Luminescence Spectra of Transition-Metal Complexes

  • V. Caglioti
  • G. Sartori
  • C. Furlani
Conference paper


Photoexcited luminescence spectra of transition metal complexes have been reported until now in the literature in several instances, some of which (e. g. Cr3+ in ruby (1) and in other complexes (2)) have acquired major importance in the elucidation of the symmetry type and of the electronic structure of coordination compounds; other literature reports include Mn2+ (3) and Mn3+ (4).


Emission Band Transition Metal Complex Symmetry Type Excited Triplet Vibronic Coupling 
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  1. 1.
    SUGANO, S., and TANABE, Y., Disc. Faraday Soc., 26, 43 (1958).CrossRefGoogle Scholar
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    FORSTER, L., and de ARMOND, K., J. Chem. Phys., 34, 2193 (1961);CrossRefGoogle Scholar
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    PORTER, G. P., and SCHLÔFER, H. C., Z. Phys. Chem. N. F., 37, 109 (1963), and several others.CrossRefGoogle Scholar
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    ORGEL, L. E., J. Chem. Phys., 23, 1958 (1955).CrossRefGoogle Scholar
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    KRÖGER, F. A., J. Chem. Phys., 20, 345 (1952).CrossRefGoogle Scholar
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    FURLANI, C., and SARTORI, G., Gazz. Chim. Ital., 87, 371, 380 (1957).Google Scholar

Copyright information

© Springer-Verlag Wien 1964

Authors and Affiliations

  • V. Caglioti
    • 1
  • G. Sartori
    • 1
  • C. Furlani
    • 1
  1. 1.Istituto ChimicoUniversità di RomaItaly

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