Abstract
The present work reports the circular dichroism spectra and the unpolarized light absorption of the tris-2, 2′-dipyridyl and the tris-1,10-phenanthroline complexes of Ni(II), Fe(II), Ru(II), Os(II), Ru(III) and Os(III). The particular enantiomers studied were those forming the less soluble (math) — salt and the less soluble antimonyl-(+)-tartrate. On solubility grounds these enantio — mers are expected to have the same absolute configuration as (math), since the latter complex ion preferentially precipitates the (-)-isomer from a solution of racemic K3Co(ox)3.
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© 1964 Springer-Verlag Wien
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McCaffery, A.J., Mason, S.F., Norman, B.J. (1964). The Electronic Spectra, Optical Rotatory Power, and Absolute Configuration of O-Phenanthroline and 2,2′-Dipyridyl Complexes. In: Gutmann, V. (eds) Proceedings of the 8th International Conference on Coordination Chemistry. Springer, Vienna. https://doi.org/10.1007/978-3-7091-3650-8_37
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DOI: https://doi.org/10.1007/978-3-7091-3650-8_37
Publisher Name: Springer, Vienna
Print ISBN: 978-3-7091-3652-2
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