Abstract
Consecutive replacement of solvent molecules by competitive ligands in the coordination sphere of class (a) transition metal cations has been followed by spectrophotometry, potentiometric and conductometric techniques. Perchlorates or tetrafluoroborates have been often used, allowing the metal ions to achieve hexacoordination by solvent molecules in the non-aqueous solutions; competitive (anionic) ligands were added to the solutions in the form of tetra-alkylammonium salts.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
Notes
Gutmann, V., and O. Bohunovsky: Mh. Chem. In Press (1968). F. A. Cotton, and R. Francis: J. Am. Chem. Soc. 82, 2986 (1960).
Gutmann, V., and H. Bardy: Mh. Chem. In Press (1968).
Gaizer, P., and M. T. Beck: J. Inorg. Nucl. Chem. 29, 21 (1967).
Gutmann, V., and K. Fenkart: Mh. Chem. 98, 1 (1967).
Gutmann, V., and K. Fenkart: Mh. Chem. 98, 286 (1967).
Fine, D. A.: J. Amer. Chem. Soc. 84, 1139 (1962).
Sramko, T.: Chem. Zvesti 17, 725 (1963); C. A. 60, 8697B (1964).
Baaz, M., V. Gutmann, G. Hampel and J. R. Masaguer: Mh. Chem. 93, 1416 (1962).
Buffagny, S., and T. M. J. Dunn: J. Chem. Soc. 1961, 5105.
Drago, R. S., andk. F. Purcell: Chapter 5 In “Non-Aqueous Solvent Systems,” Ed. T. C. Waddington, Academic Press, London, New York 1965.
Gutmann, V., and L. Hubner: Mh. Chem. 92, 1261 (1961).
Gutmann, V., and E. Wychera: Inorg. Nucl. Chem. Letters 2, 257 (1966).
Gutmann, V., and E. Wychera: Rev. Chim. Min. 3, 941 (1966).
Katzin, L. I.: Nature 182, 1013 (1958).
Hubacek, H., B, Stancic, and V. Gutmann: Mh. Chem. 94, 1118 (1963).
Gutmann, V., G. Hampel, and W. Lux: Mh. Chem. 96, 593 (1965).
Gutmann, V., A. Scherhaufer, and H. Czuba: Mh. Chem. 98, 619 (1967).
De Maine, P. A. D., and E. Koubek: J. Inorg. Nucl. Chem. 11, 329 (1959).
Gutmann, V., and M. Baaz: Mh. Chem. 90, 729 (1959).
Gutmann, V., M. Baaz, and L. Hubner: Mh. Chem. 91, 537 (1960).
Gutmann, V., and W. K. Lux: Mh. Chem. 98, 276 (1967).
Meek, D. W., and R. S. Drago: J. Amer. Chem. Soc. 83, 4322 (1961).
Gutmann, V., and G. Hampel: Mh. Chem. 94, 830 (1963).
Baaz, M., V. Gutmann, and J. R. Masaguer: Mh. Chem. 92, 590 (1961).
Gutmann, V., and H. Laussegger: Mh. Chem. 98, 439 (1967).
Gutmann, V., and W. K. Lux: J. Inorg. Nucl. Chem. 29, 2391 (1967).
Gutmann, V., and O. Leitmann: Mh. Chem. 97, 926 (1966).
Gutmann, V.: Coord. Chem. Revs. 2, 239 (1967).
Gutmann, V., O. Leitmann, H. Czuba, and A. Scherhaufer: Mh. Chem. 98, 188 (1967).
Cziszar, B., V. Gutmann, and E. Wychera: Mh. Chem. 98, 12 (1967).
Gutmann, V., and H. Bardy: Z. Anorg. Allg. Chem. In Press (1968).
Gutmann, V., and O. Bohunovsky: Mh. Chem. In Press (1968).
Gutmann, V., and K. H. Wegleitner: Mh. Chem. 99, 368 (1968).
Gutmann, V., and U. Mayer: To Be Published In Mh. Chem.
Bernal, I., and P. H. Rieger: Inorg. Chem. 2, 256 (1963).
Kivelson, D., and S. K. Lee: J. Chem. Phys. 41, 1896 (1964).
Carlin, R. L., and F. A. Walker: J. Amer. Chem. Soc. 87, 2128 (1965).
Jones, M. M., B. J. Yow, and N. R. My: Inorg. Chem. 1, 166 (1962).
Author information
Authors and Affiliations
Rights and permissions
Copyright information
© 1968 Springer-Verlag/Wien
About this chapter
Cite this chapter
Gutmann, V. (1968). Coordination Chemistry of Certain Transition Metal Ions in Donor Solvents. In: Coordination Chemistry in Non-Aqueous Solutions. Springer, Vienna. https://doi.org/10.1007/978-3-7091-8194-2_8
Download citation
DOI: https://doi.org/10.1007/978-3-7091-8194-2_8
Publisher Name: Springer, Vienna
Print ISBN: 978-3-7091-8196-6
Online ISBN: 978-3-7091-8194-2
eBook Packages: Springer Book Archive