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Zusammenfassung

Die meisten Reaktionen am sp 3 -hybridisierten Kohlenstoff sind dadurch gekennzeichnet daß ein Substituent X durch einen Substituenten Y ersetzt wird, wobei der neue Substituent beide für die C—Y-Bindung nötigen Elektronen liefert. Der ersetzte Substituent verläßt natürlich das Molekül mit beiden Elektronen der ursprünglichen σ-Bindung:

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Ergänzende Literatur

  • Ingold, C. K.: Structure and Mechanism in Organic Chemistry. Ithaca-New York: Cornell University Press. 1953.

    Google Scholar 

  • Streitwieser, A., jr.: Solvolytic Displacement Reactions at Saturated Carbon Atoms. Chem. Revs. 56, 571 ( 1956 ); New York: McGraw-Hill. 1962.

    Google Scholar 

  • Bunton, C. A.: Nucleophilic Substitution at a Saturated Carbon Atom. New York: Elsevier Publishing Co. 1963.

    Google Scholar 

  • Thornton, E. R.: Solvolysis Mechanisms. New York: The Ronald Press Co. 1964.

    Google Scholar 

  • Bethell, D., Gold V.: Carbonium Ions. An Introduction. London-New York: Academic Press. 1967.

    Google Scholar 

  • Olah, G. A., v. R. Schleyer, P.: Carbonium Ions I. Interscience Publishers. 1968.

    Google Scholar 

  • Szwarc, M.: Ions and Ion Pairs. Accounts Chem. Res. 2, 87 (1969).

    Article  CAS  Google Scholar 

  • Hückel, W.: Kryptoionen-Reaktionen. Liebigs Ann. 711, 1 (1968).

    Article  Google Scholar 

  • Olah, G. A., Pittman, C. U.: Adv. Phys. Org. Chem. 4, 305 (1966).

    Article  CAS  Google Scholar 

  • Winstein, S.: Non-Classical Ions and Homoaromaticity. Quart. Rev. 23, 141 (1969).

    Article  CAS  Google Scholar 

  • Bartlett, P. D.: Non-Classical Ions. New York: Benjamin. 1966.

    Google Scholar 

  • Amis, E. S.: Solvent Effects on Reaction Rates and Mechanisms. New York: Academic Press. 1966.

    Google Scholar 

  • Capon, B.: Neighbouring Group Participation. Quart. Rev. 18, 45 (1964).

    Article  CAS  Google Scholar 

  • Ingold, C. K.: Structure and Mechanism in Organic Chemistry. Ithaca-New York: Cornell University Press. 1953.

    Google Scholar 

  • Ingold, C. K. Proc. Chem. Soc. (London) 1962, 265.

    Google Scholar 

  • Banthorpe, D. V.: Elimination Reactions. Amsterdam: Elsevier. 1963.

    Google Scholar 

  • Bethell, D., Gold, V.: Carbonium Ions. An Introduction. London - New York: Academic Press. 1967.

    Google Scholar 

  • Hoffmann, R. W.: Dehydrobenzene and Cycloalkynes. Weinheim: Verlag Chemie. 1967.

    Google Scholar 

  • Sicher, J.: Der syn- und anti-koplanare Ablauf bimolekularer olefin-bildender Eliminierungen. Angew. Chem. 84, 177 (1972).

    Article  Google Scholar 

  • De la Mare, P. B. D., Bolton, R.: Electrophilic Additions to Unsaturated Systems. Amsterdam: Elsevier. 1966.

    Google Scholar 

  • Fahey, R. C.: Stereochemistry of Electrophilic Addition to Olefins and Acetylenes. Topics in Stereochemistry 3, 237 (1968).

    Article  CAS  Google Scholar 

  • Traylor, T. G.: Additions to Strained Olefins. Accounts Chem. Res. 2, 152 (1969).

    Article  CAS  Google Scholar 

  • Banthorpe, D. V.: π-Complexes as Reaction Intermediates. Chem. Revs. 70, 295 (1970).

    Article  CAS  Google Scholar 

  • Jencks, W. P.: Mechanism and Catalysis of Simple Carbonyl Group Reactions. Progr. Phys. Org. Chem. 2, 63 (1964).

    Article  CAS  Google Scholar 

  • Cordes, E. H.: Mechanism and Catalysis for the Hydrolysis of Acetals, Ketals, and Ortho Esters. Progr. Phys. Org. Chem. 4, 1 (1967).

    Article  CAS  Google Scholar 

  • Bender, M. L.: Mechanism of Catalysis of Nucleophilic Reactions of Carboxylic Acid Derivatives. Chem. Revs. 60, 53 (1960).

    Article  CAS  Google Scholar 

  • Lowe, P. A.: Reactive Intermediates in Organic Synthesis. I. Ylides. Chemistry and Industry 1970, 1070.

    Google Scholar 

Elektrophile aromatische Substitution

  • Ingold, C. K.: Structure and Mechanism in Organic Chemistry. Ithaca-New York: Cornell University Press. 1953.

    Google Scholar 

  • Norman, R. O. C., Taylor, R.: Electrophilic Substitution in Benzenoid Compounds. Amsterdam: Elsevier. 1965.

    Google Scholar 

  • Ridd, J. H.: Aromaticity. London: The Chemical Society. 1967.

    Google Scholar 

  • Stock, L. M.: Aromatic Substitution Reactions. Englewood Cliffs, N.J.: Prentice Hall. 1968.

    Google Scholar 

  • Banthorpe, D. V.: 71-Complexes As Reaction Intermediates. Chem. Revs. 70, 295 (1970).

    Article  CAS  Google Scholar 

  • Cerfontain, H.: Mechanistic Aspects in Aromatic Sulfonation and Desulfonation. New York: J. Wiley and Sons. 1968.

    Google Scholar 

  • Katritzky, A. R., Johnson, C. D.: Angew. Chem. 6, 608 (1967).

    Article  CAS  Google Scholar 

Nukleophile aromatische Substitution

  • Bunnett, J. F., Zahler, R. E.: Aromatic Nucleophilic Substitution Reactions. Chem. Revs. 49, 273 (1951).

    Article  CAS  Google Scholar 

  • Bunnett, J. F.: Mechanism and Reactivity in Aromatic Nucleophilic Substitution Reactions. Quart. Rev. 12, 1 (1958).

    Article  CAS  Google Scholar 

  • Buncel, E.,Norris, A. R., Russell, K. E.: Quart. Rev. 22, 123 (1968).

    Article  Google Scholar 

  • De Mayo, P.: Molecular Rearrangements, Band I, II. New York: Interscience Publishers. 1963, 1964.

    Google Scholar 

  • Olah, G. A., v. R. Schleyer, P.: Carbonium Ions, Band II. New York: Interscience Publishers. 1970.

    Google Scholar 

  • Collins, C. J.: Pinacolic Rearrangement. Quart. Rev. 14, 357 (1960).

    Article  CAS  Google Scholar 

  • Schöllkopf, U.: Neuere Ergebnisse der Carbanionchemie. Angew. Chem. 82, 795 (1970).

    Article  Google Scholar 

  • Cram, D. J.: Fundamentals of Carbanion Chemistry. New York: Academic Press. 1965.

    Google Scholar 

  • Johnson, A. W.: Ylid Chemistry. New York: Academic Press. 1966.

    Google Scholar 

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© 1972 Springer-Verlag/Wien

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Ernest, I. (1972). Polare Reaktionen. In: Bindung, Struktur und Reaktionsmechanismen in der organischen Chemie. Springer, Vienna. https://doi.org/10.1007/978-3-7091-8437-0_3

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  • DOI: https://doi.org/10.1007/978-3-7091-8437-0_3

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