Abstract
Infrared spectra of metal complexes have already been intensively studied and the effects of a metal ion on the vibration frequencies in the ligand have been investigated (1). However, not so many investigations have been reported for the metal-ligand stretching and deformation vibrations. Recently we have measured the low frequency infrared spectra of ammine, halogeno, nitro, cyano, aquo and isothiocyanato complex ions. The assignments of the bands observed have been made on the basis of a normal coordinate analysis and the force constants associated with the metal-ligand bonds have been obtained. The results may be useful for the understanding of the nature of the metalligand bonds and give further information on the already recognized tendencies of electrons (2). The present paper is a summary of the results of our study.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
COTTON, F. A., “The Infrared Spectra of Transition Metal Complexes” in LEWIS, J., and WILKINS, R. G., “Modern Coordination Chemistry”, Inter — science, 1960;
NAKAMOTO, K., “Infrared Spectra of Inorganic and Coordination Compounds”, Wiley, 1963.
ORGEL, L. E., “An Introduction to Transition-metal Chernistry”, Mathuen, 1960.
MIZUSHIMA, S., NAKAGAWA, I., and QUAGLIANO, J. V., J.Chem. Phys., 23, 1367 (1955);
BERTIN, E. P., NAKAGAWA, I., et al, J.Am. Chem. Soc., 80, 525 (1958).
BLYHOLDER, G., and VERGEZ, S., J. Phys. Chem., 67, 2149 (1963).
SHIMANOUCHI, T., Pure & Applied Chem., 7, 131 (1963).
WILSON Jr., E. B., J. Chem. Phys., 7, 1047 (1939);
WILSON Jr., E. B., J. Chem. Phys., 9, 76 (1941).
FUJITA, J., NAKAMOTO, K., and KOBAYASHI, M., J. Am. Chem. Soc., 78, 3295 (1956).
ITO, K., et al, J. Am. Chem. Soc., 83, 4526 (1961).
DRIEL, M., and VERWEEL, H. J., Z. Krist., A 95, 308 (1936).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1964 Springer-Verlag Wien
About this paper
Cite this paper
Nakagawa, I., Shimanouchi, T., Hiraishi, J. (1964). Infrared Spectra and Metal-Ligand Force Constants in Coordination Compounds. In: Gutmann, V. (eds) Proceedings of the 8th International Conference on Coordination Chemistry. Springer, Vienna. https://doi.org/10.1007/978-3-7091-3650-8_7
Download citation
DOI: https://doi.org/10.1007/978-3-7091-3650-8_7
Publisher Name: Springer, Vienna
Print ISBN: 978-3-7091-3652-2
Online ISBN: 978-3-7091-3650-8
eBook Packages: Springer Book Archive