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Coordination Chemistry of Certain Transition Metal Ions in Donor Solvents

  • Viktor Gutmann

Abstract

Consecutive replacement of solvent molecules by competitive ligands in the coordination sphere of class (a) transition metal cations has been followed by spectrophotometry, potentiometric and conductometric techniques. Perchlorates or tetrafluoroborates have been often used, allowing the metal ions to achieve hexacoordination by solvent molecules in the non-aqueous solutions; competitive (anionic) ligands were added to the solutions in the form of tetra-alkylammonium salts.

Keywords

Donor Number Transition Metal Cation Tributyl Phosphate Complete Ionization Trimethyl Phosphate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Notes

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Copyright information

© Springer-Verlag/Wien 1968

Authors and Affiliations

  • Viktor Gutmann
    • 1
  1. 1.Technische Hochschule WienAustria

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