Some New Adducts of Iodosilane

  • B. J. Aylett
  • R. A. Sinclair
Conference paper


Monohalosilanes are known to combine very readily with tertiary amines to yield 1:1 adducts (1). in the case of iodosilane, a 1:2 adduct with trimethylamine has also been reported, made under forcing conditions (2).


Petroleum Ether Tertiary Amine Dimethyl Ether Force Condition Excess Base 
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  1. 1.
    EMELÉUS and MILLER, J. Chem. Soc. (London)1939, 819.Google Scholar
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    AYLETT, EMELÉUS and MADDOCK, J.Inorg.Nucl.Chem.,1, 187 (1955).CrossRefGoogle Scholar
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    STERNBACH and MacDIARMID, J.Am.Chem.Soc.,83, 3384 (1961).CrossRefGoogle Scholar
  4. 4.
    MacDIARMID, J.Inorg.Nucl.Chem.,25, 1534 (1963).CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Wien 1964

Authors and Affiliations

  • B. J. Aylett
    • 1
  • R. A. Sinclair
    • 1
  1. 1.Chemistry DepartmentWestfield CollegeHampstead, London, N. W. 3UK

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