Decomposition of Substituted π-Allyl Palladium Halide Complexes

  • E. J. Smutny


The interaction between diolefins and palladium salts in hydroxylic and non-hydroxylic solvents leads to π-allylic complexes in yields of 80% or greater. These complexes have the empirical formula [(diolefin)(alcohol)PdCl] and their structure has been established (1) as the π-allyl type {I}.


Sodium Acetate Palladium Chloride Shell Development Fold Coordination Palladium Salt 
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  1. 1.
    ROBINSON, S. D., and SHAW, B.L., J.Chem.Soc. (London),1963, 4806.Google Scholar

Copyright information

© Springer-Verlag Wien 1964

Authors and Affiliations

  • E. J. Smutny
    • 1
  1. 1.Koninklijke/Shell LaboratoriumAmsterdam-NThe Netherlands

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