Abstract
Five coordinate compounds of cobalt are now comparatively common, though only on nitrosyl (dimethyldithiocarbonato) cobalt(I) has a detailed X ray examination been performed (1). This has been shown to have a square pyramidal structure with the N-O bond inclined at 139°to the pyramidal axis, forming an unsymmetrical π bond with the cobalt atom.
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References
ALDERMAN, P. R. H., OWSTON, P. G., and ROWE, J. M., J.Chem. Soc. (London), 1962, 668.
GRAY, H. B., BERNAL, I., and BILLIG, E., J.Am.Chem.Soc., 84, 3404 (1962).
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© 1964 Springer-Verlag Wien
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Earnshaw, A., Hewlett, P.C., Larkworthy, L.F. (1964). Five Coordinate Compounds of Cobalt. In: Gutmann, V. (eds) Proceedings of the 8th International Conference on Coordination Chemistry. Springer, Vienna. https://doi.org/10.1007/978-3-7091-3650-8_43
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DOI: https://doi.org/10.1007/978-3-7091-3650-8_43
Publisher Name: Springer, Vienna
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