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Chemical Structure Determination of Lantanides’ Coordination Compounds on the Basis of Their Absorption Spectra

  • K. B. Yatsimirsky
  • N. K. Davidenko
  • N. A. Kostromina
  • T. V. Ternovaya
Conference paper

Abstract

Heretofore the majority of investigators considered the chemical bond in coordination compounds of the rare earths elements to be of ionic nature. Within the last years, however, many arguments have been submitted in favour of a partial covalency of the formed bonds. One of the reasons points out at the impossibility to deduce thermodynamical characteristics of the complexes on the mere basis of the ions charges and radii. An ample information on the geometry and chemical structure of the rare earth coordination compounds may be obtained on the basis of their absorption spectra.

Keywords

Coordination Compound Gluconic Acid Partial Covalency Ionic Nature Crystal Field Effect 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    JØRGENSEN, C. K., “Absorption spectra and chemical bonding in com — plexes” Pergamon Press, Oxford, London, New York, Par is (1962).Google Scholar
  2. 2.
    JØRGENSEN, C. K., J. Chem. Phys., 39, 1422 (1963).CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Wien 1964

Authors and Affiliations

  • K. B. Yatsimirsky
    • 1
  • N. K. Davidenko
    • 1
  • N. A. Kostromina
    • 1
  • T. V. Ternovaya
    • 1
  1. 1.Ukrainian Academy of ScienceKievUSSR

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