Raman Effect and Competitive Formation of Tetrahedral Mixed Halide Complexes by Ga3+ in Solution
Raman spectroscopic evidence has shown (1) that in presence of excess halogen acid HX (where X is C1, Br or I)- Ga3+ forms [GaX4]- as the sole detectable complex. The present paper describes some preliminary studies of solutions containing two halogen acids, in which mixed halide complexes are present in labile equilibrium.
KeywordsRAMAN Spectroscopy Raman Line Mixed Species RAMAN Effect Chloride System
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