1977); 29, 84 (1980).

    Article  CAS  Google Scholar 

  37. E. Jackwerth, R. Höhn, and K. Musaick, Z. Anal. Chem., 299, 362 (1979).

    Article  CAS  Google Scholar 

  38. M.G. Vanderstappen and R.E. Van Grieken, Talanta 25, 653 (1978).

    Article  CAS  Google Scholar 

  39. E.A. Boyle and J.M. Edmond, Anal. Chim. Acta, 91, 189 (1977).

    Article  CAS  Google Scholar 

  40. V. Hudnik, S. Gomiííek, and B. Gorenc, Anal. Chim. Acta, 98, 39 (1978).

    Article  CAS  Google Scholar 

  41. A.J. Pik, A.J. Cameron, J.M. Eckert, E.R. Sholkovitz, and K.L. Williams, Anal. Chim. Acta, 110, 61 (1979).

    Article  CAS  Google Scholar 

  42. H. Berndt and J. Messerschmidt, Z. Anal. Chem., 299, 28 (1979).

    CAS  Google Scholar 

  43. Y. Thomassen, B.V. Larsen, F.J. Langmyhr, and W. Lund, Anal. Chim.Acta, 83, 103 (1976)

    Article  CAS  Google Scholar 

  44. G. Volland, P. Tschöpel, and G. Tölg, Anal. Chim. Acta, 90, 15 (1977).

    Article  CAS  Google Scholar 

  45. G.E. Batley and J.P. Matousek, Anal. Chem., 49, 2031 (1977).

    Article  CAS  Google Scholar 

  46. J.S. Fritz and E.M. Moyers, Talanta, 23, 590 (1976). 338

    Google Scholar 

  47. H.M. Kingston, I.L. Barnes, T.J. Brady, T.C. Rains, and M.A. Champ, Anal. Chem., 50, 2064 (1978).

    Article  CAS  Google Scholar 

  48. C. Lee, N.B. Kim, I.C. Lee, and K.S. Chung, Talanta, 24, 241 (1977).

    Article  CAS  Google Scholar 

  49. R.E. Sturgeon, S.S. Berman, A. Desaulniers, and D.S. Russell, Talanta, 27, 85 (1980).

    Article  CAS  Google Scholar 

  50. R.M. Barnes and J.S. Genna, Anal. Chem., 51, 1065 (1979).

    Article  CAS  Google Scholar 

  51. Z. Slovak and S. Slováková, Z. Anal. Chem., 292, 213 (1978).

    Article  CAS  Google Scholar 

  52. P. Burba and K.H. Lieser, Z. Anal. Chem., 286, 191 (1977).

    Article  CAS  Google Scholar 

  53. P. Burba and K.H. Lieser, Z. Anal. Chem., 297, 374 (1979).

    Article  CAS  Google Scholar 

  54. K.H. Lieser, H.M. Rober, and P. Burba, Z. Anal. Chem., 284, 361 (1977).

    Article  CAS  Google Scholar 

  55. M.M. Guedes da Mota, M.A. Jonker, and B. Griepink, Z. Anal. Chem., 296, 345 (1979).

    Article  CAS  Google Scholar 

  56. D.E. Leyden and G.H. Luttrell, Anal. Chem., 47, 1612 (1975).

    Article  CAS  Google Scholar 

  57. D.E. Leyden, G.H. Luttrell, W.K. Nonidez, and D.B. Werho, Anal. Chem., 48, 67 (1976).

    Article  CAS  Google Scholar 

  58. D.E. Leyden, G.H. Luttrell, A.E. Sloan, and N.J. DeAngelis, Anal. Chim. Acta, 84, 97 (1976).

    Article  CAS  Google Scholar 

  59. E. Jackwerth, J. Lohmar, and G. Wittier, Z. Anal. Chem., 266, 1 (1973).

    Article  CAS  Google Scholar 

  60. E. Jackwerth, Z. Anal. Chem., 271, 120 (1974).

    Article  CAS  Google Scholar 

  61. E. Jackwerth and H. Berndt, Anal. Chim. Acta, 74, 299 (1975).

    Article  CAS  Google Scholar 

  62. H. Berndt, E. Jackwerth, and M. Kimura, Anal. Chim. Acta, 93, 45 (1977).

    Article  CAS  Google Scholar 

  63. M. Kimura, Talanta, 24, 194 (1977).

    Article  CAS  Google Scholar 

  64. B.M. Vanderborght and R.E. Van Grieken, Anal. Chem., 49, 311 (1977).

    Article  CAS  Google Scholar 

  65. H. Berndt and E. Jackwerth, Z. Anal. Chem., 290, 369 (1978).

    Article  CAS  Google Scholar 

  66. K.H. Lieser, S. Quandt, and B. Gleitsmann, Z. Anal. Chem., 298, 378 (1979).

    Article  CAS  Google Scholar 

  67. A. Disam, P. Tschopel, and G. Tölg, Z. Anal. Chem., 295, 97 (1979).

    Article  CAS  Google Scholar 

  68. G.E. Batley and D. Gardner, Water Res., 11, 745 (1977).

    Article  CAS  Google Scholar 

  69. J.F. Slowey and D.W. Hood, Geochim. Cosmochim. Acta, 35, 121 (1971).

    Article  CAS  Google Scholar 

  70. M.I. Abdullah, O.A. El-Rayis, and J.P. Riley, Anal. Chim. Acta, 84, 363 (1976).

    Article  CAS  Google Scholar 

  71. A. Mizuike, M. Hiraide, and J. Mizutani, unpublished work. 339

    Google Scholar 

  72. P. Benes and E. Steinnes, Water Res., 8, 947 (1974).

    Article  CAS  Google Scholar 

  73. P. Benel, E.T. Gjessing, and E. Steinnes, Water Res., 10, 711 (1976).

    Article  Google Scholar 

  74. M.E. Bender, W.R. Matson, and R.A. Jordan, Environ.Sci.Technol., 4, 520 (1970).

    Article  CAS  Google Scholar 

  75. J.L. Means, D.A. Crerar, and J.L. Amster, Limnol. Oceanogr., 22, 957 (1977).

    Article  CAS  Google Scholar 

  76. T.M. Florence and G.E. Batley, Talanta, 23, 179 (1976).

    Article  CAS  Google Scholar 

  77. G.E. Batley and T.M. Florence, Anal. Lett., 9, 379 (1976).

    Article  CAS  Google Scholar 

  78. T.M. Florence, Water Res., 11, 681 (1977).

    Article  CAS  Google Scholar 

  79. Y. Sugimura, Y. Suzuki, and Y. Miyake, Deep-Sea Res., 25, 309 (1978).

    Article  CAS  Google Scholar 

  80. Y. Sugimura, Y. Suzuki, and Y. Miyake, J. Oceanogr. Soc. Jpn., 34, 93 (1978).

    Article  CAS  Google Scholar 

  81. J.F. Pankow and G.E. Janauer, Anal.Chim.Acta, 69, 97 (1974).

    Article  CAS  Google Scholar 

  82. R.E. Cranston and J.W. Murray, Anal.Chim.Acta, 99, 275 (1978).

    Article  CAS  Google Scholar 

  83. Y. Sugimura and Y. Suzuki, J. Oceanogr. Soc. Jpn., 33, 23 (1977).

    Article  CAS  Google Scholar 

  84. J.F. Slowey, L.M. Jeffrey, and D.W. Hood, Nature, 214, 377 (1967).

    Article  CAS  Google Scholar 

  85. K. Hiiro, T. Owa, M. Takaoka, T. Tanaka, and A. Kawahara, Japan Analyst, 25, 122 (1976).

    Article  CAS  Google Scholar 

  86. S. Osaki, T. Osaki, S. Shibata, and Y. Takashima, Japan Analyst, 25, 358 (1976).

    Article  CAS  Google Scholar 

  87. H. Bergmann and K. Hardt, Z. Anal. Chem., 297, 381 (1979).

    Article  CAS  Google Scholar 

  88. G.J. de Jong and U.A.Th. Brinkman, Anal. Chim. Acta, 98, 243 (1978).

    Article  Google Scholar 

  89. T. Kamada, T. Shiraishi, and Y. Yamamoto, Talanta, 25, 15 (1978).

    Article  CAS  Google Scholar 

  90. Y. Shimoishi and K. Töei, Anal. Chim. Acta, 100, 65 (1978).

    Article  CAS  Google Scholar 

  91. T. Kamada, Talanta, 23, 835 (1976).

    Article  CAS  Google Scholar 

  92. L. Chuecas and J.P. Riley, Anal. Chim. Acta, 35, 240 (1966).

    Article  CAS  Google Scholar 

  93. R. Fukai, Nature, 213, 901 (1967).

    Article  CAS  Google Scholar 

  94. R. Fukai and D. Yas, J. Oceanogr. Soc. Jpn., 23, 298 (1967).

    Google Scholar 

  95. H. Yamazaki, Anal. Chim. Acta, 113, 131 (1980).

    Article  CAS  Google Scholar 

  96. O. Yoshii, K. Hiraki, Y. Nishikawa, and T. Shigematsu, Japan Analyst, 26, 91 (1977).

    Article  CAS  Google Scholar 

  97. M.O. Andreae, Anal. Chem., 49, 820 (1977).

    Article  CAS  Google Scholar 

  98. J. Aggett and A.C. Aspell, Analyst, 101, 341 (1976).

    Article  CAS  Google Scholar 

  99. R.S. Braman, D.L. Johnson, C.C. Foreback, J.M. Ammons, and J.L. Bricker, Anal. Chem., 49, 621 (1977).

    Article  CAS  Google Scholar 

  100. A.U. Shaikh and D.E. Tallman, Anal. Chim. Acta, 98, 251 (1978).

    Article  CAS  Google Scholar 

  101. G.A. Cutter, Anal. Chim. Acta, 98, 59 (1978).

    Article  CAS  Google Scholar 

  102. I. Taguchi, Bunseki, 1979, 370.

    Google Scholar 

  103. E. Kitazume, T. Sakamoto, H. Kawaguchi, and A. Mizuike, Japan Analyst, 27, 566 (1978).

    Article  CAS  Google Scholar 

  104. A. Mizuike, M. Hiraide, and S. Kawakubo, Mikrochim. Acta (Wien). 1979 II, 487.

    Google Scholar 

  105. S. Kawakubo, Y. Yamaguchi, and A. Mizuike, Japan Analyst, to be published.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Engineering, Nagoya University, Chikusa-ku, Nagoya 464, Japan

    Atsushi Mizuike & Masataka Hiraide

Authors
  1. Atsushi Mizuike
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Masataka Hiraide
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

H. Malissa M. Grasserbauer R. Belcher

Rights and permissions

Reprints and permissions

Copyright information

© 1981 Springer-Verlag/Wien

About this paper

Cite this paper

Mizuike, A., Hiraide, M. (1981). Enrichment Techniques for Inorganic Micro- and Trace Analysis. In: Malissa, H., Grasserbauer, M., Belcher, R. (eds) Nature, Aim and Methods of Microchemistry. Springer, Vienna. https://doi.org/10.1007/978-3-7091-8630-5_19

Download citation

  • DOI: https://doi.org/10.1007/978-3-7091-8630-5_19

  • Publisher Name: Springer, Vienna

  • Print ISBN: 978-3-211-81653-0

  • Online ISBN: 978-3-7091-8630-5

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation