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Five Coordinate Compounds of Cobalt

  • A. Earnshaw
  • P. C. Hewlett
  • L. F. Larkworthy
Conference paper

Abstract

Five coordinate compounds of cobalt are now comparatively common, though only on nitrosyl (dimethyldithiocarbonato) cobalt(I) has a detailed X ray examination been performed (1). This has been shown to have a square pyramidal structure with the N-O bond inclined at 139°to the pyramidal axis, forming an unsymmetrical π bond with the cobalt atom.

Keywords

Nitric Oxide Coordinate Compound Cobalt Atom Molecular Weight Determination Pyramidal Structure 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

References

  1. 1.
    ALDERMAN, P. R. H., OWSTON, P. G., and ROWE, J. M., J.Chem. Soc. (London), 1962, 668.Google Scholar
  2. 2.
    GRAY, H. B., BERNAL, I., and BILLIG, E., J.Am.Chem.Soc., 84, 3404 (1962).CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Wien 1964

Authors and Affiliations

  • A. Earnshaw
    • 1
  • P. C. Hewlett
    • 1
  • L. F. Larkworthy
    • 1
  1. 1.Battersea College of TechnologyLondonUK

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