Abstract
The analysis of the mid infrared spectrum (1200–4000 cm-1) of fulminic acid yielded the identification of more than 110 new vibrational levels. Each assigned vibrational level shows interactions enhanced by the quasilinearity of the molecule HCNO. Most of the resonances can be classified into a network of resonance systems. This network can be built up with the help of the basic resonance systems 00002/00010, 00004/00100 and 00015/01000 that include Coriohs-type and Fermi-type resonances. In this paper the 00200/00104/00007/[00033] and 00114/00210/00202/01003/ [00017] resonance systems are discussed in detail.
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© 1997 Springer-Verlag Wien
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Albert, S., Winnewisser, M., Winnewisser, B.P. (1997). The Colorful World of Quasilinearity as Revealed by High Resolution Molecular Spectroscopy. In: Mink, J., Keresztury, G., Kellner, R. (eds) Progress in Fourier Transform Spectroscopy. Mikrochimica Acta Supplement, vol 14. Springer, Vienna. https://doi.org/10.1007/978-3-7091-6840-0_10
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DOI: https://doi.org/10.1007/978-3-7091-6840-0_10
Publisher Name: Springer, Vienna
Print ISBN: 978-3-211-82931-8
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