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The Electronic Spectra, Optical Rotatory Power, and Absolute Configuration of O-Phenanthroline and 2,2′-Dipyridyl Complexes

  • A. J. McCaffery
  • S. F. Mason
  • B. J. Norman
Conference paper

Abstract

The present work reports the circular dichroism spectra and the unpolarized light absorption of the tris-2, 2′-dipyridyl and the tris-1,10-phenanthroline complexes of Ni(II), Fe(II), Ru(II), Os(II), Ru(III) and Os(III). The particular enantiomers studied were those forming the less soluble (math) — salt and the less soluble antimonyl-(+)-tartrate. On solubility grounds these enantio — mers are expected to have the same absolute configuration as (math), since the latter complex ion preferentially precipitates the (-)-isomer from a solution of racemic K3Co(ox)3.

Keywords

Circular Dichroism Circular Dichroism Spectrum Optical Rotatory Optical Activity Absolute Configuration 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Copyright information

© Springer-Verlag Wien 1964

Authors and Affiliations

  • A. J. McCaffery
    • 1
  • S. F. Mason
    • 1
  • B. J. Norman
    • 1
  1. 1.Chemistry DepartmentUniversity of ExeterUK

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