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Compounds Containing Rhodium-Mercury, Osmium-Mercury or Iridium-Mercury Bonds

  • K. Vrieze
Conference paper

Abstract

In the preceding paper presented by R.S.NYHOLM various methods which can be used to prepare covalent metal-to-metal bonded compounds were summarised. The work described in this investigation employs two new essentially different reactions (see I and II below) to produce complexes containing transition metal-to-mercury bonds; these are the first complexes containing a metal-metal bond between a post-transition metal and a group VIII metal in the second and third rows.

Keywords

Ligand Field Rhodium Complex Strong Covalent Bond Group Viii Metal Longe Wavelength Transition 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    NYHOLM, R. S., and VRIEZE, K., Proc. Chem. Soc.,1963, 138.Google Scholar
  2. 2.
    NYHOLM, R. S., and VRIEZE, K., Chem.and Ind.,1964, 318.Google Scholar
  3. 3.
    VASKA, L., and DILUZIO, J. W., J.Amer. Chenm. Soc.,83, 2784 (1961).CrossRefGoogle Scholar
  4. 3a.
    VASKA, L., and DILUZIO, J. W., J.Amer. Chenm. Soc.,84, 679 (1962).CrossRefGoogle Scholar
  5. 4.
    VALLARINO, L., J. Chem. Soc. (London),1957, 2287.Google Scholar
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    NYHOLM, R. S., and VRIEZE, K., Unpublished work.Google Scholar
  7. 6.
    LEWIS, J., NYHOLM, R. S., and REDDY, G. K. N., Chem.and Ind.,1960, 1386.Google Scholar

Copyright information

© Springer-Verlag Wien 1964

Authors and Affiliations

  • K. Vrieze
    • 1
  1. 1.University College LondonUK

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