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Some New Complexes of Rhenium

  • F. Nyman
  • E. S. Stern
Conference paper

Abstract

Octahedral complexes of rhenium(V), rhenium(Iii), and rhenium(Ii) derived from ditertiary phosphines have been prepared by reaction of the phosphine with potassium perrhenate or rhenium heptoxide in the presence of a halogen acid and an organic solvent. These include complexes of the types [(R2PCH2CH2PR2) 2ReO2]+X-, [(R2PCH2CH2PR2)2ReX2]+X- and [(R2PCH2CH2PR2ReX2] where R = C6H5 or CH3 and X = Cl, Br, or I.

Keywords

Station Laboratory Physical Technique Experimental Station Unpublished Result Coordination Chemistry 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Copyright information

© Springer-Verlag Wien 1964

Authors and Affiliations

  • F. Nyman
    • 1
  • E. S. Stern
    • 1
  1. 1.Petrochemical and Polymer Laboratory, The HeathI. C. I. Ltd.RuncornEngland, UK

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