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Novel Stereochemical Effects in Certain Coordination Compounds

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Proceedings of the 8th International Conference on Coordination Chemistry

Abstract

This paper is concerned with the stereochemical properties of certain generically related mononuclear complexes in which the coordination number of the central atom or cation is 7, 8, 9, or 10. New results are reported for amine-polycarboxylate chelates of Zr (IV), high spin Fe3+, and the M3+rare earth ions; the chelating agents are ethylendiaminetetraacetic acid (EDTA; H4Y), 1, 2-diaminocyclohexane -N, N′ -tetraacetic acid (DCTA, H4Z), and nitrilotriacetic acid (NTA; H3X). X-ray diffraction analyses of three-dimensional data from single crystals provide quantitative descriptions of the chelates for theoretical discussion and correlation with other experimental observations.

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References

  1. HOARD, J. L., SMITH, G.S., and LIND, M. D., in “Advances in the Chemistry of the Coordination Compounds”, the Macmillan Company, New York, 1961, pp. 296 – 302.

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Author information

Authors and Affiliations

  1. Cornell University, Ithaca, N. Y., USA

    J. L. Hoard

Authors
  1. J. L. Hoard
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Editor information

Editors and Affiliations

  1. Technical University of Vienna, Austria

    V. Gutmann

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© 1964 Springer-Verlag Wien

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Hoard, J.L. (1964). Novel Stereochemical Effects in Certain Coordination Compounds. In: Gutmann, V. (eds) Proceedings of the 8th International Conference on Coordination Chemistry. Springer, Vienna. https://doi.org/10.1007/978-3-7091-3650-8_47

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  • DOI: https://doi.org/10.1007/978-3-7091-3650-8_47

  • Publisher Name: Springer, Vienna

  • Print ISBN: 978-3-7091-3652-2

  • Online ISBN: 978-3-7091-3650-8

  • eBook Packages: Springer Book Archive

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