Dialkylaminofluorophosphines and Their Coordination Chemistry with Transition Metals
First reference to a dialkylaminofluorophosphine, (C2H5)2NPF2, was made 25 years ago, but it was not until recently when this class of compounds of the composition (R2N)nPF3-n (n = 1,2) attracted further interest. The compound (CH3)2NPF2 has been prepared by the dimethylaminolysis of PF3, and some of its reactions have been studied (1–3).
KeywordsCoordination Chemistry Coordination Compound Metal Carbonyl Ligand Field Strength Transition Metal Carbonyl
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