Investigation of Grain Boundary Segregation in Iron-Base Alloys by Auger Electron Spectroscopy

  • H. J. Grabke
  • H. Erhart
  • R. Möller
Part of the Mikrochimica Acta book series (MIKROCHIMICA, volume 10)


Most materials, metals and ceramics, are polycrystalline and contain more or less grain boundaries. The grain boundaries are of great importance for material properties. Dissolved atoms tend to segregate at grain boundaries and they can induce strong changes in the mechanical and corrosion behaviour. Some phenomena caused by grain boundary segregation of impurities in steels may be enumerated: temper embrittlement, creep embrittlement, intergranular corrosion, stress corrosion cracking and so on.


Auger Electron Auger Electron Spectroscopy Intergranular Fracture Boundary Concentration Surface Segregation 
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  1. 1.
    L.E. Davis, N.C. Mac Donald, P.W. Palmberg, E. Riach, and R.E. Weber, Handbook of Auger Electron Spectroscopy, 2nd ed. Edina, Minnesota: Physical Electronics Industries. 1976.Google Scholar
  2. 2.
    D. F. Stein, A. Joshi, and R.P. Laforce, Trans. ASM 62, 776 (1969).Google Scholar
  3. 3.
    R. Viswanathan and A. Joshi, Metallurg. Trans. A 6A, 2289 (1975).Google Scholar
  4. 4.
    G. Tauber and H. J. Grabke, Ber. Bunsenges. physikal. Chemie 82, 298 (1978).Google Scholar
  5. 5.
    H. Erhart and H.J. Grabke, Metals Sci. 15, 401 (1981).Google Scholar
  6. 6.
    M.P. Seah, Surface Sci. 40, 595 (1973).CrossRefGoogle Scholar
  7. 7.
    L. Marchut and Ch. J. McMahon Jr., Electron and Positron Spectroscopies in Materials Science and Engineering. Academic Press. 1979. p. 183.Google Scholar
  8. 8.
    H. Viefhaus, H. Erhart, and R. Möller, unpublished data.Google Scholar
  9. 9.
    H. Viefhaus, R. Möller, H. Erhart, and H.J. Grabke, Scripta Met. 17, 165 (1983).CrossRefGoogle Scholar
  10. 10.
    C.L. Briant, Acta Met. in press.Google Scholar
  11. 11.
    H. Erhart, H.J. Grabke, and R. Möller, Arch. Eisenhüttenwes. 52, 451 (1981).Google Scholar
  12. 12.
    J. Küpper, H. Erhart, and H.J. Grabke, Corrosion Sci. 21, 227 (1981).CrossRefGoogle Scholar
  13. 13.
    C.L. Briant, Scripta Met. 15, 1013(1981).CrossRefGoogle Scholar
  14. 14.
    L. Stratmann and H.J. Grabke, unpublished results.Google Scholar
  15. 15.
    H.R. Tipler and B.E. Hopkins, Metals Sci. 10, 47 (1976).CrossRefGoogle Scholar
  16. 16.
    D.S. Wilkinson, K. Akibo, N. Thyagarajan, and D.P. Pope, Metallurg. Trans. 11A, 1829 (1980).Google Scholar
  17. 17.
    D.J. Gooch, Metals Sci. 15, 45 (1981).CrossRefGoogle Scholar
  18. 18.
    Jin Yu and H.J. Grabke, Metals Sci. in press.Google Scholar
  19. 19.
    W.G. Hartweck and H.J. Grabke, Scripta Met. 15, 653 (1981).CrossRefGoogle Scholar
  20. 20.
    U. Franzoni, H. Goretzki, and S. Sturlese, Scripta Met. 15, 743 (1981).CrossRefGoogle Scholar
  21. 21.
    H.J. Grabke, H. Viefhaus, and B. Egert, Stahl u. Eisen 99, 1497 (1979).Google Scholar
  22. 22.
    A.R. Waugh and M J. Southon, Surface Sci. 68, 79 (1977).CrossRefGoogle Scholar
  23. 23.
    T. Sakurai, Y. Kuk, A.K. Birchenall, H.W. Pickering, and H.J. Grabke, Scripta Met. 15, 535 (1981).CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Wien 1983

Authors and Affiliations

  • H. J. Grabke
    • 1
  • H. Erhart
    • 1
  • R. Möller
    • 1
  1. 1.Max-Planck-Institut für Eisenforschung GmbH.DüsseldorfFederal Republic of Germany

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